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All Journal BERKALA FISIKA Jurnal Spektra
Tuti Susilawati
Departemen Fisika FMIPA Universitas Padjadjaran Jl. Raya Bandung-Sumedang Km. 21 Jatinangor Sumedang 45363
Physics

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SIFAT OPTIK DAN ELEKTRONIK MATERIAL ORGANIK SPIRO-TAD SEBAGAI LAPISAN TRANSPORT HOLE DALAM SEL SURYA ORGANIK Safriani, Lusi; Aprilia, Annisa; Mulyana, Cukup; Susilawati, Tuti
Jurnal Spektra Vol 16, No 3 (2015): Spektra: Jurnal Fisika dan Aplikasinya
Publisher : Jurnal Spektra

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AbstrakSemikonduktor berbasis material organik memiliki berbagai keuntungan dibandingkan dengan semikonduktor berbasis material anorganik yang selama ini dipergunakan dalam berbagai divais optik dan elektronik. Diantara berbagai macam semikonduktor organik, material organik terkonjugasi spiro menarik perhatian karena memiliki sifat optik dan sifat elektronik yang unik yang dihasilkan dari ikatan spiro. Material spiro terdiri dari dua atau lebih molekul yang memiliki sistem-p dengan fungsi yang sama ataupun berbeda melalui hibridisasi atom sp3. Salah satu contoh material spiro adalah 2,2′,7,7′-tetrakis(diphenylamino)-9,9′-spirobifluorene (spiro-TAD) yang digunakan sebagai lapisan transport hole dalam divais elektronik organic light emitting diode (OLED). Dalam makalah ini dilakukan kajian untuk menentukan sifat optik dari material spiro-TAD melalui pengukuran transparansi/absorbsi pada daerah UV-Vis dan sifat elektronik melalui pengukuran emisi untuk menentukan celah energi dari spiro-TAD. Hasil pengukuran absorbsi menunjukkan bahwa spiro-TAD memiliki puncak absorbsi pada panjang gelombang 415 nm, sedangkan dari hasil pengukuran emisi diperoleh celah energi spiro-TAD adalah 2.98 eV. AbstractSemiconductor-based organic material has various advantages compared to semiconductor-based inorganic material that has been used in optoelectronic devices. One of organic semiconductors, that is spiro conjugated material attracted much attention because it has an optical and unique electronic properties resulting from spiro bond. Spiro material consists of two or more molecules that have system-p with the same or different functions through atomic sp3 hybridization. One example of spiro material is 2,2 , 7,7-tetrakis (diphenylamino) -9,9-spirobifluorene (spiro-TAD) which is used as hole transport layer in organic light emitting diode (OLED). This paper discussed the optical property of spiro-TAD by measuring transparency/absorption in UV-Vis region and electronic property by measuring emission spectra to determine bandgap of spiro-TAD. Absorbtion spectrum of spiro-TAD shows a maximum peak at 415 nm, while from emission spectra it was found that spiro-TAD has bandgap 2.98 eV.Keywords: OLED, spiro-TAD, hole transport layer
STUDI KOROSIVITAS DAN MORFOLOGI PERMUKAAN BAJA KARBON API 5L GR-B YANG DILAPISI POLIMER HIBRID PADA LINGKUNGAN AIR LAUT DAN GAS H2S PADA KONDISI JENUH CO2 Setiawidiani, Dinar; Susilawati, Tuti; Suryaningsih, Sri; Harjo, Hardoyo
BERKALA FISIKA 2014: Berkala Fisika Vol. 17 No. 2 Tahun 2014
Publisher : BERKALA FISIKA

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It has been tested with the corrosion protection of carbon steel using hybrid inorganic - organic polymer. Hybrid polymer precursor materials is synthesized from monomers poly (TMSPMA) using sol- gel technique. The hybrid polymer precursors coated on the surface of carbon steel API 5L GR - B, and then thermally polymerized. Corrosion test conducted in a seawater environment, H2S, CO2 saturation using potentiodynamic polarization method and morphological examination using a Scanning Electron Microscope. The obtained results shows the corrosion rate of carbon steel without coating in critical condition was 1.643 mm/year. Once the hybrid polymer coated carbon steel with a corrosion rate becomes 0.903 mm/year. The corrosion rate was reduced to 0.74 mm/year. Corrosion rate is related to the protection efficiency of 45.05%. These results are supported by data that shows the surface morphology uneven corrosion on carbon steel surface after coated with polymer hybrid. Keywords : corrosion , carbon steel , polymer hybrid , potentiodynamic polarization
Co-Authors Afifah Nurida, Afifah Annisa Aprilia Ayi Bahtiar Ayunita Chintia, Ayunita Cukup Mulyana Dinar Setiawidiani Hardoyo Harjo Lusi Safriani MARIA OKTAVIANI, MARIA RISDIANA RISDIANA, RISDIANA SATRIA AUFFA D U, SATRIA AUFFA Sheila Sakkyananda, Sheila Sri Suryaningsih Togar Saragi, Togar YONATAN R PURBA, YONATAN R