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Studi Adsorpsi Sianida dari Tailings Pengolahan Emas dengan Metode Resin-In-Pulp Ninik Lintang E.W.; Cut Shafira; Palguno Helyoso
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2016: Prosiding SNTKK 2016
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Cyanidation is an efficient and inexpensive gold extracting process from ore, allowing gold recovery from low-grade ore carried out economically. The disadvantage of cyanidation process is the generation of highly toxic cyanide-containing tailings. Such tailings need to be treated prior to disposal, in order to comply with environmental requirements. There are two methods to overcome cyanide-containing tailing, by recycling and recovery. Cyanide recovery will eliminate the cyanide destruction cost and will reduce fresh cyanide purchasing cost. Cyanide adsorption (as part of Hannah Process) has been studied using batch adsorption techniques, to examine the contact time, adsorbent dose, and maximum adsorption capacity of Lewatit U-SO4 resin for cyanide removal. Results revealed that adsorption rate initially increased rapidly, and the optimum removal efficiency was reached within two hours. Further increase in contact time did not show significant change in equilibrium concentration; that means, the adsorption has reached equilibrium. The adsorption isotherms could be fitted well by the Langmuir model. The  RLvalue in the investigation was less than one, indicating that the adsorption of cyanide onto the  resin is favorable. The resin optimum dose was 44 g/L and  the maximum capacity was20 mg CN/g resin, equivalent to 0.846eq/L resin. 
THE EFFECT OF SULFURIC ACID CONCENTRATION ON NICKEL RECOVERY FROM LATERITE ORE BY USING ATMOSPHERIC ACID LEACHING METHOD Althafa Muntaqin; Lutfiah Rahmasari; Ninik Lintang Edi Wahyuni; Rony Pasonang Sihombing
Jurnal Kimia Riset Vol. 7 No. 1 (2022): June
Publisher : Universitas Airlangga, Campus C Mulyorejo, Surabaya, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20473/jkr.v7i1.35712

Abstract

The processing of laterite ore by pyrometallurgy requires high temperatures whereas the Atmospheric Acid Leaching (AAL) method can be performed below 100 ℃ although its nickel recovery is inconsistent. This research aims to determine the effect of sulfuric acid concentration on nickel recovery and to determine nickel recovery after extract purification by precipitation of non-nickel metals. AAL was performed with an operating temperature of 95 °C, an operating time of 5 hours, an ore-to-solvent ratio of 0.05 g/ml, a particle size of ± 200 mesh, and sulfuric acid concentration variation of 0.2–1 M. Iron precipitation was completed with a pH variation of 0.5–3.8 by the addition of ammonia. The result showed that the concentration of sulfuric acid increased nickel recovery. The nickel recovery reached 96.43% at a concentration of sulfuric acid of 1 M. Furthermore, after extract purification, nickel recovery reached 50.61%, which was achieved at an optimum pH of 3.2.
Effect of Process Variables and Zeolite Adsorbent in Coffee Bean Drying Bambang Soeswanto; Ninik Lintang Edi Wahyuni; Ghusrina Prihandini; Yusuf Pratama; Taufik Akbar Firmansyah; Dewi Widyabudiningsih
Jurnal Internasional Penelitian Teknologi Terapan Vol 4 No 1 (2023): April 2023
Publisher : Bandung State Polytechnic (Politeknik Negeri Bandung)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35313/ijatr.v4i1.100

Abstract

Green coffee beans to be stored for transportation must meet storage quality standards, especially the maximum moisture content of 12.5%, so the drying process must be carried out to achieve quality standards, but still economical. The study aims to obtain optimum operating conditions on the drying of Arabica-type coffee beans using a fluidized bed dryer assisted by zeolite adsorbents in a separated fluidized bed prior to heating, as well as calculating the energy consumption of blowers and air heater. The operating conditions were varied, namely air flow rate of 1.79 – 2.29 m/s, air temperature of 45 o C, 50 o C, and 55 o C, zeolite adsorbent mass of 150 g, 175 g, and 200 g. The coffee beans quality tests carried out were the moisture, carbohydrates, protein content, and the visual appearance of the beans. The results show that the optimum drying process of coffee beans resulting a minimum protein and carbohydrate damage are the air velocity of 2.1 m/s, air temperature of 55°C, drying time of 240 minutes, and zeolite adsorbent mass of 150 grams, with energy consumption of 5.02 KWH (equivalent to 180 MJ/T). The addition of zeolite as much as 150 grams, 175 grams, and 200 grams as adsorbent was able to reduce the relative humidity (RH) of air by 16.65%, 18.60%, and 21.17% respectively. The drying rate of coffee beans is mainly influenced by air temperature (more predominantly) than the adsorption of air humidity by zeolite.
Laju Korosi Logam Baja Karbon Rendah di Larutan Garam pada Berbagai Konsentrasi Inhibitor Korosi dari Ekstrak Daun Pepaya: Low Carbon Steel Metal Corrosion Rate in Salt Solution at Various Concentrations of Corrosion Inhibitor from Papaya Leaf Extract Ninik Lintang Edi Wahyuni; Rony Pasonang Sihombing; Nurcahyo; Agustinus Ngatin; Yunus Tonapa Sarungu; Alfiana Adhitasari; Bambang Soeswanto; Emma Hermawati Muhari; retno indarti
KOVALEN: Jurnal Riset Kimia Vol. 9 No. 2 (2023): August Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2023.v9.i2.16344

