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All Journal Seminar Nasional Teknik Kimia Kejuangan Journal of Engineering and Technological Sciences
Yogi Wibisono Budhi
Research Group of Chemical Engineering Process Design and Development, Faculty of Industrial Technology, Institut Teknologi Bandung
Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Engineering Environmental Science

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Determination of Kinetic Parameters for Methane Oxidation over Pt/γ-Al2O3 in a Fixed-Bed Reactor Wonoputri, Vita; Effendy, Mohammad; Budhi, Yogi Wibisono; Bindar, Yazid; Subagjo, S.
Journal of Engineering and Technological Sciences Vol 45, No 2 (2013)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (518.085 KB) | DOI: 10.5614/j.eng.technol.sci.2013.45.2.7

Abstract

This paper describes akinetic study for the determination of the kinetic parameters of lean methane emission oxidation over Pt/γ-Al2O3 in a dedicated laboratory scale fixed bed reactor. A model ofthemechanistic reaction kinetic parameters has been developed. The reaction rate model was determined using therate-limiting step method, which was integrated and optimized to find the most suitable model and parameters. Based on this study, the Langmuir-Hinshelwood reaction rate model with the best correlationis the one where the rate-limiting step is thesurface reaction between methane and one adsorbed oxygen atom. The pre-exponential factor and activation energy were 9.19 x 105 and 92.04 kJ/mol, while the methane and oxygen adsorption entropy and enthalpy were –17.46 J/mol.K, –2739.36 J/mol,–16.34 J/mol.K, and –6157.09 J/mol, respectively.
Homogeneity of Continuum Model of an Unsteady State Fixed Bed Reactor for Lean CH4 Oxidation Subagjo, S.; Budhi, Yogi Wibisono; Effendy, M.; Bindar, Yazid
Journal of Engineering and Technological Sciences Vol 46, No 2 (2014)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (479.426 KB) | DOI: 10.5614/j.eng.technol.sci.2014.46.2.6

Abstract

In this study, the homogeneity of the continuum model of a fixed bed reactor operated in steady state and unsteady state systems for lean CH4 oxidation is investigated. The steady-state fixed bed reactor system was operated under once-through direction, while the unsteady-state fixed bed reactor system was operated under flow reversal. The governing equations consisting of mass and energy balances were solved using the FlexPDE software package, version 6. The model selection is indispensable for an effective calculation since the simulation of a reverse flow reactor is time-consuming. The homogeneous and heterogeneous models for steady state operation gave similar conversions and temperature profiles, with a deviation of 0.12 to 0.14%. For reverse flow operation, the deviations of the continuum models of thepseudo-homogeneous and heterogeneous models were in the range of 25-65%. It is suggested that pseudo-homogeneous models can be applied to steady state systems, whereas heterogeneous models have to be applied to unsteady state systems.
Axial Inlet Geometry Effects on the Flow Structures in a Cyclone Burner Related to the Combustion Performance of Biomass Particles Pasymi, P.; Budhi, Yogi Wibisono; Bindar, Yazid
Journal of Engineering and Technological Sciences Vol 50, No 5 (2018)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1675.528 KB) | DOI: 10.5614/j.eng.technol.sci.2018.50.5.7

Abstract

Solid fuel combustion is always preceded by chemical decomposition. This process is largely determined by the flow structure and affected by the geometry and operating conditions of the combustion chamber. This study aimed to investigate the effect of relative axial inlet diameter (Dai//Dbc) on the flow structure in the proposed cyclone burner. The flow structure was determined with the standard k-e turbulent model using the Ansys-Fluent software. From the simulation results it was concluded that with all the axial inlet diameters used an integrated vortex formed in the center of the burner cylinder. The integrated vortex consisted of two vortices, namely a primary vortex and a secondary vortex. The primary vortex penetrated from the furnace box to the burner cylinder, while the secondary vortex was formed in the burner cylinder itself. There were two integration patterns from the primary vortex and the secondary vortex, namely a summation pattern and a multilayer pattern. The presence of a vortex in the center of the burner cylinder is allegedly responsible for an increase in the degree of mixing and pressure drop in that zone. The flow structure induced from the proposed burner had high symmetricity and was largely determined by the burner’s axial inlet diameter.
Intensifikasi Proses dalam Sistem Reaksi dan Pemisahan Dinamik Yogi Wibisono Budhi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2020: PROSIDING SNTKK 2020
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Co-Authors M. Effendy Mohammad Effendy Pasymi, P. S. Subagjo S. Subagjo Vita Wonoputri Yazid Bindar