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All Journal Reaktor Journal of Engineering and Technological Sciences agriTECH Jurnal Litbang Industri Jurnal Litbang Industri Jurnal Rekayasa Kimia & Lingkungan Teknologi dan Industri Pertanian Indonesia
Husni Husin
Universitas Syiah Kuala
Agriculture, Biological Sciences & Forestry Chemical Engineering, Chemistry & Bioengineering Chemistry Control & Systems Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

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Synthesis of Nanocrystalline of Lanthanum Doped NaTaO3 and Photocatalytic Activity for Hydrogen Production Husin, Husni; Pontas, Komala; Sy, Yuliana; Syawaliah, S.; Saisa, S.
Journal of Engineering and Technological Sciences Vol 46, No 3 (2014)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (603.06 KB) | DOI: 10.5614/j.eng.technol.sci.2014.46.3.6

Abstract

Sodium tantalum oxide doping lanthanum (La-NaTaO3) compounds were successfully synthesized by a sol-gel method and calcined at different temperatures. Tantalum chloride (TaCl5) was used as starting material and lanthanum nitrate (La(NO3)3.6H2O) as lanthanum source. X-ray diffraction (XRD) revealed that the calcination temperature strongly influenced the crystallinity of the prepared samples.The crystallite sizes of the resultant La-NaTaO3were in the range of 27-46 nm. The photocatalytic activities of the samples were examined for hydrogen production from an aqueous methanol solution under UV light irradiation. It was found that the photocatalytic activity of the La-NaTaO3 depended strongly on the calcination temperature. The range of calcination temperatures were 500, 700, and 900°C. The La-NaTaO3 sample calcined at 900°C showed the highest photocatalytic activity compared to the samplescalcined at the other temperatures. The rate of hydrogen production reached a value of 6.16 mmol h-1 g-1 catalyst.
Sulfur Removal in Bio-Briquette Combustion Using Seashell Waste Adsorbent at Low Temperature Mahidin, Mahidin; Gani, Asri; Muslim, Abrar; Husin, Husni; Hani, M. Reza; Syukur, Muhammad; Hamdani, Hamdani; Khairil, Khairil; Rizal, Samsul
Journal of Engineering and Technological Sciences Vol 48, No 4 (2016)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (361.363 KB) | DOI: 10.5614/j.eng.technol.sci.2016.48.4.8

Abstract

Presently, biomass is mostly utilized as co-fuel in coal combustion in view of energy diversification and emission reduction. However, since the coal content of bio-briquettes is high (up to 80% in this study), gas emissions such as those of SOx still occur. Therefore, the introduction of SO2adsorbent is common in coal briquette or bio-briquette combustion. A calcium-based material is usually used for this goal. The aim of this study was to observe the effects of desulfurization temperature and Ca/S ratio (Ca = calcium content in adsorbent; S = sulfur content in coal and biomass) on desulfurization efficiency and kinetics. The ratio of coal to biomass (palm kernel shell/PKS) was fixed at 90:10 (wt/wt) and the ratios of Ca to S were varied at 1:1, 1.25:1, 1.5:1, 1.75:1 and 2:1. The mixtures of coal, PKS and adsorbent were briquetted at a molding pressure of 6 ton/cm2 with Jatropha curcas seeds and starch mixture as binding agents. Desulfurization was performed within a temperature range of 300 to 500°C for 720 seconds at an airflow rate of 1.2 L/min. The results showed that the highest desulfurization efficiency (90.6%) was associated with the Ca/S ratio of 2:1 and temperature of 400°C. Moreover, the highest reaction rate constant of desulfurization was 0.280 min-1.
Preparasi Katalis Abu Kulit Kerang untuk Transesterifikasi Minyak Nyamplung Menjadi Biodiesel Zuhra Zuhra; Husni Husin; Fikri Hasfita; Wahyu Rinaldi
agriTECH Vol 35, No 1 (2015)
Publisher : Faculty of Agricultural Technology, Universitas Gadjah Mada, Yogyakarta, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (257.964 KB) | DOI: 10.22146/agritech.9421

