Bulletin of Chemical Reaction Engineering & Catalysis
2022: BCREC Volume 17 Issue 2 Year 2022 (June 2022)

Synthesis Metal-Organic Framework (MOFs) Cr-PTC-HIna Modulated Isonicotinic Acid for Methylene Blue Photocatalytic Degradation

Adawiah Adawiah (Integrated Laboratory Centre, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Wulandari Oktavia (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Nanda Saridewi (Department of Chemistry Education, Faculty of Tarbiya and Teaching Sciences, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Farhan Maulana Azhar (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Risma Nur Fitria (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Muhammad Shofyan Gunawan (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Sri Komala (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Agustino Zulys (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424)

Article Info

Publish Date
30 Jun 2022

Abstract

A novel responsive visible light Cr-based MOF, Cr-PTC-HIna, was synthesized using the solvothermal method. Cr-PTC-HIna peaks were observed at 2θ = 9.04°, 12.71°, 14.88°, 25,48°, 27.72°, 28.97°, and 43.60° with a crystal size of 21 nm. Band gap energy achieved from the Cr-PTC HIna was 2.05 eV. Scanning Electron Microscope (SEM) analysis obtained a 3D structural morphology of MOFs Cr-PTC-HIna with a cylindrical tube shape and a particle size of 251.45 nm. Cr-PTC-HIna gave the optimum methylene blue degradation at pH of 7 under 250 watts mercury lamp irradiation for 180 minutes with degradation capacity of 95.40 mg/g. Electron holes and hydroxyl radicals were found as the dominant species contributing to methylene blue degradation. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

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Journal Info
Bulletin of Chemical Reaction Engineering & Catalysis
Website

Abbrev

bcrec

Publisher

Universitas Diponegoro

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...