JURNAL KIMIA SAINS DAN APLIKASI
Vol 23, No 6 (2020): Volume 23 Issue 6 Year 2020

Utilization of Montmorillonite-Modified Earthenware from Bentonite-Ca as a Microbial Fuel Cell (MFC) Membrane Based on Tempe Liquid Waste as a Substrate

Sudarlin Sudarlin (Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Sunan Kalijaga Yogyakarta)
Andika Wahyu Afrianto (Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Sunan Kalijaga Yogyakarta)
Melly Khoerunnisa (Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Sunan Kalijaga Yogyakarta)
Dhea Wiegya Rahmadhani (Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Sunan Kalijaga Yogyakarta)
Anggit Nugroho (Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Sunan Kalijaga Yogyakarta)



Article Info

Publish Date
30 Jun 2020

Abstract

Modifications of the Microbial Fuel Cell (MFC) membrane need to be carried out to increase its electric potential energy. This research aims to determine the effect of montmorillonite from bentonite-Ca as a composite in modified earthenware (GT), which is then used as a membrane of the MFC-based on tempe wastewater as substrate. The results obtained were compared to MFC that used pure earthenware membrane (GM). The ratio of bentonite-Ca and clay in GT was 50:50, while GM used 100% of clay. Characterizations of GT dan GM were performed using FTIR, XRD, and SAA. MFC testing was carried out for 24 hours, where every 2 hours, measurements of potential difference (V), current (A), and power density (W/cm2) were carried out. FTIR and XRD data showed an increase in montmorillonite content in GT, while SAA data showed a decrease in pore volume in GT. The decrease in pore volume GT occurs due to an increase in the number of trivalent cations (Al3+, Fe3+) and bivalent (Mg2+). These cations help transfer protons from the anode to the cathode, which causes a decrease in the potential difference and an increase in the current strength and the MFC-GT power density. The average difference between the decrease in potential difference from MFC-GM to MFC-GT is 0.043 V, while the increase in current is 0.022 mA, and the increase in power density is 0.163 mW/cm2.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...