Spektra: Jurnal Fisika dan Aplikasinya
Vol 6 No 3 (2021): SPEKTRA: Jurnal Fisika dan Aplikasinya, Volume 6 Issue 3, December 2021

SPECTROSCOPIC AND RADIATIVE PROPERTIES OF SM3+ DOPED SODIUM-LEAD-ZINC-LITHIUM-BORATE GLASSES

Donna Rajagukguk (Physics Study Program of Postgraduate School of Universitas Negeri Medan, Medan 20221, Indonesia)
Juniastel Rajagukguk (Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia)
Pintor Simamora (Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia)
Rappel Situmorang (Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia)
Chayani Sarumaha (Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University, 73000, Thailand)
Widyaningrum Indrasari (Physics Department, Faculty of Mathematics and Science, Universitas Negeri Jakarta, Jakarta 13220, Indonesia)



Article Info

Publish Date
30 Dec 2021

Abstract

The glasses with a composition of (65 - x) B2O3 – 5ZnO – 5Li2O – 15 Na2O – 10PbO – x Sm2O3 (x = 0.0; 0.05; 0.1; 0.5; 1.0; 2.0 and 4.0 mol.%) which has been prepared using the melt quenching technique (1100oC for 3 hour). The spectroscopic properties can be determined by investigating the absorption, excitation, and emission spectra of a glass sample. There are 14 centered absorption bands starting from 6H5/2. The excitation spectrum of the Sm3+ doped borate glasses was measured at the wavelength of 300-550 nm which is the strongest intensity (4F7/2 at 403 nm) used as the excitation wavelength to measure the glass emission spectrum. The emission peaks transition starts from 4G5/2. The Judd-Ofelt theory has been applied to the absorption spectrum of Sm3+ doped borate glass to estimate the intensity parameters (Ωλ, λ = 2, 4 and 6) which are then used to calculate the radiative properties. The energy of the optical bandgap is in the range 3.85-3.77 eV for direct transitions and 3.42 - 4.22 eV for indirect transitions. The decay times obtained were 3.42, 3.99, 3.98, 2.96, 1.67, 1.48 ms for 0.05 - 4.00 mol%. Using the CIE chromaticity diagram for borate glass it can be determined that the glass from this work has a high performance for use as an orange emitting material application.

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