Bulletin of Chemical Reaction Engineering & Catalysis
2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)

Kinetic Modeling of C3H6 Inhibition on NO Oxidation over Pt Catalyst

Muhammad Mufti Azis (Chemical Engineering Department, Faculty of Engineering, Gadjah Mada University, Jl. Grafika No. 2, Kampus UGM, Yogyakarta)
Derek Creaser (Chemical Engineering, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, SE-41296)



Article Info

Publish Date
01 Apr 2016

Abstract

Exhaust after treatment for lean burn and diesel engine is a complex catalytic system that consists of a number of catalytic units. Pt/Al2O3 is often used as a model Diesel Oxidation Catalyst (DOC) that plays an important role to facilitate oxidation of NO to NO2. In the present study, we proposed a detailed kinetic model of NO oxidation as well as low temperature C3H6 inhibition to simulate temperature-programmed reaction (TPR) data for NO oxidation over Pt/Al2O3. A steady-state microkinetic model based on Langmuir-Hinshelwood mechanism for NO oxidation was proposed. In addition, low temperature C3H6 inhibition was proposed as a result of site blocking as well as surface nitrite consumption. The model can explain the experimental data well over the studied temperature range. 

Copyrights © 2016






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...