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Lanthanum (III) Selective Electrode Based on 1,10-Diaza-4,7, 13,16-Tetraoxacyclooctadecane-N,N’-Diacetic Acid (DACDA) as an Ionophore Susanto Imam Rahayu; Buchari Buchari; Indra Noviandri; Suyanta Suyanta
Jurnal Matematika & Sains Vol 11, No 1 (2006)
Publisher : Institut Teknologi Bandung

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Abstract

A lanthanum(III) ion selective electrode based on ionophore 1,10-diaza-4,7,13,16-tetraoxacyclooctadecane-N,N-diacetic acid was studied. The electrode was prepared with an inner solution system in a membrane composition that contained an active ionophore 1,10-diaza-4,7-13,16-tetraoxacycloocta decana-N,N-diacetic acid (DACDA), an anionic side potassium tetrakis (4-chlorophenyl) borate (KTCPB), a plasticizer o-nitro phenyl octyl ether (NPOE) and a polyvinyl chloride (PVC) matrix support. A good response was obtained with a slope of 19.53 ± 1.62 mV/decade and the electrode gave responses with a detection limit of 3.92x10-6 M. The measurement range was wide (10-5-10-1 M) and the responses time was about 27 seconds. The electrode could measure lanthanum ion with a few interfering alkali, earth alkali and transition elements.
Separation of Manganese Metal Ions with Natural Zeolite Adsorbents and Activated Charcoal of Shall Water use Column Adsorption Method Batrisya, Batrisya; Suyanta, Suyanta
Indonesian Journal of Chemistry and Environment Vol 3, No 1 (2020): JUNE 2020
Publisher : Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21831/ijce.v3i1.40815

Abstract

The purpose of this study is to determine the effectiveness of natural zeolite and activated charcoal to reduce levels of manganese in shall water, determine the effect of contact time with the effectiveness of separation of manganese metal in a shallow well water and know the condition before-after the adsorption process. Method that used was column adsorption with a flow system in which sample is applied to the filtration tube containing zeolite and active carbon. The tests carried out included testing of drinking water parameters namely pH and TDS, testing of manganese content in a shallow well water using Atomic Absorption Spectrophotometer (AAS). The results showed the effectiveness value of natural zeolite adsorbent and activated charcoal using an adsorption column to reduce manganese content in a shallow well water of 90.404%. The longer the use of natural zeolite and activated charcoal, the effectiveness of reducing the manganese content in a shallow well water tends to decrease. A shallow well water samples before the adsorption process have safe conditions for pH and TDS parameters, for manganese metal parameters are also still below the appropriate threshold (SNI) number 01-0220-1987 and RI Permenkes No.492 / MENKES / PER / IV / 2010, after the process of adsorption of f a shallow well water is safe for consumption.
Caring for Labuhan Merapi Tradition, One of The Local Wisdom-Based Disaster Risk Reduction Efforts Tyas, Rizki Arumning; Pujianto, Pujianto; Suyanta, Suyanta
KOMUNITAS: International Journal of Indonesian Society and Culture Vol 13, No 1 (2021): March 2021
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/komunitas.v13i1.26335

Abstract

Local wisdom is the result of the dialectic process between the individual and his environment. One of the local wisdom in Merapi Mountain, Indonesia is the traditional ceremony of Labuhan. This study is a qualitative descriptive study with literature review techniques. Based on the results of this study, it is known that the traditional ceremony of Labuhan Merapi is one of the local wisdom, tradition, culture, and traditional intelligence in the residents of the southern slope of Mount Merapi. Merapi's traditional ceremony is one of the traditional intelligence that can be managed in building a community-based disaster risk reduction system, especially at the disaster mitigation stage. Traditional intelligence is formed from the results of people's interaction with their physical environment over a long period of time. The formation of traditional intelligence allows people to know and read the signs of nature related to the eruption disaster of Mount Merapi.
PEMENUHAN DAN PENINGKATAN GIZI BAGI MASYARAKAT MISKIN Suyanta, Suyanta
Cakrawala Pendidikan CAKRAWALA PENDIDIKAN, EDISI 3,1994,TH.XIV
Publisher : LPMPP Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21831/cp.v3i3.9144

