Jurnal Ilmu Dasar
Vol 17 No 1 (2016)

Synthesis zeolitic Imidazolate Framework-8 (Zif-8) In Solvothermal: The Effect Comparison of Metal-Ligand

Muhammad Nadjib (Jurusan Kima Institut Teknologi Sepuluh Nopember, Surabaya)
Ratna Ediati (Jurusan Kima Institut Teknologi Sepuluh Nopember, Surabaya)
Yudi Aris Sulistiyo (Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Jember, Jember)
Lutfiatun Nadifah (Jurusan Kima Institut Teknologi Sepuluh Nopember, Surabaya)

Article Info

Publish Date
24 Jan 2017

Abstract

Synthesis of ZIF-8 (zeolitic Imidazolate Frameworks-8) have been successfully carried out by the reaction of zinc nitrate and 2-methylimidazolate in DMF (N'N-dimethylformamide) solvent at a temperature of 120 °C for 24 hours. Synthesis of ZIF-8 has been conducted five times with variations molar ratio of metal (Zn2+):ligand (MeIM) consecutive 1:1; 1:1.5; 1:2; 1:2.5 and 1:3 to study the influence of metal-ligand ratio of the crystallinity and morphology of ZIF-8 that was produced. The results of characterization by X-ray diffraction, FTIR and SEM show that ZIF-8 is synthesized with a ratio of metal: ligand = 1:2 showed the highest crystallinity and has the most irregular surface morphology with form box. Keywords: ZIF-8, solvotermal, metal/ligand ratio 

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Journal Info
Jurnal Ilmu Dasar
Website

Abbrev

JID

Publisher

Universitas Jember

Subject

Control & Systems Engineering Mathematics

Description

Jurnal ILMU DASAR (JID) is a national peer-reviewed and open access journal that publishes research papers encompasses all aspects of natural sciences including Mathematics, Physics, Chemistry and Biology. JID publishes 2 issues in 1 volume per year. First published, volume 1 issue 1, in January ...