Garuda - Garba Rujukan Digital

p-Index From 2019 - 2024

1.066

P-Index

This Author published in this journals

All Journal Jurnal Rekayasa Proses Reaktor Jurnal Teknik Kimia USU Eksergi Seminar Nasional Teknik Kimia Kejuangan JURNAL INTEGRASI PROSES agriTECH ALCHEMY Jurnal Penelitian Kimia Jurnal Rekayasa Proses ASEAN Journal on Science and Technology for Development ASEAN Journal of Chemical Engineering Equilibrium Journal of Chemical Engineering Jurnal Teknik Kimia USU

Sang Kompiang Wirawan

Chemical Engineering Department, Faculty Of Engineering, Universitas Gadjah Mada, Jalan Grafika No. 2, Yogyakarta 55281, Indonesia

Author-ID : 370154

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Control & Systems Engineering Education Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mathematics Social Sciences Other

Published : 19 Documents Claim Missing Document

Claim Missing Document

Articles

1 2

Chitosan Concentration and Cross-linker Volume Effect on The Release Kinetic of Red Ginger Oleoresin Microcapsule in Simulated Intestinal Fluid (SIF) Medium Jayanudin Jayanudin; Moh. Fahrurrozi; Sang Kompiang Wirawan; Rochmadi Rochmadi
Eksergi Vol 16, No 2 (2019)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v16i2.3088

Red ginger oleoresin contains components that can be used as antioxidants. Release kinetics studies are used to provide doses to achieve the desired drug concentration. The purpose of this study was to determine the release kinetics of red ginger oleoresin microcapsules based on changes in chitosan concentration and volume of cross-linker and determine the diffusion coefficient of red ginger oleoresin through microcapsule walls. Red ginger oleoresin microcapsules were prepared from a mixture of red ginger oleoresin in chitosan solution and stirred to form an emulsion. After that, it was added to corn oil and stirred again to form a second emulsion. Glutaraldehyde saturated toluene was added dropwise after finished added the 25% glutaraldehyde solution and remains stirred for 2 hours. Red ginger oleoresin microcapsules were separated and washed with petroleum ether and hexane, then dried in an oven. Microcapsules inserted in the release medium (simulated intestinal fluid) without enzymes, and then the samples were analyzed using a UV-vis spectrophotometer to determine the absorbance. The release kinetics models used were zero order, first order, Higuchi, Korsmeyer-Peppas, and Hixon-Crowell. The highest correlation coefficient (R2) was obtained from the Korsmeyer-Peppas release kinetics model, R2 = 0.73-0.85 with the value of n = 0.39-0.41. Based on the n value, the release mechanism of red ginger oleoresin microcapsules was Fickian diffusion. The diffusion coefficients obtained were 2,807 x 10-13 - 3,675 x 10-13 cm2 /sec.

Pengaruh Proses Pengeringan dan Konsentrasi Gliserol terhadap Karakteristik Mekanik Pektin Edible Film Widra Putri Juwita; Sang Kompiang Wirawan; Aswanti Mindaryani
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2019: PROSIDING SNTKK 2019
Publisher : Seminar Nasional Teknik Kimia Kejuangan

Show Abstract | Download Original | Original Source | Check in Google Scholar

Analisis Permeasi Air pada Dehidrasi Osmosis Pepaya (Carica papaya) Sang Kompiang Wirawan; Natalia Anasta
agriTECH Vol 33, No 3 (2013)
Publisher : Faculty of Agricultural Technology, Universitas Gadjah Mada, Yogyakarta, Indonesia

