The Journal of Pure and Applied Chemistry Research
Vol 5, No 3 (2016)

Optical Properties of Nd3+ Doped Phosphate Glasses at 4F3/2 -> 4I11/2 Hypersensitive Transitions

Juniastel Rajagukguk (Universitas Negeri Medan)
M. Djamal (Institut Teknologi Bandung)
R. Hidayat (Institut Teknologi Bandung)
Suprijadi Suprijadi (Institut Teknologi Bandung)
A. Amminudin (Universitas Negeri Medan)
Yotsakit Ruangtaweep (Nakhon Pathom Rajabhat University)
Jakrapong Kaewkhao (Nakhon Pathom Rajabhat University)



Article Info

Publish Date
26 Sep 2016

Abstract

The lasing transition 4F3/2®4I11/2 for Nd3+ doped phosphate glass centered around 1.05 – 1.07mm is referred as hypersensitive transition. The radiative properties such as effective linewidth (Dleff), radiative transition probability (AR), branching ratio (bR), radiative lifetime (tR), quantum efficiency (h) and stimulated emission cross section have been obtained for several phosphate and fluorophosphate glass contained Nd3+. The experimental and calculated oscillator strength were used to analysis Judd-Ofelt parameters (W2, W4 and W6) also to predict the quality of factor c. The phosphate glass material with the approximately 69P2O5-15Na2O-15K2O-1Nd2O3 composition at 4F3/2 ®4I11/2 transition  is suitable for laser medium. The enhanced radiative transition probability as well as branching ratio and stimulated emission cross section in this glass are 3694 s-1, 52% and 8.67 x10-20 cm2 respectively.  As in commercial laser, the magnitudes of the emission cross section in this study achieved in the range 4.0-5.0 x 10-20 cm2.

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Journal Info

Abbrev

jpacr

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Materials Science & Nanotechnology Medicine & Pharmacology

Description

The Journal of Pure and Applied Chemistry Research focuses in publishing research articles in the field of Chemistry and Applied Chemistry. The target is in exploring, investigating, and developing chemicals sources from local and/or Indonesian to increase the value. Scope of the journal is organic ...