Mudasir Mudasir
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281

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Surface Morphology of Fe(III)-Porphyrin Thin Layers as Characterized by Atomic Force Microscopy Utari Utari; Kusumandari Kusumandari; Budi Purnama; Mudasir Mudasir; Kamsul Abraha
Indonesian Journal of Chemistry Vol 16, No 3 (2016)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (356.597 KB) | DOI: 10.22146/ijc.21136


Surface morphology of Fe(III)–porphyrin thin layers was studied using atomic force microscopy. The thin layer samples used in these experiments were deposited by spin coating methods on indium–tin-oxide substrates at room temperature under atmospheric conditions. Variations of thin layer of Fe(III)-porphyrin were done by modifying the rotational speed and the concentration of the solution. The experimental results demonstrated that the Fe(III)–porphyrin layers were observed as discrete nanomolecular islands. Both the number of nano-islands and thickness of the layer increased significantly with increasing concentration. A layer thickness of 15 nm was obtained for low concentrations of 0.00153 M and become 25 nm for dense concentrations of 0.153 M. Conversely, the higher number of islands were deposited on the surface of the substrate at a lower rotational speed.
Preparation and Pb(II) Adsorption Properties of Crosslinked Pectin-Carboxymethyl Chitosan Film Budi Hastuti; Mudasir Mudasir; Dwi Siswanta; Triyono Triyono
Indonesian Journal of Chemistry Vol 15, No 3 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (416.77 KB) | DOI: 10.22146/ijc.21192


A modified pectin has been synthesized by reacting/combining -OH group among pectin and chitosan with BADGE (Bisphenol A diglycidyl ether) crosslinker agent. The structure and morphology of the new material were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and X-ray Diffraction (XRD) analysis. Thermogravimetric studies showed an improvement in thermal characteristic. Adsorption experiments were performed in batch processes; sorption isotherms and kinetics were also studied. The Langmuir and Freundlich adsorption isotherm models were applied to describe the isotherms and isotherm constants for the adsorption of Pb(II) ion onto adsorbent pectin-carboxymethyl chitosan-BADGE (pec-CMC-BADGE). The dynamic study showed that the sorption process followed the second-order kinetic equation. Result indicated also that Pb(II) ion uptake could be well described by the Langmuir and Freundlich adsorption model of pec-CMC-BADGE and CMC with DG° of 25.3 and 23.1 kJ mol-1,respectively, while that of pectin followed Freundlich isotherm with DG° of 16.6 kJ mol-1.
Characterization of Butanediol-Alginate Ester as Candidate of Hemodialysis Membrane Choirul Amri; Mudasir Mudasir; Dwi Siswanta; Roto Roto
Indonesian Journal of Chemistry Vol 15, No 2 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (374.355 KB) | DOI: 10.22146/ijc.21208


An ester of butanediol-alginate has been studied as a possible hemodialysis membrane. With 1,4-butanediol molar ratio of 0.1, 0.5, and 1.0, it showed that the membrane mechanical properties, stability, protein adsorption, platelet adhesion and performance for urea and creatinine clearance are better than that of unmodified alginate. The increase in 1,4-butanediol molar ratio causes hemodialysis ratio to improve, and causes protein adsorption and platelet adhesion at the membrane surface to decrease. In the case of protein adsorption and platelet adhesion, the membrane with the molar ratio of 1.0 has better hemocompatibility properties. In the hemodialysis test for 4 h, using 2.742 mg cm-2 h-1 of urea and 0.058 mg cm-2 h-1 of creatinine flux, this membrane showed that 48.5% of urea and 44.2% of creatinine were cleaned.
PAN-Immobilized PVC-NPOE Membrane for Environmentally Friendly Sensing of Cd(II) Ions Moersilah Moersilah; Dwi Siswanta; Roto Roto; Mudasir Mudasir
Indonesian Journal of Chemistry Vol 17, No 1 (2017)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (351.228 KB) | DOI: 10.22146/ijc.23544


A simple, cheap and environmentally friendly analytical method of Cd(II) in the aqueous system has been developed by immobilization of 1-(2-pyridilazo)-2-naphtol (PAN) in poly vinyl chloride (PVC) matrix and nitrophenyl octyl ether (NPOE) as a plasticizer. Upon contact with Cd(II) in solution, the color of sensor membrane changes from dark yellow to dark red, which is due to the formation of Cd(II)–PAN complex. The best sensing results were obtained at pH 8.0 and λmax 558 nm. The dimension of the proposed sensor membrane was 0.8 cm x 2 cm with a thickness of 0.05 mm, the volume of sample was 2 mL with the Cd(II) concentration range of  0 – 1.2 ppm. The limit of detection of the method was found to be 0.432 + 0.104 ppm, which was reversible. The proposed methods have been applied in the determination of Cd(II) in water samples after addition of internal standard.