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Teuku Rihayat

Politeknik Negeri Lhokseumawe

Author-ID : 3858988

Automotive Engineering Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering

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Pembuatan Grafena dengan Metode Reduksi Graphene Oxide Menggunakan Bahan Baku Grafit dan Reduktor Natrium Hipopospit Ratna Sari; Cut Dina Mastura; Teuku Rihayat; Ratni Dewi; Lukman Hakim
Jurnal Serambi Engineering Vol 7, No 2 (2022): April 2022
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v7i2.4211

One of the new materials that has developed recently is graphene. Graphene is a new closed, strongest, and superior material in the world today which is formed from a single layer of carbon atoms which has a hexagonal structure resembling a honeycomb. This study aims to determine the effect of graphite size on the quality of graphene produced using the graphene oxide reduction method. This method uses sodium hypophosphite reductor and oxidizing agent KMnO4, sulfuric acid and hydrogen peroxide. The quality of graphene is observed by looking at the electrical conductivity produced. This study varied the size of the graphite (106 µm, 125 µm, 150 µm, 180 µm dan 250 µm) and the reductor volume variation (3 ml, 5 ml, 7 ml, 9 ml dan 11 ml). The graphene oxide solution was heated in hot water and then filtered, ultrasonically for 3 hours, and in the oven for 6 hours at 80oC. From the results of the electrical conductivity test, the best results were obtained at a graphite size of 106 µm while for the volume of the reductor the best results were at 11 ml. Graphene was characterized using FTIR (Fourier transform infrared) and SEM (scanning electron microscope). The results of the characterization of the powder samples show that there has been a change in the structure of graphite to graphene. The size of the graphite and the volume reducing agent has a significant effect on the graphene’s electrical conductivity.

Modification of polyurethane coating based on palm oil with filler bentonite to improve heat resistant properties Teuku Rihayat; Shafira Riskina; Adi Saputra Ismy
Jurnal POLIMESIN Vol 18, No 1 (2020): Februari
Publisher : Politeknik Negeri Lhokseumawe

This work aims to prepare and characterize polyurethane nanocomposite sequences modified with bentonite as fillers and palm oil as a soft segment component while Toluene Diisocyanate (TDI) was chosen as a hard segment component. Bentonite fillers are needed to provide heat resistance to the polyurethane coating. Morphological, structural and thermal polyurethane nanocomposites are characterized by SEM, FTIR, and TGA. FTIR analysis is the NH urethane group in palm oil polyurethane compounds while the absorption of C=O urethane group widens at 1735 cm-1. While the CH group occurs at absorption wavelengths of 2120-2180 cm-1, adding bentonite (7% by weight) is completely laminated and well dispersed in the form of a mixture of peeling / intercalating layers in the polymer matrix. Polyurethane nanocomposites have a morphology separated by clearer microphase. The resulting thermal stability is higher compared to the addition of bentonite 3 and 5% by weight. Because of its enhanced features, the polymer developed can be considered a material with heat resistance as a coating.

Study on improving thermal and compatibility behavior of gypsum PLA/stearic-lauric acid composite as phase change material Nurhanifa Aidy; Rozanna Dewi; Azhari Azhari; Teuku Rihayat; Aida Safitri; Adi Saputra Ismy
Jurnal POLIMESIN Vol 19, No 2 (2021): Agustus
Publisher : Politeknik Negeri Lhokseumawe

Commercial buildings, one of which is for hospitality, consumes a large amount of energy. The energy needs are generally dominated by lighting systems, domestic hot water systems and air conditioning systems. Energy consumption in commercial buildings and residential use of 35.3% of the total global energy use. The aim of this study is to investigate thermal properties and chemical compatibility of PCM based eutectic fatty acid (lauric-stearic) combined with polylactic acid in the pores of the gypsum that was established using the vacuum impregnation method. The procedure ensures that pla 1.5% and 2% with Lauric-Stearic (LA-SA) are mixed evenly, compared with pure gypsum and LA-SA addition. Based on TGA test specific lauric acid and stearic acid heat analysis was performed in the modulated tga mode between 90.34oC and 369.51oC. The degradation material decreased significantly at -3.404 mg. Sample mixed between Poly lactid acid, eutectic fatty acid and gypsum contain hydroxyl groups with significant absorptions for ft-ir analysis. The bonded oxygen-hydrogen stretching vibrations of lactid acids and gypsum, range between 2000 and 3000 cm-1. Similarly, alcohols exhibit similar shapes at higher wavenumbers ranging from 3230 to 3550 cm-1.

