Reaktor
Volume 15 No.3 April 2015

Synthesized of Double Layer Thin Film ZnO/ZnO:Ag by Sol-Gel Method for Direct Blue 71 Photodegradation

Heri Sutanto (Unknown)
Singgih Wibowo (Diponegoro University)
Eko Hidayanto (Diponegoro University)
Iis Nurhasanah (Diponegoro University)
Hady Hadiyanto (Diponegoro University)



Article Info

Publish Date
10 Oct 2015

Abstract

The objective of this paper is to synthesize and to characterize a single and a double layer ZnO and ZnO/ZnO:Ag thin films and their application for degradation of direct blue 71. Double layer (DL) thin films of zinc oxide and silver-doped zinc oxide (ZnO/ZnO:Ag) were deposited on the substrate glass by using sol-gel spray coating technique. Ag doping variations (2, 4, 6 and 8 %mol) into ZnO were studied. X-Ray Diffractometer (XRD) and UV-Vis spectrophotometer were used to analyze structure and optical properties of thin films. Direct Blue 71 (DB71) was used for photocatalytic evaluation under UV light irradiation. XRD result showed that all prepared thin films have wurtzite structure with better crytalinity compared to double layer preparation and increasing concentration of Ag doping. UV-Vis transmittance spectra showed that decreasing of transparency of films followed by DL preparation and Ag doping concentration. By using envelope method, energy gap of films can be determined. ZnO/ZnO:Ag 6% (DL 6%) indicated the smallest energy gap 3,038 eV. The highest DB71 degradation result under UV light irradiation was reached by DL 6% with 55.43% and 8.56 x 10-3 min-1 for photocatalytic efficiency and photodegradation rate, respectively.

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Journal Info

Abbrev

reaktor

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology

Description

Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering ...