Indonesian Journal of Chemistry
Vol 17, No 2 (2017)

Comparison of NAA XRF and ICP-OES Methods on Analysis of Heavy Metals in Coals and Combustion Residues

Agus Taftazani (Center for Accelerator Science and Technology, National Nuclear Energy Agency)
Roto Roto (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Novitasari Restu Ananda (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Sri Murniasih (Center for Accelerator Science and Technology, National Nuclear Energy Agency)



Article Info

Publish Date
31 Jul 2017

Abstract

Heavy metals in the samples of coals and combustion residues (bottom ash and fly ash) from Pacitan coal-fired power plant (CPP) have been identified by using NAA, XRF, and ICP-OES methods. This research was aimed to understand the analysis results correlation coefficient (R) and determine the enrichment ratio (ER) value of the samples by using three analysis methods. The results showed 10 elements have been simultaneously detected in all samples. The correlation coefficient of analysis results of metals content in coals by using NAA-XRF, XRF-ICP OES and with ICPOES-NAA methods gives R2£1 respectively. The correlation coefficient of analysis results of metals content in bottom ash and fly ash by using the methods of NAA-XRF, XRF-ICPOES, and ICPOES-NAA gained R2»1 respectively. ICP-OES method was most satisfactory in this study. The value of ER for identified metals by using the three methods in the samples of bottom ash and fly ash yielded the value over one, and ER value of fly ash was greater in comparison to the bottom ash.

Copyrights © 2017






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...