Fruit preservation using low temperature drying is commonly initiated by osmotic dehydration process. The osmotic time is strongly influenced by the water permeation from the fruit to the osmotic solution. This research aimed to study the osmotic dehydration process of papaya by finding out the permeation rate of water to the osmotic solution across a semi permeable membrane. The effect of temperature and osmotic solution concentration on the permeation rate were also observed. The osmotic temperatures were 30, 40, 50, and 60oC, and the osmotic solution concentration were 55, 60, 65, and 70%. In order to study the water permeation through the semi permeable membrane, a simple mass transfer mathematical models based on Fick’s and Van’t Hoff laws were applied. Generally, higher temperature and osmotic solution concentration, higher water permeation rate was achieved. The results also showed that osmotic dehydration has the same identity or characteristic as drying process at high temperature. The water removal from product slices into the osmotic solution increased by the increase of osmotic period. The mass transfer coefficient and effective diffusivity of water increased when temperature and osmotic solution concentration were increased. However, the membrane permeability has a special characteristic at the ranges conditions studied.ABSTRAKPengawetan buah dengan pengeringan suhu rendah pada umumnya diawali dengan proses dehidrasi osmosis. Lama waktu osmosis sangat dipengaruhi oleh permeasi air dari bahan ke larutan osmosis. Penelitian ini bertujuan untuk mempelajari proses dehidrasi osmosis dan kecepatan permeasi air dari pepaya ke larutan gula sebagai larutan osmosis melalui membran semipermeabel. Pengaruh suhu dan konsentrasi larutan osmosis terhadap kecepatan permeasi air juga diamati. Suhu osmosis adalah 30, 40, 50, dan 60oC, sedangkan konsentrasi larutan osmosis 55, 60, 65, dan 70%. Untuk mempelajari kecepatan permeasi air melalui membran, digunakan model matematis sederhana berdasar pada hukum Fick’s dan Van’t Hoff. Secara umum hasil pengamatan menunjukkan bahwa semakin tinggi suhu dan konsentrasi larutan osmosis kecepatan permeasi air juga semakin tinggi. Profil dehidrasi osmosis menunjukkan karakteristik yang sama dengan profil proses pengeringan suhu tinggi. Dengan bertambahnya waktu osmosis, air yang berpindah dari potongan pepaya ke dalam larutan osmosis juga semakin banyak. Pemodelan matematis memberikan gambaran bahwa koefisien transfer massa dan difusivitas efektif meningkat dengan naiknya suhu dan konsentrasi larutan osmosis Permeabilitas membran pada bahan menunjukkan karakteristik yang spesifik pada rentang kondisi operasi yang dipelajari.

Pengaruh Kadar Air Umpan dan Rasio C/N pada Produksi Biogas dari Sampah Organik Pasar Zuliyana; Sang Kompiang Wirawan; Wiratni Budhijanto; Rochim Bakti Cahyono
Jurnal Rekayasa Proses Vol 9, No 1 (2015)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Nowadays, Indonesia is facing serious problem related to the rapid generation of municipal solid waste (MSW) and dependence on fossil energy. Converting organic content of MSW into biogas through biological process by mean of anaerobic digester is one of promising proposals to solve the MSW problem. In order to optimize biogas production, this research studies the effect of Total Solid (TS) content and ratio of carbon to nitrogen (C/N) within organic fraction of MSW as raw material for biogas production. The organic fraction of MSW consists of vegetables and fruits waste which originated from traditional market. The experiments using various TS concentrations (10%, 15% and 20%) were conducted in batch reactors. The results showed that TS content of MSW raw material had significant effects on the total volume and CH4 concentration of biogas production. High water content in MSW raw material enhanced the hydrolysis of organic fraction as well as avoided the excessive Volatile Fatty Acid (VFA) concentration which posed the risk of inhibition on the anaerobic process. Based on the results, the TS concentration of 10-15% in the organic MSW would offer an optimum yield of biogas production. In order to examine the effect of C/N ratio, the organic MSW was modified using ZA fertilizer (36, 30, 20 and 10 C/N ratios). The C/N ratios of 20-30 produced high amount biogas and CH4 concentration compared to others. The C/N ratio should be maintained at the optimum value to prevent the accumulation of free ammonia which could cause problems in the anaerobic process. Based on the results, the biogas production from organic MSW would yield the optimum biogas amount and CH4 concentration when the TS concentration and C/N ratio were 10-15% and 20-30, respectively. This outcome would give recommendation on the water addition to the raw organic fraction of MSW and C/N modification when converting the organic fraction of MSW to biogas. Keywords: biogas, C/N ratio, municipal solid waste, total solid. Permasalahan sampah dan ketergantungan akan energi fosil mendorong pemanfaatan sampah organik menjadi biogas. Penelitian ini dilakukan untuk mempelajari pengaruh konsentrasi Total Solid (TS) dan rasio C/N dari sampah kota sebagai bahan baku produksi biogas. Sampah kota berupa sayuran dan buah yang merupakan fraksi organik yang diperoleh dari pasar tradisional dan selanjutnya produksi biogas dilakukan dalam reaktor batch. Konsentrasi TS bahan baku divariasikan menjadi tiga variasi nilai TS yaitu 20%, 15% dan 10%. Konsentrasi TS pada bahan baku digester berpengaruh secara signifikan terhadap jumlah akumulatif biogas yang dihasilkan dan kadar CH4. Diperlukan air dengan jumlah yang optimum untuk mempercepat proses hidrolisis sekaligus mencegah konsentrasi Volatile Fatty Acid (VFA) terlalu tinggi yang beresiko inhibitor dalam sistem anaerob. Pada penelitian ini, untuk jenis sampah sayur/buah, nilai TS yang relatif baik adalah antara 10-15%. Modifikasi nilai rasio karbon terhadap nitrogen (C/N) dilakukan pada bahan baku dengan kadar TS optimum dimana nilai rasio C/N dimodifikasi menjadi 36 (rasio C/N orisinal TS optimum), 30, 20 dan 10. C/N ratio yang lebih rendah daripada nilai orisinalnya dicapai dengan penambahan pupuk ZA. Dalam penelitian ini, rasio C/N antara 20-30 memberikan hasil yang relatif paling baik dibandingkan nilai rasio C/N yang lain. Perlu dijaga agar nilai rasio C/N tidak terlalu rendah yang menyebabkan kinerja sistem anaerob justru lebih buruk. karena akumulasi ammonia bebas yang justru merupakan inhibitor. Berdasarkan hasil yang diperoleh, produksi biogas dari sampah buah dan sayur menunjukkan hasil yang optimum saat kisaran konsentrasi TS 10-15% dan rasio C/N 20-30. Hal ini memberikan rekomendasi jumlah penambahan air dan perlu tidaknya koreksi rasio C/N pada umpan bahan baku saat operasi skala industri. Kata kunci: biogas, rasio C/N, sampah kota, total solid.

