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Ika Rosemiyani
Department of Chemistry, Faculty of Mathematic and Natural Science, Brawijaya University, Malang
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Journal : UNEJ e-Proceeding

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Determination of Lead in Cosmetic Sampels Using Coated Wire Lead (II) Ion Selective Electrode Based On Phyropillite Qonitah Fardiyah; Barlah Rumhayati; Ika Rosemiyani
UNEJ e-Proceeding 2016: Proceeding The 1st International Basic Science Conference
Publisher : UPT Penerbitan Universitas Jember

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Abstract

A coated wire ion selective electrode (CW-ISE) based on pyrophyllite for detection lead (II) in cosmetic samples was developed. CW-ISE has easy measurement for field analysis, good selectivity and sensitivity. The CW-ISE’s membrane consist of mixture an inorganic material of pyrophyllite as  ionophore, polyvinylchloride (PVC) as the matrix polymer, activated carbon and dioktilftalat (DOP) as a plasticizer dissolved in tetrahydrofuran (THF) solvent (1:3 w/v).  It showed a good Nernstian slope of 29.33 mV/decade concentration, a lead linear range concentration between 10-1- 10-5 M, and detection limit of 8.054 x10-6 M  (equal with 1.669 ppm of lead). And could be used optimally at pH 5 and showed a good selectivity for interfering ions (sodium ion, mercury ion and chromium ion) with selectivity order of lead >mercury>chromium>sodium.  The CW-ISE Lead (II) based on pyrophyllite could be applied for determination lead in cosmetic samples, with precision of 95.42% and accuracy of 96.49%. Based on the statistical t test with 5% confidence limit, the potentiometric method and Atomic Absorption Spectrophotometry method had no significant differences.
Co-Authors Barlah Rumhayati Qonitah Fardiyah