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All Journal BIOTROPIA - The Southeast Asian Journal of Tropical Biology Prosiding Seminar Nasional Sains Dan Teknologi Fakultas Teknik
Teguh Ariyanto
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Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Computer Science & IT Engineering Immunology & microbiology Veterinary

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DEGRADASI LIMBAH ZAT WARNA DENGAN KATALIS KARBON AKTIF TEREMBAN OKSIDA BESI Shinta Amelia; Wahyudi Budi Sediawan Sediawan; Imam Prasetyo; Teguh Ariyanto
Prosiding SNST Fakultas Teknik Vol 1, No 1 (2017): PROSIDING SEMINAR NASIONAL SAINS DAN TEKNOLOGI 8 2017
Publisher : Prosiding SNST Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (312.582 KB)

Abstract

Limbah zat warna dapat memberikan dampak negatif bagi kesehatan dan lingkungan. Metode adsorpsi yang dianggap paling efektif untuk mengelola limbah zat warna memiliki kekurangan karena sistem ini hanya mentransfer limbah ke bahan padat dan adsorben tidak dapat di recycle. Pada studi ini, reaksi degradasi katalitik heterogen zat warna dengan sistem reaksi Fenton dilakukan untuk mengatasi limitasi metode adsorpsi. Katalis heterogen oksida besi/karbon dibuat melalui dua tahapan, yaitu impregnasi garam besi dengan metode incipient wetness dan kalsinasi pada suhu 300 °C. Loading oksida besi divariasikan dari 0.5 sampai 2% massa. Reaksi degradasi katalitik zat warna dengan katalis oksida besi/karbon dilakukan pada sistem batch dengan 200 ml larutan metilen biru (konsentrasi 20 ppm) dan penambahan 5 ml H2O2 50%v/v. Uji adsorpsi tanpa reaksi katalitik dilakukan sebagai pembanding. Hasil penelitian menunjukkan bahwa degradasi katalitik lebih efektif 31.3% dibandingkan proses adsorpsi. Degradasi metilen biru meningkat dengan naiknya katalis loading dan hasil dekolorisasi tertinggi sebesar 0.365 mmol/(gr katalis) dengan katalis 2% oksida besi/karbon. Studi ini menunjukkan bahwa degradasi katalitik dapat menjadi metode yang efektif untuk mengatasi limbah zat warna.Kata kunci: karbon aktif; oksida besi; oksidasi katalitik 
INCORPORATION OF SODIUM HYALURONATE AND NYAMPLUNG (Calophylum inophyllum) CAKE EXTRACT TO IMPROVE BIOPLASTIC CHARACTERISTIC : Rini Umiyati; Chusnul Hidayat; Ria Millati; Teguh Ariyanto
BIOTROPIA - The Southeast Asian Journal of Tropical Biology Vol. 29 No. 1 (2022): BIOTROPIA Vol. 29 No. 1 April 2022
Publisher : SEAMEO BIOTROP

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11598/btb.2022.29.1.1626

Abstract

The cross-linking agent plays an important role in bioplastic mechanical properties. This study aimed to determine the effect of Sodium Hyaluronate (SoHA) as a synthetic cross-linking agent and the addition of Nyamplung Cake Extract (NCE) as an antimicrobial agent in the manufacture of bioplastic with hydroxypropyl starch (HPS) as based ingredient using the thermo-compression method. The novelty of the study was thiocyanate (SCN) formation in zone 3 (2161.66-2162.02/cm) and cyanate (C-N=O) in zone 6 (1,411.57 - 1,412.61/cm) of (1, 2 and 3%) SoHA bioplastic and cyanate formation in zone 6 and 7 (1,411.37 - 1,558.59/cm) of (1, 2 and 3%) SoHA – 20% NCE combined bioplastic originating from acetanilide group in SoHA and amide group in NCE. The formation of SCN and C-N=O in 2 and 3% SoHA bioplastic improved its sensitivity against gram-positive bacteria (Staphylococcus aureus) indicated by 0.6 mm and 0.45 mm inhibition zone, respectively. C-N=O formed in (1, 2 and 3%) SoHA – 20% NCE combined with bioplastic had 3.25 mm average inhibition zone against gram-positive bacteria (S. aureus), 2.75 mm against gram-negative bacteria (Escherichia coli), and 0.71 mm against fungi (Aspergillus niger). The analysis of mechanical properties showed that an addition of 3% SoHA was able to increase tensile strength and modulus of elasticity while reducing elongation, water solubility and water vapor permeability. Addition of (1, 2 and 3%) SoHA – 20% NCE resulted in a reverse effect.   Keywords: acetanilide, amide, cross-linking agent, cyanate, thiocyanate
Co-Authors Chusnul Hidayat Imam Prasetyo Ria Millati Rini Umiyati Shinta Amelia Wahyudi Budi Sediawan Sediawan