Abstract

Biodiesel, as a potential substituted energy, has attracted a great attention in recent years, which can be produced from o3 renewable sources and provides complete combustion with less gaseous pollutant emission. Biodiesel is produced conventionally via transesterification of vegetable oils using homogeneous catalysts, e.g. KOH, NaOH, and HaSO4. The homogeneous catalytic process, however, provides some disadvantages, such as, a huge production of wastewater from washing process of catalyst residues and non-reusability of the catalysts. In order to circumvent most of the economical and environmental drawbacks of homogeneous process, heterogeneous catalysts, this can be easily separated from reaction mixture by filtration. These catalysts are less corrosive and more environment-friendly. The objective of this work was to develop the effectivity of using waste of cockle (Clinocardium nuttalli) shell as a heterogeneous base catalyst for the biodiesel production. The catalysts were prepared by simple calcination methods, at temperatures of 600, 700, 900 oC, and without calcination. Calcined catalysts were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) technique. Transesterification process of Calophyllum inophyllum L.oil and o methanol were carried out under bath reactor over the cockle shellcatalysts to produce biodiesel. The XRD patterns depicted that CaCO3 was successfully converted into CaO. SEM recorded demonstrates that the particle catalyst become smaller after heating. The highest activity was found at calcined catalyst of 900 oC, with the yield of biodiesel reaching 87.4% during 3 hours. The solid catalyst from waste cockle shell was proven to be durable for the transesterification of edible oil.ABSTRAKBiodiesel, sebagai sumber energi potensial telah menarik perhatian dalam beberapa tahun terakhir, karena dapat diproduksi dari sumber terbaharukan dan menghasilkan polutan yang rendah. Secara konvensional, biodiesel diproduksi melalui transesterifikasi minyak nabati menggunakan katalis homogen, yaitu: KOH, NaOH, dan H2SO4. Proses katalitik homogen memiliki beberapa kekurangan, seperti: banyak mengeluarkan air buangan dari pencucian residu katalis dan tidak dapat digunakan kembali. Untuk mengatasi kekurangan penggunaan katalis homogen baik secara ekonomi maupun lingkungan ditempuh dengan mengembangkan katalis heterogen atau katalis padat, yang dapat dengan mudah dipisahkan dari campuran reaksi secara filtrasi. Katalis ini juga rendah korosi dan lebih ramah lingkungan. Tujuan dari penelitian ini adalah untuk mengetahui efektivitas penggunaan abu kulit kerang yang mengandung CaO (kalsium oksida) sebagai katalis heterogen terhadap rendemen biodiesel. Bahan baku untuk pembuatan biodiesel adalah minyak nyamplung. Katalis disiapkan dengan metode kalsinasi sederhana pada temperatur: 600, 700, 900 oC, dan tanpa kalsinasi. Setelah kalsinasi, katalis dikarakterisasi denganmetode X-ray Diffraction (XRD) dan Scanning Electron Microscopy (SEM). Reaksi transesterifikasi minyak nyamplung dengan metanol dilangsungkan di dalam reaktor berpengaduk menggunakan katalis padat dari kulit kerang. Dari pola XRD mengindikasikan bahwa CaCO3 terkonversi dari kulit kerang sempurna menjadi CaO ketika kulit kerang dikalsinasi pada suhu 900 oC. Hasil rekaman SEM diperoleh ukuran partikel katalis setelah dipijar menjadi kecil. Aktivitas katalis tertinggi diperoleh pada penggunaan abu kulit kerang yang dikalsinasi pada suhu 900 oC. Rendemenmetil ester tertinggi mencapai 87,4% setelah 3 jam reaksi. Katalis abu kulit kerang telah terbukti dapat digunakan untuk reaksi transesterifikasi minyak nabati menjadi biodiesel.
STUDI PENGGUNAAN KATALIS ABU SABUT KELAPA, ABU TANDAN SAWIT DAN K2CO3 UNTUK KONVERSI MINYAK JARAK MENJADI BIODIESEL Husni Husin; Mahidin Mahidin; Marwan Marwan
Reaktor Volume 13, Nomor 4, Desember 2011
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (280.026 KB) | DOI: 10.14710/reaktor.13.4.254-261

