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All Journal Bulletin of Chemical Reaction Engineering & Catalysis Bulletin of Chemical Reaction Engineering & Catalysis
Risfidian Mohadi
Graduate School of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang-Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra
Chemical Engineering, Chemistry & Bioengineering Chemistry

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The Utilization of Mg-Al/Cu as Selective Adsorbent for Cationic Synthetic Dyes Arini Fousty Badri; Neza Rahayu Palapa; Risfidian Mohadi; Mardiyanto Mardiyanto; Fitri Suryani Arsyad; Aldes Lesbani
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 4 Year 2021 (December 2021)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.4.11043.696-706

Abstract

Mg-Al-LDH is a chemical compound produced through co-precipitation technique and modified with Cu(NO3)2.6H2O to form Mg-Al/Cu. However, the research on the capability of these compounds for adsorbing mixtures of cationic dyes as well as malachite green (MG), methylene blue (MB), and Rodhamine-B (Rh-B) has not been carried out. Therefore, this research aims to determine the performance of Mg-Al-LDH and Mg-Al/Cu for removing cationic dyes. The materials used were characterized by using XRD powder, FT-IR, and N2 adsorption desorption. The Adsorption process was conducted by batch system and several effects were investigated, such as kinetic parameter, isotherm, and the temperature condition. The stability feature of Mg-Al-LDH and Mg-Al/Cu was obtained from the regeneration process in the five cycles. The results presented that Mg-Al/Cu was effectively produced, which was indicated by the formation of layer at 10.792° (003), 22.94° (006), 35.53° (112), 55.78° (110), and  56.59° (116). Mg-Al-LDH and Mg-Al/Cu were found to adsorbed MG than the other cationic dyes with adsorption capacity of 68.996 mg/g and 104.167 mg/g, respectively. The unique properties of Mg-Al/Cu includes, structural stability towards the reuse of adsorbent subsequently for five times, without significant decrease of adsorption capacity. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
The Utilization of Mg-Al/Cu as Selective Adsorbent for Cationic Synthetic Dyes Arini Fousty Badri; Neza Rahayu Palapa; Risfidian Mohadi; Mardiyanto Mardiyanto; Fitri Suryani Arsyad; Aldes Lesbani
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 4 Year 2021 (December 2021)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.4.11043.696-706

Abstract

Mg-Al-LDH is a chemical compound produced through co-precipitation technique and modified with Cu(NO3)2.6H2O to form Mg-Al/Cu. However, the research on the capability of these compounds for adsorbing mixtures of cationic dyes as well as malachite green (MG), methylene blue (MB), and Rodhamine-B (Rh-B) has not been carried out. Therefore, this research aims to determine the performance of Mg-Al-LDH and Mg-Al/Cu for removing cationic dyes. The materials used were characterized by using XRD powder, FT-IR, and N2 adsorption desorption. The Adsorption process was conducted by batch system and several effects were investigated, such as kinetic parameter, isotherm, and the temperature condition. The stability feature of Mg-Al-LDH and Mg-Al/Cu was obtained from the regeneration process in the five cycles. The results presented that Mg-Al/Cu was effectively produced, which was indicated by the formation of layer at 10.792° (003), 22.94° (006), 35.53° (112), 55.78° (110), and  56.59° (116). Mg-Al-LDH and Mg-Al/Cu were found to adsorbed MG than the other cationic dyes with adsorption capacity of 68.996 mg/g and 104.167 mg/g, respectively. The unique properties of Mg-Al/Cu includes, structural stability towards the reuse of adsorbent subsequently for five times, without significant decrease of adsorption capacity. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Co-Authors Aldes Lesbani Aldes Lesbani Arini Fousty Badri Fitri Suryani Arsyad Mardiyanto Mardiyanto