Pla-zno nanocomposite paper for antimicrobial packaging application Teuku Rihayat; Suryani Suryani; Adi Saputra Ismi; Nurhanifa Nurhanifa; Shafira Riskina
Jurnal POLIMESIN Vol 17, No 2 (2019): Agustus
Publisher : Politeknik Negeri Lhokseumawe

Many food packages (plastic wrappers) today cannot be broken down by the environment. therefore, it is necessary to add natural substances that can make the food package decompose and be resistant to contamination with bacteria. Development of biodegradable polymers from renewable sources is highly desirable for food preservation and packaging, provided they can be effective as plastics or paper that are currently used in packaging, protecting food against microbial contamination, physical damage and chemical reactions (eg oxidation). Poly lactic acid (PLA) is one of the natural polymers produced by several bacteria that grow in crops rich in carbohydrates (such as sugar beets, corn and others). This research aims to insert ZnO nanoparticles and chitosan into a plastic layer of PLA (poly lactic acid) which can improve the antibacterial properties of the resulting packaging. The method used in making PLA-ZnO-chitosan nanocomposite is the precipitation method and the heating method. PLA-ZnO nanocomposites were obtained by varying ZnO nanoparticles 0.5% by weight, 2% by weight, and 3.5% by weight. The results obtained in SEM images show that nanoparticles are homogeneously distributed on the plastic surface. Antimicrobial tests show nanocomposites work effectively in deactivating E. coli and S. aureus. where it was found that E. coli was more susceptible to this type of nanocomposite, where there was a reduction of 3.4 logs to 3.5% ZnO loading in the PLA layer.

Isolasi Senyawa Anti Bakteri Geraniol Dari Minyak Sereh Wangi (Citronella Oil) Dengan Menggunakan Distilasi Vakum Uswatun Hasanah; Zulkifli Zulkifli; Teuku Rihayat; Andi Wardana; Cut Nazia N
Jurnal Teknologi Vol 21, No 1 (2021): April 2021
Publisher : Politeknik Negeri Lhokseumawe

This study aims to increase geraniol levels in citronella oil, using vacuum distillation. Geraniol is a compound that has been legalized by IFRA (Fragrance International Association) as a scent compound, so geraniol is a reference to be formulated in the form of Anti-bacterial perfume products, but the levels of geraniol in citronella oil are still very low. This encourages the processing of fragrant citronella oil to be processed, by increasing geraniol levels using vacuum distillation, with variations in pressure: 8,6,4,2,1 mbar, during operating times: 20, 40, and 60 minutes up to FBP ( Final Boiling Point). Samples were analyzed using GC-MS (Gas Chromatography-Mass Spectrometry), FT-IR, refractive index, and bacterial testing. The results showed that the use of low pressure affected increasing geraniol levels. The maximum increase in geraniol content was 80.11% at a pressure of 1 mbar at the Final Boiling Point operation, with a refractive index of 1.501, whereas in the FTIR test there was an intense broad peak in the range 2200-3200 cm-1 especially at 3086.98cm-1 according to the OH hydroxyl polymer group at Geraniol. This study increased geraniol levels from 20.32% to 80.11%.

Co-Authors Adi Saputra Ismi Adi Saputra Ismy Aida Safitri Andi Wardana Azhari Azhari Cut Dina Mastura Cut Nazia N Dewi, Ratni Hanif, Hanif Lukman Hakim Nurhanifa Nurhanifa Ratna Sari Rozanna Dewi Shafira Riskina Suryani, Suryati Uswatun Hasanah Zulkifli Zulkifli

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