Abstract

A STUDY ON THE UTILIZATION OF OIL PALM FIBRE AND FRUIT BUNCH ASH AND K2CO3 FOR CATALYTIC CONVERSION OF JATHROPA OIL TO BIODIESEL. Study on the use of coconut fiber ash, palm bunch ash and K2CO3 as the catalysts for conversion of jatropha oil into biodiesel using methanol solvent has been done. The biodiesel is produced by converting unpurified jatropha oil over catalyst through transesterification reaction. The catalysts are burned at temperature of 500, 600, 800 and 900oC for 10 hours. Transesterification reaction is conducted in three-neck flask at constant temperature of 60oC for 3 hours. The results showed that the unburned and burned coconut fiber ashes at 800oC catalysts give the highest biodiesel yield (87.05 and 87.97%) with low soap content (0.23-0.26%). The characteristic of biodiesel produced over those catalysts met the Indonesian and international quality standards, therefore those catalysts can be used as substitute for K2CO3 commercial catalyst.Abstrak   Studi penggunaan katalis abu sabut kelapa, abu tandan sawit dan K2CO3 untuk konversi minyak jarak menjadi biodiesel dengan pelarut metanol telah dilakukan. Biodiesel dibuat melalui konversi minyak jarak yang belum dimurnikan, menggunakan katalis, melalui reaksi transesterifikasi. Katalis-katalis tersebut dipijarkan pada temperatur 500, 600, 800 dan 900oC selama 10 jam. Reaksi dilangsungkan dalam labu leher tiga pada temperatur konstan 60oC selama 3 jam. Hasil penelitian menunjukkan penggunaan katalis abu sabut kelapa tanpa pemijaran dan dengan pemijaran pada 800oC memberikan perolehan biodiesel tertinggi (87,05 dan 87,97%) dengan kadar sabun rendah (0,23-0,26%). Karakteristik biodiesel yang dihasilkan dari penggunaan katalis-katalis tersebut ini telah sesuai dengan syarat mutu yang ditetapkan oleh Standar Indonesia dan Internasional, sehingga katalis-katalis tersebut layak digunakan sebagai pengganti katalis K2CO3 komersial
Transesterifikasi minyak kemiri sunan menjadi biodiesel menggunakan katalis padat K2O/C Muhammad Zaki; Teku Muhammad Asnawi; Husni Husin; Saifullah Ramli; Sofyana Sofyana; Fikri Hasfita; Justaman Arifin Karo Karo
Jurnal Litbang Industri Vol 10, No 2 (2020)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24960/jli.v10i2.6143.83-88

Abstract

Preparasi katalis padat K2O/C telah berhasil disiapkan dengan mengimpregnasi K2CO3 pada permukaan karbon aktif sekam padi selama 6 jam. Campuran tersebut dikalsinasi pada suhu 300 oC selama 3 jam hingga terbentuk K2O/C. Tujuan penelitian ini adalah untuk menginvestigasi kinerja katalis K2O/C dalam proses  transesterifikasi minyak biji kemiri sunan menjadi biodiesel. Karbon sekam padi (C) dipersiapkan dengan proses pirolisis sekam padi, dilanjutkan dengan proses aktivasi untuk mendapatkan karbon sebagai penyangga berpori. Katalis K2O/C  dikarakterisasi dengan Scanning Electron Microscopy (SEM) dan Energy-Dispersive X-ray (EDX). Hasil analisa EDX menunjukkan bahwa komposisi katalis didominasi oleh karbon (C) dan kalium (K). Fasa aktif K2O terdistribusi pada permukaan karbon aktif secara merata. Katalis K2O/C yang dihasilkan digunakan dalam reaksi transesterifikasi minyak kemiri sunan menggunakan reaktor batch. Yield biodiesel tertinggi dicapai hingga 98,68% ketika menggunakan katalis 4%, loading K2CO3  pada karbon aktif 0,5% berat, waktu  reaksi 90 menit, serta rasio molar metanol terhadap minyak 8:1. Katalis K2O/C sangat berpotensi untuk dikembangkan selanjutnya sebagai salah satu katalis padat untuk mengkonversi minyak nabati menjadi biodiesel.
Transesterifikasi minyak kemiri sunan menjadi biodiesel menggunakan katalis padat K2O/C Muhammad Zaki; Teku Muhammad Asnawi; Husni Husin; Saifullah Ramli; Sofyana Sofyana; Fikri Hasfita; Justaman Arifin Karo Karo
Jurnal Litbang Industri Vol 10, No 2 (2020)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (886.651 KB) | DOI: 10.24960/jli.v10i2.6143.83-88

Abstract

Preparasi katalis padat K2O/C telah berhasil disiapkan dengan mengimpregnasi K2CO3 pada permukaan karbon aktif sekam padi selama 6 jam. Campuran tersebut dikalsinasi pada suhu 300 oC selama 3 jam hingga terbentuk K2O/C. Tujuan penelitian ini adalah untuk menginvestigasi kinerja katalis K2O/C dalam proses  transesterifikasi minyak biji kemiri sunan menjadi biodiesel. Karbon sekam padi (C) dipersiapkan dengan proses pirolisis sekam padi, dilanjutkan dengan proses aktivasi untuk mendapatkan karbon sebagai penyangga berpori. Katalis K2O/C  dikarakterisasi dengan Scanning Electron Microscopy (SEM) dan Energy-Dispersive X-ray (EDX). Hasil analisa EDX menunjukkan bahwa komposisi katalis didominasi oleh karbon (C) dan kalium (K). Fasa aktif K2O terdistribusi pada permukaan karbon aktif secara merata. Katalis K2O/C yang dihasilkan digunakan dalam reaksi transesterifikasi minyak kemiri sunan menggunakan reaktor batch. Yield biodiesel tertinggi dicapai hingga 98,68% ketika menggunakan katalis 4%, loading K2CO3  pada karbon aktif 0,5% berat, waktu  reaksi 90 menit, serta rasio molar metanol terhadap minyak 8:1. Katalis K2O/C sangat berpotensi untuk dikembangkan selanjutnya sebagai salah satu katalis padat untuk mengkonversi minyak nabati menjadi biodiesel.
Pembuatan Katalis Cu/ZnO/Al2O3 untuk Proses Steam Reforming Metanol menjadi Hidrogen sebagai Bahan Bakar Alternatif Husni Husin; Yanna Syamsuddin
Jurnal Rekayasa Kimia & Lingkungan Vol 7, No 3 (2010): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (229.914 KB)

Abstract

Study on the use of copper zinc oxide supported on alumina catalyst for steam reforming of methanol to hydrogen has been done. The aim of this work is to study the catalytic properties of copper based catalysts used in the steam reforming of methanol. This method is known as one of the most favorable catalytic processes for producing hydrogen on-board. The catalyst was prepared by impregnation method with Cu loading of 5%, 10%, and 15%,. The X-ray diffraction pattern shows that the catalyst compositions are Cu, CuO, ZnO, and Al2O3. The reactions were carried out in the fixed bed tubular reactor operating at temperatures of 150oC, 200oC, 250oC, 300oC, and 350oC and atmospheric pressure. The product was analyzed using Shimadzu Gas Chromatography GC 8A with mole sieve 5A and porapak-N column 80/100 mesh. The performance of the catalyst shows that the highest methanol conversion was 86% over Cu/ZnO/Al2O3 catalyst with 15% of Cu loading. The selectivity and yield of hydrogen was 66% and 57% respectively over Cu/ZnO/Al2O3 catalyst with 15% of Cu loading. Selectivity of carbon dioxide is 18% over Cu/ZnO/Al2O3 catalyst with 15% of Cu loading at 300oC.Keywords: alumina oxide catalyst, copper zinc oxide, hydrogen, impregnation
Studi Oksidasi Etanol Menjadi Asetaldehida Menggunakan Katalis Molibdenum Oksida Berpenyangga Al2O3, TiO2, dan SiO2 Husni Husin; Fikri Hasfita
Jurnal Rekayasa Kimia & Lingkungan Vol 5, No 1 (2006): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (344.543 KB)

Abstract

Penelitian ini bertujuan untuk mengevaluasi pengaruh penyangga Al2O3, SiO2, dan TiO2 pada MoO3 terhadap kinerjanya dalam oksidasi etanol menjadi asealdehida. Katalis disiapkan dengan metode impregnasi dengan kandungan MoO3 of 25% dan 50%. Hasil identifikasi  dengan X-ray Difraction (XRD) menunjukkan bahwa komponen katalis terdiri dari kristal MoO3, TiO2, Al2O3, dan SiO2. Reaksi uji kinerja katalis dilangsungkan dalam reaktor pipa lurus berunggun tetap, beroperasi pada 150-300oC dan tekanan atmosfir. Produk dianalisis menggunakan gas kromatografi GC 8A buatan Shimadzu dengan kolom porapak Q 80/100 mesh. Konversi etanol tertinggi diperoleh 83% menggunakan katalis 50%MoO3/TiO2. Selektivitas asetaldehida tertinggi dihasilkan 96% menggunakan katalis 25%MoO3/SiO2. Yield asetadehida tertinggi dicapai 51% menggunakan katalis 25%MoO3/TiO2.Kata kunci:  katalis MoO3/TiO2, Al2O3, SiO2, impregnasi, oksidasi etanol, asetaldehida
Pembuatan Katalis Padat ZrO2/Al2O3 untuk Produksi Biodiesel dari Minyak Jarak Yanna Syamsuddin; Husni Husin
Jurnal Rekayasa Kimia & Lingkungan Vol 7, No 3 (2010): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (325.92 KB)

