Jurnal Kimia dan Kemasan
Vol. 39 No. 1 April 2017

Synthesis and Characterization of Superabsorbent Sodium Alginate-G-Poly (Potassium Acrylate) Hydrogels Prepared By Using Gamma Irradiation

Erizal Erizal (Centre for Application of Isotopes and Radiation, JL. Lebak bulus raya no.49, Jakarta 12070, Indonesia)
Fajar Lukitowati (Centre for Application of Isotopes and Radiation, JL. Lebak bulus raya no.49, Jakarta 12070, Indonesia)
Intan Oktaviani (Faculty of Pharmacy and Science, University Muhammadyah, Prof.Dr.Hamka, Jl. Delima II/IV, Klender ,Jakarta 13460,Indonesia)
Dhena Ria Barleany (Dept. Chemical Engineering , University Sultan Ageng Tirtayasa, Jl.Jend.Sudirman KM.3, Cilegon-Banten 42435, Indonesia)
Basril Abbas (Centre for Application of Isotopes and Radiation, JL. Lebak bulus raya no.49, Jakarta 12070, Indonesia)
Sudirman Umar (PSTBM-BATAN)



Article Info

Publish Date
10 Jul 2017

Abstract

The aim of this research was to use gamma rays as sources for the preparation of superabsorbent hydrogels through radiation induced copolymerization. A series of superabsorbent hydrogels were prepared from aqueous solution containing partially neutralized acrylic acid (15%) with different sodium alginate (NaAlg) concentrations (0.5% to 1.5%) by ionizing gamma irradiation (10 kGy to 40 kGy) at room temperature. The effect of NaAlg concentration and irradiation doses on the water absorption behavior of the obtained hydrogels was investigated. The structural changes of hydrogels were characterized using Fourier Transform Infrared (FTIR) whereas the morphologies of hydrogels were examined using Scanning Electron Microscope (SEM). The results showed the swelling of hydrogel in water and NaCl solution increases with increasing NaAlg concentration and decreases with increasing irradiation dose up to 40 kGy. The extend of gel fraction increases as a function of NaAlg concentration. The results of FTIR analysis revealed that acrylic acid and sodium alginate had been successfully grafted, while SEM examination showed that the hydrogels demonstrated large numbers of pores.     

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