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A Comparison of the Utilization of Carbon Nanopowder and Activated Carbon as Counter Electrode for Monolithic Dye-Sensitized Solar Cells (DSSC) Hidayat, Jojo; Tahir, Dahlang; Shobih, Shobih; Nursam, Natalita Maulani; Mubarak, Zaky
Jurnal Elektronika dan Telekomunikasi Vol 18, No 1 (2018)
Publisher : Indonesian Institute of Sciences

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14203/jet.v18.15-20

Abstract

Monolithic design is one of the most promising dye-sensitized solar cell (DSSC) architectures to develop, because it allows the elimination of one conductive substrate and offers the possibility for printing layer-by-layer of the materials that made up its structure. In this study, titanium dioxide-based monolithic type DSSCs were fabricated on a single fluorine-doped transparent oxide coated glass with TiO2 as photoanode and porous ZrO2 as spacer. The type of the carbon material used as the composite paste for the counter electrode was varied to see the effect on the solar cell efficiency. Four-point probes measurement revealed that the resistivity of the carbon layer synthesized using activated carbon exhibited slightly higher conductivity with a sheet resistance of 10.70 Ω/sq and 11.09 Ω/sq for activated carbon and carbon nanopowder, respectively. The efficiency of DSSC that uses activated carbon as counter electrode was higher (i.e. 0.221%) than the DSSC with carbon nanopowder (i.e. 0.005%). The better performance of DSSC with activated carbon as a counter electrode was due to its better conductivity and higher surface area compared to those of carbon nanopowder.
Analysis of Thermal Treatment Zirconia as Spacer Layer on Dye-Sensitized Solar Cell (DSSC) Performance with Monolithic Structure Tahir, Dahlang; Hidayat, Jojo; Shobih, Shobih; Rosa, Erlyta Septa; Anwar, Chairil
Jurnal Elektronika dan Telekomunikasi Vol 18, No 1 (2018)
Publisher : Indonesian Institute of Sciences

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14203/jet.v18.21-26

Abstract

Monolithic dye-sensitized solar cells (DSSC) offer the prospect of lower material cost and require a simpler manufacturing process compared with conventional DSSC. Fabricated on a single fluorine tin oxide (FTO) glass substrate consists of a nanoporous TiO2 photoanode layer, a ZrO2 spacer layer, a carbon counter electrode layer, a dye, and an electrolyte. The spacer layer on the monolithic DSSC serves as electrolyte storage and insulating layer to separate between photoanode and counter electrode. Zirconia is often used as a spacer because it has high temperature resistant properties, high dielectric constant and adhesive as an insulator that has band gap between 5-6 eV. The effects of the thermal treatment of zirconia layer as a spacer electrolyte on the performance of monolithic DSSC have been investigated. The cell’s performance increases with the sintering temperature as well as indicated by the decreased in particle size and increased in quantum efficiency in the absorption region of the titania layer. Co-sintering treatment tends to drastically reduce cell’s performance. The highest performance was obtained at a temperature sintering of 500o C with an PCE of 0.22%, Isc = 0.16 mA and Voc = 0.71 V.
Effect of Geometrical Structure to the Performance of Monolithic Dye–Sensitized Solar Cells Hidayat, Jojo; Shobih, Shobih; Nugraha, Bayu Aditya; Tahir, Dahlang
Jurnal Elektronika dan Telekomunikasi Vol 18, No 2 (2018)
Publisher : Indonesian Institute of Sciences

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14203/jet.v18.53-59

Abstract

Since invented for the first time, researchers in the world were focusing on how to increase the efficiency of dye-sensitized solar cells (DSSC) and reduce of the fabrication cost. Monolithic type of DSSC is one of the best solutions to reduce the fabrication cost due to the elimination of one of transparent conductive oxide (TCO) substrate. In this study, DSSC monolithic was fabricated layer by layer by using screen printing method. There are three layers that printed in each cell namely TiO2, ZrO2, and carbon before being injected with electrolytes. The geometrical structure of DSSC was varied to find the highest performance. From the I-V characteristics and incident photon-to-current efficiency (IPCE) characterization shows the highest efficiency is 0.137% and the highest conversion of photons to current occurs at around 510 nm wavelength, for a structure which has ZrO­2 layer not crosses over the no-FTO area, while TiO2 layer half crosses the no-FTO area, this is most likely caused by the imperfection of the ZrO2layer.
Analysis Optical Properties of Carbon Dots from Paper Flowers (Bougainvillea spectabilis) Ramlan, Nurul Mutmainnah; A'yun, Arini Qurrata; Putri, Radha Hartina; Fatimah, Siti; Isnaeni, .; Tahir, Dahlang
Omega: Jurnal Fisika dan Pendidikan Fisika Vol 4 No 2 (2018)
Publisher : Program Studi Pendidikan Fisika UHAMKA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31758/OmegaJPhysPhysEduc.v4i2.30