Abstract

Biodiesel is one of the alternative energy to replace petroleum diesel. Biodiesel is produced by transesterification of vegetable oil into alkyl ester and glycerol as by-product. The vegetable oil based put biodiesel as a renewable and environmentally friend energy source. Research on making of solid catalyst ZrO2/Al2O3 for biodiesel production from jatropha oil has been done. The catalysts were prepared by impregnation method with different amount of Zr (2, 5, 15, and 20%) and the components were characterized by using XRD. Transesterification reaction was done by reacting jatropha oil with methanol and catalyst with the ratio of oil to methanol of 1:6, reaction temperature of 60oC, and reaction time of 3 hours. Biodiesel produced were analyzed for their yield and composition using GC-MS. The biodiesel products were also characterized for their viscosity, density, acidic and saponification value. Characterization of catalysts showed that components of synthesized ZrO2/Al2O3 were ZrO, ZrO2, and Al2O3. The highest yield of biodiesel produced was resulted from transesterification reaction using catalyst with 2% Zr. GC-MS results showed that methyl esters of biodiesel produced confirmed with fatty acids in jatropha oil with methyl oleic is the highest. Characteristic of the biodiesel has met the quality standard of ASTM, prEN and SNI.Keywords: biodiesel, katalis, minyak jarak, ZrO2/Al2O3
Oksidasi Parsial Metana Menjadi Metanol dan Formaldehida Menggunakan Katalis CuMoO3/SiO2 : Pengaruh Rasio Cu:Mo, Temperatur Reaksi dan Waktu Tinggal Husni Husin; Lia Mairiza; Zuhra Zuhra
Jurnal Rekayasa Kimia & Lingkungan Vol 6, No 1 (2007): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (183.834 KB)

Abstract

Oksidasi parsial metana menjadi metanol dan formaldehida menggunakan katalis tembaga molybdenum oksida berpenyangga silica (CuMoO3/SiO2) telah dilakukan. Preparasi katalis dilakukan dengan metode impregnasi. Hasil identifikasi dengan XRD menunjukkan bahwa komponen katalis terdiri dari senyawa MoO3, CuO, dan SiO2. Uji kinerja katalis dilangsungkan dalam reactor pipa lurus berunggun tetap, beroperasi pada temperature 400, 425, 450, 475, dan 500oC, dengan waktu tinggal (W/F) 5,82, 9,7, dan 14,55 gram katalis jam/mol. Produk reaksi dianalisis menggunakan gas kromatografi dengan kolom molsieve 5A dan porapak-Q. konversi metana tertinggi sebesar 36,83% diperoleh saat menggunakan katalis dengan rasio Cu:Mo=1:1,5 pada W/F 14,55 grcatjam/mol dan temperatur reaksi 500oC. Selektivitas metanol tertinggi diperoleh 11,19 % menggunakan katalis dengan rasio Cu : Mo 1 : 3,5 pada W/F 5,82 grcat.jam/mol dan temperatur reaksi 400oC. Selektivitas formaldehida tertinggi diperoleh 20,75% menggunakan katalis dengan rasio Cu : Mo 1 : 2,5 pada W/F 9,7 grcatjam/mol dan temperatur reaksi 400oC.Keywords: formaldehida, katalis CuMoO3/SiO2, metanol, oksidasi metana
Co-Authors Gani, Asri Hamdani, Hamdani Hani, M. Reza Jefry Yusuf Justaman Arifin Karo Karo Khairil, Khairil Komala Pontas Lia Mairiza Mahidin Mahidin Mahidin, Mahidin Marwan Marwan Marwan Marwan Marwan Marwan Muhammad Zaki Muslim, Abrar Rizal, Samsul S. Saisa S. Syawaliah Saifullah Ramli Sofyana, Sofyana Syukur, Muhammad Teku Muhammad Asnawi Wahyu Rinaldi Yuliana Sy Zuhra Zuhra