PENGARUH RASIO ISOPROPIL ALKOHOL TERHADAP RECOVERY DAN KARAKTERISTIK SERBUK PEKTIN DARI KULIT KAKAO Venitalitya A. S. Augustia; Dian Ika Nugraha; Sang Kompiang Wirawan
Jurnal Teknik Kimia USU Vol 7, No 2 (2018)
Publisher : Universitas Sumatera Utara

Cocoa is a fruit crop which is able to be planted in tropical climate, e.g. Indonesia. Generally, people only take the flesh of cocoa fruit and the peel is removed so that it will increase the volume of waste. The cocoa peel contains useful compounds for food and pharmaceutical industries, such as pectin. Hence, a research to increase the pectin retrieval quality from cocoa peel is needed in order to utilize the useful cocoa waste. Methods used in this research is solid-liquid extraction with water as solvent in the presence of acid (HCl). The process of making pectin powder is done through several steps here: (1) Raw material preparation, (2) Pectin extraction, and (3) Analysis of pectin powder. The extraction process is done at temperature of 70℃ for 90 minutes with the pH of the solvent is 1.5. The variation is done on the ratio of volume of isopropyl alcohol to the retrieved pectin. The result of the research shows that the recovery of pectin is at its peak at 6.50% with the percentage of water at 5,82%, equivalent weight of 6454,5242, metoxyl percentage of 5,76%, galacturonate percentage of 35,45%, and esterification level of 92,31%. The best quality of pectin, determined by the highest value of characterization, is obtained when the ratio of the filtrate to the volume of isopropyl alcohol is 1:1.

PELUANG OLEORESIN JAHE SEBAGAI SUMBER BAHAN BAKU BERKELANJUTAN UNTUK OBAT-OBATAN Jayanudin Jayanudin; Rochmadi Rochmadi; Mohammad Fahrurrozi; Sang Kompiang Wirawan
JURNAL INTEGRASI PROSES VOLUME 8 NOMOR 2 DESEMBER 2019
Publisher : JURNAL INTEGRASI PROSES

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36055/jip.v8i2.6776

Jahe oleoresin adalah produk dari rimpang jahe melalui proses ekstraksi menggunakan pelarut organik. Komponen aktif oleoresin jahe adalah sama dengan rimpang jahe seperti gingerol dan zingiberene sementara shogaol diperoleh dari proses dehidrasi selama penyimpanan dan ekstraksi. Bahan aktif seperti gingerol, shogaol, zingiberene dapat digunakan sebagai antioksidan, antiinflamasi, antimikroba, dan antikanker. Jahe oleoresin memiliki potensi besar untuk dikembangkan sebagai bahan baku alami dan berkelanjutan untuk industri farmasi