Abstract

Synthesized carbon dots (CDs) from paper flowers (Bougainvillea spectabilis) was performed by microwave assisted. CDs were characterized by ultraviolet visible light (UV-Vis), photoluminescence (PL) and time resolved luminescence (TRPL). PL data shows wavelength intensity of CDs paper flowers at 493 nm for 3.9 ns and 512 nm for 4.2 ns respectively for purple and white paper flowers that excited at 420 nm. The absorbance for CDs white paper flower at 262 nm and 350 nm, while CDs purple flower paper at 260 nm, 324 nm, and 530 nm. CDs from paper flower shows excellent optical properties. So, it is mean that method applied to this experiment effectively, cheap and eco-friendly for synthesis CDs from paper flower.
Sintesis Komposit ZnO/Ca3(PO4)2 menggunakan metode Sol-gel sebagai Material Fotokatalis Limbah Cair Industri (Metilen Biru) Nurul Fajri R Tang; Dahlang Tahir; Heryanto Heryanto
Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat Vol 19, No 1 (2022): Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat
Publisher : Lambung Mangkurat University Press

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1191.841 KB) | DOI: 10.20527/flux.v19i1.11824

Abstract

This study use composite ZnO/Ca3(PO4)2 material was synthesized by using the sol-gel method. Composite material ZnO/Ca3(PO4)2 is made from beef tailbone which is heated at a temperature of 300  for 10, 90, 120, and 240 minutes. Samples were characterized using X-ray diffraction ( XRD ), Fourier transforms infrared ( FTIR ) dan UV - Visible ( UV-Vis ). Quantitative analysis of XRD spectra showed the lowest crystal size with a diameter of 21.71 nm on heating for 90 m. The results of the FTIR spectrum show the vibration of the PO4 and ZnO bond at wavenumber 1039 cm-1 and 400-500 cm-1. The best percentage of degradation is indicated by small crystal size and high infrared absorption by O-H bonds. The degradation results reached 93.98% in just 5 minutes with an energy gap of 3.84 eV. Based on these results, the ZnO/Ca3(PO4)2 composite is one of the promising and potential catalyst materials to solve the problem of industrial waste pollution, especially methylene blue.
Evaluasi Tingkat Kebisingan Pada SMK Darussalam Makassar: (Evaluation of Noise Level at SMK Darussalam Makassar) Hamsi, Taufik; Rauf, Nurlaela; Tahir, Dahlang
Gravitasi Vol. 20 No. 1 (2021):
Publisher : Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/gravitasi.v20i1.15526

Abstract

Penelitian mengenai tingkat kebisingan di SMK Darussalam Makassar menggunakan alat sound level meter. Tingkat kebisingan di ukur di 5 titik. Pada penelitian ini aspek yang dianalisis adalah tingkat polusi bising dan hubungannya dengan jumlah kendaraan yang melintas di depan sekolah. Secara umum kebisingan di SMK Darussalam Makassar berada pada level dapat di terima sampai tidak dapat di terima dengan nilai berkisar 54,6 dB – 88,1 dB. Semakin kedalam letak titik pengukuran kebisingan di SMK Darussalam, maka semakin rendah pula tingkat kebisingan yang terjadi.
Radon (222Rn) Radioactivity Level at the BATAN Workplace using RAD7 Arsita sita; Dahlang Tahir; June Mellawati; R Pradana
Jurnal Ilmiah Aplikasi Isotop dan Radiasi Vol 16, No 2 (2020): Desember 2020
Publisher : BATAN

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17146/jair.2020.16.2.6000

Abstract

Measurement of Radon (222Rn) radioactivity level at BATAN office Jakarta has been done. Radon is a radioactive emitting alpha particle, very dangerous to the health because if it is inhaled, will be accumulated in the lungs and cause lung cancer. The purpose of the research was to determine the activity concentration of 222Rn in the workplace and to estimate the dose received by workers. The sampling method is purposive sampling, in several office rooms of the BATAN office (staff room, laboratory, and warehouse), measurement 222Rn using RAD7 continuously for 24 hours. Based on the activity concentration of 222Rn in the rooms, an estimate of the effective dose received by the workers while working indoors can be calculated. The results showed that exposure of 222Rn gas radiation in the workplace was relatively varied, radiation exposure in warehouses was 18.90-32.90 (25.90) Bq.m-3 higher than in laboratory 8.20-34.00 (22.43) Bq.m-3 and staff room 5.40-29.60 (16.68) Bq.m-3. The estimated effective dose received by workers in the warehouse is 0.1865 mSv.year-1, laboratory 0.1615 mSv.year-1, and in the staff rooms 0.1267 mSv.year-1, and this value still meets the quality standards of radiation exposure required by the Ministry of Health No. 7 of 2019 and is categorized as safe.
Studi Uji Kesesuaian Selisih Lapangan Kolimasi pada Pesawat Mammografi Analog dan Digital Fitriani Fitriani; Bualkar Abdullah; Dahlang Tahir
Jurnal Fisika FLUX Vol 16, No 2 (2019): Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat
Publisher : Lambung Mangkurat University Press

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (97.957 KB) | DOI: 10.20527/flux.v16i2.6344

Abstract

Study of collimation field difference suitability test on analog and digital mammography at leading hospital in Makassar from 2016-2018. This test was carried out by using four coins of the same size placed on the edge of the collimator lamp field, one different size coin was placed on the table edge of the chest wall section, and one coin was placed on the surface under the compression pedal to coincide with the edge of the chest wall. The results of the p value obtained for each measurement point, both for the difference of the light collimation field toward the X-ray beam and the difference of X-ray beam collimation field toward image receptor have the same value of 0.000 (p < 0.05). This value states that there are significant differences in the collimation field difference from 2016-2018. The results of collimation field difference suitability test on analog and digital mammography are still within the tolerance limits recommended by BAPETEN, for the difference of the light collimation field toward X-ray beam ≤ 1% SID and the difference of X-ray beam collimation field toward image receptor ≤ 2% SID. This shows that mammography is feasible and able to operate safely for patients and non-patients.
Pembuatan Prototipe Dye Sensitized Solar Cell (DSSC) Menggunakan Antosianin Dari Dye Bunga Kenikir (Cosmos Caudatus L.) dan Bunga Zinnia ( Zinnia Peruviana) Eunike Dwioknain; Hardianti Hardianti; Dahlang Tahir; Paulus Lobo Gareso
Jurnal Fisika FLUX Vol 16, No 1 (2019): Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat
Publisher : Lambung Mangkurat University Press

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1112.492 KB) | DOI: 10.20527/flux.v16i1.4967

Abstract

Prototype dye sensitized solar sel (DSSC) menggunakan antosianin dari bunga Kenikir (Cosmos Cudatus L.) dan bunga Zinnia (Zinnia Peruviana) untuk pertama kalinya telah di fabrikasi. Prototype DSSC dibuat dalam bentuk struktur sandwich, dengan menggunakan metode spin coating untuk deposisi lapisan TiO2., Kemudian dikarakterisasi  menggunakan XRD yang menunjukkan Kristal TiO2 berada pada fase anatase, dengan ukuran Kristal sebesar 37,99 nm menggunakan persamaan Debye Scherrer dan 30,10  nm menggunakan metode UDM. Hasil spektrum UV-Vis dalam rentang 300 nm - 800 nm, memperlihatkan absorbansi masing-masing untuk dye bunga Zinnia, bunga Kenikir, dan dye campuran adalah 331 nm; 328 nm; 327 nm. Hasil FTIR menunjukkan adanya senyawa antosianin pada bahan dye yang ditunjukkan dengan adanya ikatan senyawa flavonol, karboksil dan hikdroksil. Keluaran yang di hasilkan dari prototype DSSC berupa arus dan tegangan yang kemudian di akumulasi untuk menghitung efisiensi  DSSC. Efisiensi DSSC sebesar 0,0193 % pada dye bunga Zinnia dengan lama perendaman 66 jam. Efisiensi dari DSSC yang terbaik adalah dye dari bunga Zinnia bila dibandingkan dengan bunga Kenikir dan  campuran dye dari bunga Kenikir dan bunga Zinnia.
Fabrikasi Bahan Penyerap Gelombang Elektromagnetik Berbasis CuC Hendri Hendri; Bualkar Abdullah; Dahlang Tahir
Jurnal Fisika FLUX Vol 15, No 2 (2018): Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat
Publisher : Lambung Mangkurat University Press

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1194.057 KB) | DOI: 10.20527/flux.v15i2.4903

Abstract

Fabrikasi bahan penyerap gelombang elektromagnetik berbasis CuC telah dilakukan. Tembaga Karbon (CuC) diolah dengan metode kompaksi/pemadatan, karakterisasi dilakukan dengan menggunakan XRD, FTIR dan VNA. Penyerap gelombang elektromagnetik (reflection loss (RL)) diperoleh pada rentang -17,73 dB hingga -24,94 dB. Nilai RL dipengaruhi oleh konsentrasi karbon aktif (AC). Spectrum RL terbaik diperoleh pada frekuensi 4 GHz – 5 GHz.