Jurnal Spektra
Vol 15, No 1 (2014): Spektra: Jurnal Fisika dan Aplikasinya

KAJIAN PEROVSKITE LA0,73CA0,27MN1-XCUXO3 DENGAN 0

Gunanto, Y. E. ( Universitas Pelita Harapan)
Sinaga, K. (Unknown)
Purwanto, A. (Unknown)
Kurniawan, B. (Unknown)
Poertadji, S. (Unknown)
Steven, E. (Unknown)
Brooks, J. S. (Unknown)



Article Info

Publish Date
01 May 2014

Abstract

We have performed the synthesis and characterization of materials La0.73Ca0.27Mn1-xCuxO3 for 0 <x< 0.19 using  neutron scattering diffraction (HRPD) and SQUID.All the samples are already in phase with the crystal structure  orthorombic and space group P nma. Parameters of the Mn-O bond length obtained from the charactyerization HRPD. From  the parameters of Mn-O bond length can be determined the value of Jahn-Teller distortion. The greater x will result in an  average radius of position B (<rB>) increasing and the tolerance factor t decreasing. From the characterization of the SQUID  was found that the maximum value of conductivity for Cu-doped samples will be lower when compare to the sample without  doping, except for Cu=0.10. If the value of the conductivity is getting smaller, the activation energy will be higher. Keywords: Jahn-Teller distortion, factor tolerance, conductivity, activation energy

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