Mathematical Modelling of Micronutrient Recovery from Vegetable Oil by Silica-based Adsorption: Vitamin E from Palm Fatty Acid Distillate Ari Diana Susanti; Wahyudi Budi Sediawan; Sang Kompiang Wirawan; Budhijanto Budhijanto
Equilibrium Journal of Chemical Engineering Vol 1, No 1 (2017): Volume 1 No 1 January 2017
Publisher : Program studi Teknik Kimia UNS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/equilibrium.v1i1.40363

Mathematical modelling on kinetics of batch adsorption of vitamin E separation from palm fatty acid distillate (PFAD) has been set-up and then applied for literature experimental data. Since the sizes of adsorbent particles used are usually relatively small, the concentration in the particles is assumed to be uniform. Hence, the adsorption rate is controlled by the rate of solute mass transfer from the bulk fluid to the surface of particles. In this model, the rate of mass transfer is assumed to be proportional to the concentration deviation from the equilibrium state. Meanwhile, the equilibrium models applied were coefficient distribution, Freundlich, and Langmuir with the values of the parameters obtained from literature data. It turned out that the model set-up can quantitatively describe the experimental kinetics data from literature. The value of mass transfer coefficient per unit adsorbent mass (kca) is obtained by curve fitting. It is also observed that the model proposed quantitatively describes the batch adsorption process well. The three equilibrium models applied are suitable for the mathematical modelling. Adjustment of the values of equilibrium isotherm parameters from literature significantly improves the accuracy of the model.

Penentuan Pelarut untuk Adsorpsi Oryzanol dari Minyak Bekatul dengan Investigasi Kromatografi Lapis Tipis (Thin Layer Chromatography) Ari Diana Susanti; Wahyudi Budi Sediawan; Sang Kompiang Wirawan; Budhijanto Budhijanto
Equilibrium Journal of Chemical Engineering Vol 1, No 2 (2017): Volume 1 No 2 July 2017
Publisher : Program studi Teknik Kimia UNS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/equilibrium.v1i2.40424

Oryzanol yang terkandung dalam minyak bekatul mempunyai kekuatan antioksidan lebih tinggi daripada vitamin E dan terbukti mempunyai efek hipokolesteromik sehingga berguna untuk kesehatan jantung dan pembuluh darah. Metode adsorpsi menggunakan adsorben silika merupakan salah satu metode isolasi oryzanol yang menjanjikan. Keberhasilan proses pemungutan oryzanol sangat ditentukan oleh pemilihan pelarut yang digunakan karena oryzanol merupakan senyawa ester sehingga sifatnya mirip dengan sifat trigliserida minyak bekatul yang ingin dipisahkan darinya. Oleh karena itu perlu ditentukan pemodifikasi pelarut sehingga diperoleh campuran pelarut yang cocok untuk proses tersebut. Modifikasi dilakukan terhadap pelarut utama n-heksana dan pemodifikasi potensial yang digunakan adalah etil asetat, diklorometana, kloroform, dan aseton. Performa campuran pelarut diuji menggunakan metode kromatografi lapis tipis (thin layer chromatography - TLC) menggunakan plat TLC silika gel grade 60. Hasil penelitian menunjukkan kombinasi n-heksana/aseton = 85/15 memberikan hasil pemisahan oryzanol terbaik, sedangkan kombinasi n-heksana/etil asetat = 90/10 patut dipertimbangkan apabila elusi secara gradien dipilih dalam proses pemisahan.

Problem Solving of Isopropyl Alcohol – Water Azeotropic Characteristics Using Packed (Natural Zeolite) Bed Adsorber Laras Prasakti; Muhammad Hartono; Pandu Prabowo Jati; Muhammad Fajar Setiaji; Sang Kompiang Wirawan; Hanifrahmawan Sudibyo
ASEAN Journal on Science and Technology for Development Vol. 37 No. 1 (2020): Earth, Water & Fire
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29037/ajstd.611

The adsorption kinetics of water from an azeotropic mixture of isopropyl alcohol and water using chemically activated natural zeolites with and without a binder (starch) was investigated. In addition, an investigation of the compressive strength of zeolite pellets was conducted to ascertain the performance of the adsorbent for long-term operation. Three parameters were applied in the zeolite-making process: the particle size of zeolite (20, 30, 50, and 80 mesh), the sintering temperature (550, 750, and 1,000°C), the compaction pressure (2, 4, and 6 tonnes), and the starch-to-zeolite weight ratio (0, 1:3, 1:5, and 1:7). Initial screenings indicated that the strongest zeolite pellet was 80-mesh zeolite powder (without starch addition) that was compacted using 6 tonnes pressure and was sintered at 750°C. The adsorption tests using the strongest zeolite were conducted in a packed-bed column for three cycles, followed by compressive strength tests on the zeolite pellets after each cycle. According to the experimental data, zeolite pellets made without the addition of starch could adsorb up to 98.4% of the initial water in the mixture. From the four models proposed to describe the kinetics of adsorption of water from the mixture, the Freundlich model turned out to be the best model.

