Yusuf Nampira
Pusat Teknologi Bahan Bakar Nuklir (PTBBN), BATAN Kawasan Puspiptek-Tangerang Selatan 15314, Banten

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SYNTHESIS AND CHARACTERIZATION OF COMPOSITE ZEOLITE-RESIN POLYMETHACRYLATE Nampira, Yusuf
Jurnal Zeolit Indonesia Vol 7, No 2 (2008)
Publisher : Jurnal Zeolit Indonesia

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Abstract

Composite of Zeolite-resin polymethacrylate have been made with various compositions of zeolite on composite. The composite were made by homogenous mixture of zeolite powder with powder of tetrahidro furfuryl methacrylate, methacrylate polymerization which was conducted by pasta phases with mixing 1 ml mixture solution of tetrahidro furfuryl methacrylate and hydroxy propyl methacrylate. A big part of zeolite in product composite was in the polymer solution phase. The balance between supporting material and matrix material around the zeolite on composite of zeolite-resin polymethacrylate obtained on the fraction of zeolite in the composite between the 46.67% of weight up to 70% of weight. Strength and hardness of zeolite-resin polymethacrylate depends on balance between zeolite and resin polymethacrylate. The optimum hardness of this composite reaches value of 29,7 N/ım2, which obtained from composite that have a fraction zeolite 46,67% of weight.
SELECTIVITY OF LAMPUNG ZEOLITE TOWARDS MATRICES CATIONS GENERATED FROM URANIUM FISSION Amini, Siti; Anggraini, Dian; Nampira, Yusuf; Rosika, Rosika; Noviarti, Noviarti; Nugroho, Arif
Jurnal Zeolit Indonesia Vol 2, No 1 (2003)
Publisher : Jurnal Zeolit Indonesia

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Selectivity of zeolite-lampung (ZKK) towards some matrices cations generated from uranium fission products has been investigated using some typical fission product-non-radioactive cations by cation exchange batch-system process. The previous investigation showed that zeolite-lampung is effectively able to absorb cesium ion from radioactive waste, consequently the presence of others cations i.e. generated cations from the uranium fission products are assumed as the competitive cations which may affect the zeolite selectivity on to Cs exchanges, on the otherhand the Cs-exchange capacity of zeolite would decrease. The main matrices cations which present in the natural zeolite are K+, Na+ and Ca2+and those are generated from fission products such as Cs+, Ba2+, Sr2+ and Ce4+ exist in the nuclear spent fuel solution. The ion exchanges of counterpart cations in zeolites with that each of Cs+, Ba2+, Sr2+ and Ce4+ ion or/and its mixtures have been examined. The selectivity of zeolite onto mentioned exchanged cations has been shown by the correlation of fraction of the cations concentration in the zeolite (Az) towards that in equilibrated solution (As). The results show that the raw zeolite Lampung selectivity is decrease in order to Cs+> Ba2+= Sr2+ > Ce4+. The exchanged capacity of zeolite into Cs+ ion is decreased by the presence of combining ions of Ba2+, Sr2+ and Ce4+, and so are those competitive cations.