Bulletin of Chemical Reaction Engineering & Catalysis
2017: BCREC Volume 12 Issue 1 Year 2017 (April 2017)

Analyzing Loose Contact Oxidation of Diesel Engine Soot and Ag/CeO2 Catalyst Using Nonlinear Regression Analysis

Yasukazu Kobayashi (Materials Research Center for Element Strategy, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503||Japan Department of Chemical Science and Engineering, Tokyo National College of Technology, 1220-2 Kunugida-cho, Hachioji, 19)
Riki Hikosaka (Department of Chemical Science and Engineering, Tokyo National College of Technology, 1220-2 Kunugida-cho, Hachioji, 193-0997)



Article Info

Publish Date
30 Apr 2017

Abstract

Loose contact (LC) oxidation kinetics of carbon black (CB) model soot and Ag/CeO2 catalyst was deduced from thermogravimetric analysis (TG) experiments. In the LC mode at ≧750 K, CB particles were likely to be combusted also by non-catalyzed oxidation, especially those particles located far from the catalyst surface, as well as Ag/CeO2-catalyed oxidation. Since the non-catalyzed oxidation is not due to catalytic activity, in order to deduce the catalytic activity from TG data, a nonlinear regression analysis method was proposed in this study to extract only the catalyzed oxidation part of the TG data. It was verified that this was successfully done with the equations used by the very good curve fits to the experimental TG data, and the catalytic activity was correctly obtained from LC samples with various degrees of physical contact between the CB and catalyst. 

Copyrights © 2017






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...