Evaluasi Nilai Difusivitas Ion Kalsium & Magnesium pada Proses "Low Salinity Waterflood" di Batuan Berea Yusmardhany Yusuf; Suryo Purwono; Sang Kompiang Wirawan
Jurnal Rekayasa Proses Vol 11, No 2 (2017)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.28890

In recent years Low Salinity Waterflood (LSW) had been supposed as trusty method to improve oil recovery and the most essential aspect is a alteration of divalent ion concentration in reservoir pore volume as a respon LSW. The objective of this paper are to find divalent diffusivity constant (Ca2+ and Mg2+) in berea sandstone by ionsmass conservation equation along with Atomic Absorption Spectroscopy (AAS) as validation. The study was conducted at 2 berea core having porosity : 0.235 and 0.230 and permeability : 661 mD and 550 mD, we use synthetic formation water accordance to "LN" field property. Experiment was treated by by diluting Ca2+ up to 79% from its original value and by diluting Mg2+ up to 95% from its original value while other ion were maintained fit to their original value. As a result we got difusion constant 0.0620 cm2.min-1 and 0.2667 cm2.min-1for Ca2+ and Mg2+, respectively.ABSTRAKPenelitian mengenai metode low salinity waterflood (LSW) dalam beberapa tahun terakhir mengalami perkembangan yang cukup pesat. Salah satu aspek esensial dalam metode tersebut adalah respon perubahan konsentrasi ion divalent dalam ruang pori reservoir. Penelitan ini bertujuan mencari konstanta difusivitas ion kalsium dan magnesium pada batuan Berea sandstone. Konstanta difusivitas dihitung menggunakan persamaan konservasi massa dan ditinjau secara difusi yang divalidasi oleh atomic absorption spectroscopy (AAS). Penelitian dilakukan pada 2 batuan Berea dengan porositas masing-masing: 661 mD dan 550 mD. Air formasi dibuat secara sintetik sesuai data lapangan "LN". Eksperimen difusivitas Ca2+ dilakukan dengan pengenceran hingga 79% dari konsentrasi awal. Sedangkan eksperimen Mg2+ dilakukan dengan pengenceran hingga 95% dari konsentrasi awal. Sementara itu ion lain diatur tetap sesuai konsentrasi awal. Dari hasil percobaan didapat konstanta difusivitas Ca2+ sebesar 0,0620 cm2/menitdan Mg2+ sebesar 0,2667 cm2/menit.

Co-Authors Afrizal Luthfi Anggara Agus Prasetya Ari Diana Susanti Asdi Restana Aswanti Mindaryani Budhijanto Budhijanto Budhijanto Budhijanto Cahyono, Rochim Bakti Chandra Wahyu Purnomo Daniel Timotius Derek Creaser Derek Creaser Dian Ika Nugraha Dian Ika Nugraha Endang Tri Wahyuni Endhy Kesuma Ernie Ernie Hirofumi Hinode I Made Bendiyasa I Wayan Warmada Ihda Novia Indrajati Ivone Marselina Nugraha Jayanudin Jayanudin Martin Petersson Moh. Fahrurrozi Moh. Fahrurrozi Mohammad Fahrurrozi Muhammad Fajar Setiaji Muhammad Hartono Natalia Anasta Pandu Prabowo Jati Panut Mulyono Prasakti, Laras Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Sayoga Hidayatullah Sudibyo, Hanifrahmawan Suryo Purwono Venitalitya A. S. Augustia Venitalitya A. S. Augustia Wahyudi Budi Sediawan Wahyudi Budi Sediawan Wahyudi Budi Sediawan Wahyudi Budi Sediawan Widra Putri Juwita Wiratni Budhijanto Yusmardhany Yusuf Zuliyana

Title

Found 19 Documents
Search

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Title Search

Found 19 Documents Search

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Title

Found 19 Documents
Search