Abstract

Papaya leaf extract could be used as an organic corrosion inhibitor. Corrosion inhibitors were used as a method to reduce corrosion rate. The most corrosive environment was the marine environment. The purpose of this study was to determine the best concentration of papaya (Carica papaya) leaf extract inhibitor which could reduce the corrosion rate of low carbon steel in a 3.56% NaCl solution environment. The maceration process was carried out for 24 hours with 70% ethanol solvent with a solute:solvent ratio of 1:8 (w/v) at room temperature. Inhibitor extracts were analyzed qualitatively with the phytochemical method. The addition of FeCl3 was carried out on the inhibitor extract from papaya leaves. The color change occurred from blackish brown to greenish black which indicated the presence of tannin compounds in the papaya leaf extract. Corrosion testing was carried out with hot stream temperature setting at 45⁰C to 55⁰C and concentrations of inhibitor extracts at 300, 600, and 900 ppm. The test was conducted for 36 hours with a span of metal mass every 6 hours. Corrosion rate calculation is done by weight loss method. The results showed that papaya leaf extract inhibitors positive contained corrosion inhibitor and could reduce the corrosion rate in 3.56% NaCl solution. The corrosion rate without inhibitor is 1.023 mmpy. Corrosion rates with inhibitor concentrations of 300, 600, and 900 ppm were 0.755, 0.585, and 0.438 mmpy, respectively.
Pengolahan Air Limbah Tahu Menggunakan Metode Elektrokoagulasi dan Adsorpsi Secara Kontinyu: Tofu Wastewater Treatment Using Continuous Electrocoagulation and Adsorption Method Ninik Lintang Edi Wahyuni; Nurcahyo; Unung Leoanggraini; Robby Sudarman; Bambang Soeswanto; Emma Hermawati Muhari; Agustinus Ngatin; Rony Pasonang Sihombing
KOVALEN: Jurnal Riset Kimia Vol. 9 No. 2 (2023): August Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2023.v9.i2.16446

Abstract

Tofu wastewater contains a lot of protein therefore it is easily degraded to produce foul odors and harmful gases due to microbes. Protein levels can be reduced through the electrocoagulation method which is equipped with adsorption. The purpose of this study is to reduce the value of turbidity, TSS, and COD in tofu wastewater due to the influence of voltage in the electrocoagulation process which is equipped with an adsorption process. This research was conducted with an electrocoagulation process at a rate of 250L/min with voltage variations of 15, 20, and 24Volt in a 10L tank containing 3 pairs of aluminum (Al) electrodes connected with direct current. The output water from the electrocoagulation process flows into the settling basin and flows into the adsorption tank containing activated carbon adsorbent. Both of these continuous processes were the innovation of this research. Sampling was conducted every 10 minutes for analysis of turbidity, TSS, COD, and pH. The results of the output water analysis from the electrocoagulation process after passing through the precipitation and adsorption processes show that increasing the voltage results in the decrease of turbidity, TSS, and COD values, however, increased efficiency and pH. Thus, a voltage of 24V with a flow rate of 250mL/min resulted in the highest efficiency of the voltage variations (15, 20, and 24V) with a process time of 90 minutes with a turbidity impurity reduction efficiency value of 45.42% with a value of 41.36 NTU from 75.22NTU, TSS 91.42% with a decrease to 1827mg/L from 21288mg/L, and COD 55.56% with a COD value of 9600mg/L from 21600mg/L, and a process output water pH of 4.91, as well as a reduction in aluminum electrode weight of 1.024grams.