Bulletin of Chemical Reaction Engineering & Catalysis
2021: BCREC Volume 16 Issue 4 Year 2021 (December 2021)

Kinetic Study of SN2 Reaction between Paranitrophenyl Benzoate and Hydrazine in the Presence of CTAB Reverse Micelles

K. Bhargavi (Department of PNCO, School of Chemistry, Andhra University, Visakhapatnam, 530017, Andhra Pradesh)
P. Shyamala (Department of PNCO, School of Chemistry, Andhra University, Visakhapatnam, 530017, Andhra Pradesh)
M. Padma (Department of PNCO, School of Chemistry, Andhra University, Visakhapatnam, 530017, Andhra Pradesh)
K. V. Nagalakshmi (Department of Chemistry, Gayatri Vidya Parishad College of Engineering (Autonomous), Visakhapatnam, 530048, Andhra Pradesh)



Article Info

Publish Date
20 Dec 2021

Abstract

Kinetic study of the reaction between p-Nitrophenyl benzoate (PNPB) by hydrazine (HYN) in the presence of Cetyltrimethylammonium bromide (CTAB)/Chloroform/Hexane reverse micellar medium shows that the reaction obeys first order kinetics with respect to each of the reactants. The rate of the reaction is much slower in reverse micellar medium compared to aqueous medium under identical conditions (kˈAq = 2.84×10−3 sec−1, krm =1.34×10−4 sec−1). The rate constants for the reaction in the reverse micellar medium have been determined at different values of W {W=[H2O]/[CTAB]} and at different concentrations of CTAB. It was found that the observed rate constant decreases with W. This kinetic behaviour was interpreted by using modified Berezin pseudo phase model, taking into consideration the distribution of the reactants, PNPB and hydrazine between the three pseudo phases, i.e., water pool, interface an organic phase. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

Copyrights © 2021






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...