Bulletin of Chemical Reaction Engineering & Catalysis
2021: BCREC Volume 16 Issue 1 Year 2021 (March 2021)

Light-Harvesting Metal-Organic Frameworks (MOFs) La-PTC for Photocatalytic Dyes Degradation

Agustino Zulys (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia)
Adawiah Adawiah (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia)
Jarnuzi Gunlazuardi (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia)
Muhammad Derry Luthfi Yudhi (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia)



Article Info

Publish Date
31 Mar 2021

Abstract

A novel porous metal organic framework, La-PTC was synthesized by solvothermal method using a perylene-3,4,9,10-tetracarboxylate ligand and lanthanum metal ion. The FTIR analysis showed that La-PTC has a different structure with PTCDA and Na4PTC. The La-PTC MOF has high crystallinity, bandgap energy of 2.21 eV with a maximum absorption area at 561 nm. A rod shape structure of La-PTC has been obtained with the surface area of 22.2364 m2.g−1 and classified into mesoporous material. The La-PTC was relative stable up to 376.93 °C. The La-PTC can degrade 64.76% of MO within ca. 240 min under visible light irradiation with the amount of 30 mg La-PTC. The addition of H2O2 improved the photocatalytic activity of La-PTC with degradation efficiency of 67.02%, 70.00%, and 99.60% for MB, RhB, and MO, respectively. This study presents the fabrication of the light-harvesting metal organic framework, La-PTC and its potential in dyes degradation. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

Copyrights © 2021






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...