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STUDI ab-initio MEKANISME PEMBENTUKAN TRANSISI REAKSI OKSIDASI CO OLEH NO2 DI UDARA Beri, Deski
Sainstek : Jurnal Sains dan Teknologi Vol 4, No 2 (2012)
Publisher : IAIN Batusangkar

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (616.889 KB) | DOI: 10.31958/js.v4i2.64

Abstract

The transition state formation?s mechanism of CO oxidation reaction by molecule of NO2 has been done using ab-initio computation by Density Functional Theory (DFT). Geometry optimation was done by B3LYP and 6-31G* basis set using HyperGauss and HyperDFT computer software. The result is we hypothese that there was three transition state takes place, therewere trans-Transition State (KTt), cis-Transition State (KTc) and cyclic-Transition State (KTs). All of three was gradually takes place in a very short time intervals. Keywords: density functional theory (DFT), geometry optimation, intermediate, transition state 
Sintesis Keramik Refraktori Al2O3.MnO2.SiO2 Dengan Metoda Sol-Gel dan Sifat Fisikanya Dalam Berbagai Temperatur Kalsinasi Rahmi Muthia; Deski Beri; Ali Amran
Jurnal Periodic Jurusan Kimia UNP Vol 2, No 1 (2013)
Publisher : Departemen Kimia FMIPA UNP

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (280.816 KB) | DOI: 10.24036/p.v2i1.1934

Abstract

Ceramic oxide Al2O3.MnO2.SiO2 ceramics has relatively high strength, tough electrical capacitance and temperature resistant. It’s synthesized by sol-gel methods using raw materials Tetraethyl Orthosilicates (TEOS), Al (NO3) 3.9H2O and Mn (NO3) 2.4H2O with calcination temperature variation of 900-1100oC. XRD (X-Ray Diffraction) analysis of ceramic Al2O3.MnO2.SiO2 showes peak °2Th=33.2875 intensity relatif=100%, °2Th=55.8688 intensity relatif 24,28%,°2Th=26.1289 intensity relatif 13,22%,°2Th=66.4815 intensity relatif 12,84%,°2Th=35.4375 intensity relatif 11,39%. Ceramic Al2O3.MnO2.SiO2 morphology by SEM (Scanning ElectronMicroscopy) showed that the ceramic at a temperature of 1100oC was homogeneous microscopic. Capacity as measured by the LCR meter instrument empirical equation F (C, T) = 0.01625 T - 11.0833 can be explained that the higher the calcination temperature the higher the value of the capacitor capacity.
Degradation of Methyl Green Dyes with ZnO Catalyst using the Photosonolysis Method Muhammad Gani Ariski; Hary Sanjaya; Alizar Alizar; Deski Beri; Yohandri Yohandri
Jurnal Periodic Jurusan Kimia UNP Vol 11, No 2 (2022): PERIODIC
Publisher : Departemen Kimia FMIPA UNP

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1352.044 KB) | DOI: 10.24036/p.v11i2.113614

Abstract

Textile and dyestuff industrial dye waste remain the most difficult wastewater to treat due to the complex aromatic molecular structure of industrial dyes, which are very difficult to decompose. This research was conducted on the degradation of methyl green using the photosonolysis method. The purpose of this study was to determine the optimum time and amount of ZnO used in degrading methyl green dye. The results of the percentage degradation were obtained from the absorbance value measured using a UV-Vis Spectrophotometer. (λmax) Methyl green obtained from the measurement of a UV-Vis spectrophotometer was 640 nm. The results showed that the optimum irradiation and sonication time to degrade methyl green was 60 minutes with a degradation percentage of 92.77%. For the effect of mass variation of ZnO catalyst obtained the optimum mass of 0.05 grams with a degradation percentage of 96.38%.
Pengaruh Penambahan Konsentrasi (NH2)2CO Terhadap Karakteristik TiO2 dan Aktifitas Fotokatalitiknya Dalam Mendegradasi Methylene Blue Novera Elsi Mudia; Rahadian Zainul; Deski Beri; Syamsi Aini
Jurnal Periodic Jurusan Kimia UNP Vol 11, No 2 (2022): PERIODIC
Publisher : Departemen Kimia FMIPA UNP

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (79.339 KB) | DOI: 10.24036/p.v11i2.114521

Abstract

Titanium dioxide (TiO2) is a semiconductor material that is often applied as a photocatalyst. TiO2 has a band gap of 3.20 eV which is less effective when used in visible light. Nitrogen dopants are dopants that have high effectiveness to improve the performance of TiO2 in the visible light region. This study aims to determine the effect of adding nitrogen dopant concentration on the characteristics of TiO2 and its photocatalytic activity in degrading methylene blue. The photocatalytic activity of TiO2-N was tested with 10 ppm methylene blue under sunlight for 1 hour. The addition of dopants to the TiO2 matrix has an effect on the band gap and photocatalytic activity of TiO2
Isolasi dan Karakterisasi α-Selulosa Dari Kulit Buah Matoa (Pometia pinnata) Fauzan Aulia Akbar; Edi Nasra; Desy Kurniawati; Deski Beri; Hary Sanjaya
Periodic Vol 12, No 2 (2023): PERIODIC
Publisher : Departemen Kimia FMIPA UNP

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/periodic.v12i2.117793

Abstract

Cellulose isolation from the matoa fruit peel (Pometia pinnata) has been carried out by means of acid hydrolysis and alkaline hydrolysis. The purpose of this study was to isolate cellulose in the peel of matoa fruit and determine what is the purity level of cellulose contained in the peel of matoa fruit, FTIR is used to identify cellulose functional groups in matoa fruit peel. Results of this study, an yeild of the results of cellulose isolation of matoa peel was 41.3% with the purity level of cellulose of matoa fruit peel of 47.63%. The results of characterization using FTIR are known to have cellulose groups contained in the matoa peel such as -OH, -CH, and C-O groups which are the main functional groups in cellulose.