Jurnal Matematika & Sains
Vol 12, No 2 (2007)

Pengaruh Temperatur Penumbuhan terhadap Struktur Kristal dan Morfologi Film Tipis TiO2:Eu yang Ditumbuhkan dengan Metode MOCVD [The Effect of Growth Temperature on the Crystall Structure and Morphology of the Thin Film TiO2:Eu Grown with MOCVD Method]

Edy Supriyanto ( Jurusan Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam,Universitas Jember)
Goib Wiranto ( Pusat Penelitian Elektronika dan Telekomunikasi, LIPI, Bandung)
Hery Sutanto ( Jurusan Fisika, Universitas Negeri Jember, Jember)
Agus Subagio ( Jurusan Fisika, Universitas Negeri Jember, Jember)
Mikrajuddin Abdullah ( Kelompok Keahlian Fisika Material Elektronik, Fakultas Matematika dan Ilmu Pengetahuan Alam, ITB)
Maman Budiman ( Kelompok Keahlian Fisika Material Elektronik, Fakultas Matematika dan Ilmu Pengetahuan Alam, ITB)
Pepen Arifin ( Kelompok Keahlian Fisika Material Elektronik, Fakultas Matematika dan Ilmu Pengetahuan Alam, ITB)
Sukirno Sukirno ( Kelompok Keahlian Fisika Material Elektronik, Fakultas Matematika dan Ilmu Pengetahuan Alam, ITB)
Mohamad Barmawi ( Kelompok Keahlian Fisika Material Elektronik, Fakultas Matematika dan Ilmu Pengetahuan Alam, ITB)



Article Info

Publish Date
07 Oct 2009

Abstract

Thin film of TiO2:Eu had been grown on an n-type Si(100) substrate using Metalorganic Chemical Vapor Deposition (MOCVD) method with titanium (IV) isopropoxide [Ti{OCH(CH3)2}4] 99.99% and europium nitrate [Eu(NO3)3.6H2O] 99.99% as the metal organic precursors. The tetrahydrofuran (THF) was used as a solvent for the precursor. X-ray Diffraction (XRD) analysis showed that the TiO2:Eu thin film grown at temperature of 450 οC had crystal planes of rutile (200), rutile (002) and anatase (211), whereas film grown at 500 οC resulted in a crystal plane of rutile (002) with columnar grain and surface morphology relatively smooth. On the other hand, film grown at temperature of 550 οC has rutile (200) and rutile (002) planes. The surface morphology of thin films TiO2:Eu was affected by Eu atom concentration. The roughness of surface morphology increased with increasing Eu content and therefore the grains became larger. It can be concluded that the crystal structure and surface morphology properties of the films depended significantly on the substrate temperature.

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