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Journal : Jurnal Penelitian Tanaman Industri (Littri)

MODEL PENDUGAAN KANDUNGAN AIR, LEMAK DAN ASAM LEMAK BEBAS PADA TIGA PROVENAN BIJI JARAK PAGAR (Jatropha curcas L.) MENGGUNAKAN SPEKTROSKOPI INFRAMERAH DEKAT DENGAN METODE PARTIAL LEAST SQUARE (PLS) LADY C. E. CH. LENGKEY; I WAYAN BUDIASTRA; KUDANG B. SEMINAR; BAMBANG S. PURWOKO
Jurnal Penelitian Tanaman Industri Vol 19, No 4 (2013): Desember 2013
Publisher : Pusat Penelitian dan Pengembangan Perkebunan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21082/jlittri.v19n4.2013.203-211

Abstract

ABSTRAKJarak pagar berpotensi sebagai sumber biodiesel karena kandunganlemak yang tinggi (>40%) dan belum ada penggunaan lainnya.Spektroskopi (Near Infrared) NIR adalah metode yang cepat untukmengukur spektrum sampel dan tidak terdapat limbah kimia. Tujuanpenelitian adalah mengembangkan metode pendugaan komposisi kimiabeberapa  provenan  jarak  pagar  berdasarkan  spektroskopi  NIRmenggunakan kalibrasi PLS. Pengujian dilakukan menggunakan tigaprovenan jarak pagar yaitu IP-3A, IP-3M, dan IP-3P masing-masing 85sampel. Spektrum reflektansi diukur menggunakan alat NIRFlex SolidsPetri pada panjang gelombang 1000–2500 nm. Sekitar ⅔ jumlah sampeldigunakan untuk mengembangkan persamaan kalibrasi dan ⅓ jumlahsampel untuk validasi. Pra perlakuan data spektrum dilakukan dengannormalisasi antara 0-1, turunan pertama Savitzky-Golay 9 titik dangabungan keduanya. Hasil penelitian menunjukkan spektroskopi NIRdapat menduga kadar air, lemak, dan asam lemak bebas . Koefisienkorelasi (r) antara komponen kimia metode acuan dengan dugaan NIR>0,83 menunjukkan ketepatan model cukup baik (r kadar air=0,96, r kadarlemak=0,92, dan r ALB=0,89 ). Konsistensi model kalibrasi kadarair=94,85%, lemak=82,56%, dan ALB=87,80%. Koefisien keragamandugaan (Prediction Coeficient Variability/PCV) ketiga model <10%menunjukkan model yang dibangun cukup handal. Ratio of standard errorprediction to deviation (RPD) menunjukkan metode spektroskopi NIRdapat digunakan untuk menentukan kadar air (RPD=3,30) dan lemak(RPD=2,06). Model-model yang dikembangkan secara umum layakuntuk menentukan kadar air dan lemak biji jarak pagar, tetapi belumoptimal untuk penentuan kadar ALB biji jarak pagar.Kata kunci: NIR , jarak pagar, kadar air, kadar lemak, kadar asam lemakbebasABSTRACTPhysic nut is a potential source of biodiesel. It is high in fat content,above 40% and has not been usesed for other purposes. Moisture, free fattyacid, and fat content are the chemical compounds and determinant factorfor physic nut seed quality. The objective of this study was to develop amethod to predict chemical composition of physic nut by NIRspectroscopy and PLS calibration. The study was conducted using threeprovenances of physic nut, i.e. IP-3A, IP-3M, and IP-3P, with 85 sampleseach. The wavelengths of near infrared reflectance ranged from 1000 to2500 nm, and measured by NIR Flex Solids Petri Apparatus.Approximately ⅔ of total samples were used for developing calibrationequation, while ⅓ of total samples for performing validation. Pre-treatmentof spectrum data was done by applying normalization, first derivative ofSavitzky–Golay 9 points, and as well as their combination. The resultsshowed that NIR spectroscopy performed acceptable prediction formoisture and fat content. Correlation coefficients (r) between the referencemethod and NIR prediction were 0.96 for moisture content, 0.92 for fatcontent, and 0.89 for FFA and the consistency of the model were 94.85%for moisture content, 82.56% for fat, and 87.80% for FFA. Prediction ofcoefficient of variability (PCV) of the three models ≤10 % shows that themodels are reliable. Ratio of standard error prediction to deviation (RPD)for moisture content has the potential to be used for screening (RPD=3.30)though the fat content model has rough screening (RPD=2.06).Key words: NIR, physic nut, moisture, fat, free fatty acid contents.
Co-Authors . Saputera . Sutrisno A. Trisnobudi Adrizal . Agus A Munawar Ahmuhardi Abdul Azis Amin Rejo Amoranto Trisnobudi Anggie Yulia Sari Aris Purwanto Aryanis Mutia Zahra Baihaqi Baihaqi Bambang Haryanto Bambang Haryanto Bambang Haryanto Bambang Haryanto BAMBANG S. PURWOKO Bambang S. Purwoko Bambang Soenarto Baskoro Wicaksono, Baskoro Dheni Mita Mala Dwi Dian Novita Ei Mon Kyaw Emmy Darmawati Fadfhillah, Dini Nur Fadhillah, Dini Nur Fila Rodotul Jannah Hadi K. Purwadaria Hadi K. Purwadaria Hadi K. Purwadaria Hafiz Fajrin Aditama Harmi Andrianyta Herna Permata Sari I Kadek Suardika I M. S. Wibawa I Nyoman Sutarpa Sutama I Wayan Redana I Wayan Redana I Wayan Redana I. B. M. Suryatika Indah Kurniasari Irawaty Irawaty Jajang Juansah Jajang Juansah Jati Sumarto Putro Jeris Habfrons Wiatri Djereng Juhana, Juhana Ketut Agus Karmadi KUDANG B. SEMINAR Kudang B. Seminar Kustoko, Kusriani La Rianda LADY C. E. CH. LENGKEY Lady Lengkey Lalu Hendri Setiawan Mar'atus Sholihah Mawiti Infantri Mawiti Infantri Yekti N. N. Ratini Noneng Fahri Novi Andareswari Noviar Harun Nur Arifiya Ocarina, Estika Parida, Desca Putu Doddy Heka Ardana Rini Rosita Rizal Syarief Rizky Wiradinata Rokhani Hasbullah Ruri Wijayanti Samsudin Samsudin SEDARNAWATI YASNI Sigid Hariyadi Siti Djamila Siti Zulaikah Slamet Susanto Slamet Widodo Slamet Widodo Sobir Sobir Sri Agustina Sri Citra Yuliana Madi Sugiyono . Sugiyono Sugiyono Suharta, I Wayan Gede Sukrisno Widyotomo Suroso . Suroso . Suroso Suroso Sut risno Sutrisno - Sutrisno . Sutrisno Mardjan Sutrisno Sutrisno Trisma Rezeki Zairisman Usman Ahmad Vita N. Lawalata Wendianing Putri Luketsi Wiranda G. Piliang Yasin, Yasnita Yul Y Nazaruddin Yunisa Tri Suci