Abstract

Jangka Panjang (PJP) II mencanangkan program nasionaluntuk mengentaskan kemiskinan, yaitu masyarakat yangmasih hidup kekurangan dengan mengkonsumsi makanankurang dari 1800 kalori. Banyak langkah yang ditempuh untukmengentaskan kemiskinan, antara lain dengan memberikandana Inpres Desa Tertinggal, bimbingan usaha, industri kecil,dan lain-Jain. Juga tidak kalah pentingnya adalah denganmemberikan penyuluhan tentang cara mengatur menumakanan yang sehat agar kebutuhan gizi dan kalori terpenuhi.Setiap tubuh memerlukan gizi dan kalori yang cukup,yang meliputi: kat'bohidt'at, lemak, protein, vitamin, meniraldan air. Untuk memenuhi kebutuhan gizi maka setiap kalimakan harus dengan menu yang sehat, yaitu menu yangmeliputi: nasi, sayur, lauk-pauk. buah-buahan dan susu atauair. Untuk memenuhi menu yang sehat tidak harus denganbiaya yang banyak dan dengan ha'rga yang mahal, tetapidengan bahan makanan yang sederhana dan dengan biaya yangmurah pun dapat untuk memenuhi kebutuhan gizi dan kaloribagi tubuh. Bahan-bahan yang murah banyak terdapat di desabahkanmudah untuk diusahakan sendiri dengan bercocoktanam sendiri atau dengan beternak di rumah. Untuk itudiperlukan usaha yang sungguh-sungguh dari masyarakatmiskin. Juga dengan bantuan dari berbagai pihak yangterkait.
Integrating Cangkringan’s Local Potential in Chemistry Education Concept: Is It Really Integrated? Rizki Arumning Tyas; Wilda Muhimmatun Nisa; Jody Febriandini; Insih Wilujeng; Suyanta Suyanta
Indonesian Journal of Science and Education (IJOSE) Vol 5, No 1 (2021): Indonesian Journal of Science and Education
Publisher : Fakultas Keguruan dan Ilmu Pendidikan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31002/ijose.v5i1.3471

Abstract

Indonesia is a country with very rich in local regional potential. The local potential can be utilized as one of the natural science learning sources in junior high school. One of the local potentials that can be integrated with science lessons is food. This research aimed to conduct the study, analysis, and develop science subject specific pedagogy of natural science learning integrated local food in Cangkringan Sub-District to introduce chemical materials in junior high school, namely additives in food and its impact on health. This research was research and development (R&D) with 4-D model, consist of define, design, develop, and disseminate. Product eligibility is assessed by the validator using the product feasibility assessment sheet. Product feasibility assessment scores are then classified in product rating category classification. This research results is produce science subject specific pedagogy that consist of syllabuses, lesson plans, handouts, and student worksheets. The developed syllabus gets a feasibility score of 4.00, lesson plan gets a score of 3.80, the handout gets a score of 3.60, while the student worksheet gets a score of 3.80. Based on these results, overall, the science subject specific pedagogy developed gained a very good category.
Students’ Science Process Skill in Volcanoes Eruption Disaster Preparedness and Mitigation Rizki Arumning Tyas; Pujianto Pujianto; Suyanta Suyanta
Jurnal Ilmu Pendidikan Vol 27, No 1 (2021): June
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um048v27i1p1-7

Abstract

This study aimed to determine the achievement of the mastery of science process skills of students who are trained in integrated learning disaster risk reduction efforts. This research is an experimental research design with one sample control group design. The sample in this study were 60 students of 7th grade student in SMP N 2 Cangkringan, Yogyakarta, Indonesia. SMP N 2 Cangkringan is located near Merapi Mountain areas. Science process skills data were obtained using a process skills observation sheet that was filled in by the observer. Data analysis was performed descriptively. The results shows that the scientific process skills profile of students who were trained together with the training of volcanic eruption disaster mitigation increased at each meeting. The most significant improvement was observing, followed by predicting skills, communicating skills, and drawing conclusions
MECHANISM OF LANTANUM METAL TRANSPORT IN MEMBRAN LIQUID WITH CARRIER SENYA WA MACROSIKLIS Suyanta Suyanta
Jurnal Penelitian Saintek Vol 8, No 2: Oktober 2003
Publisher : Institute of Research and Community Services, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (6003.843 KB) | DOI: 10.21831/jps.v8i2.5560

Abstract

The transport mechanism of lanthanum element in the supported liquidmembrane with macrocycle compound Di benzo IB crowns 6 carriers was studied.  These transport are two kinds. that is  chemical transport and potential   transport.   The  chemical  transport  is   done  with  two  cell compartment   (feed   compartment   and   stripping   compartment).  and separate with membrane that prepare with DiBenzoIBCrown6. Poly Vinyl Chloride. Di  Octyl Ptalate, Sodium  tetra butyl borate  in  Tetra hydro furan solution. A 150 mL solution of La3+   JO-3  Min feed  cell stirrer with300 rpm speed along 3 hour. The stripping phase is solution that varied the pH from  1 to B. The same way. then solution in the feed cell is varied from  10-1  M to 5.10-4  M. The potential  transport is measured with the relative  same  cell.  The potential   transport  measure  with  two  kind reference electrode. Ag/AgCI reference  electrode in the inner cell and calomel reference electrode in the outer cell. Inner cell is contain mixture solution KCL 10-3 M and La3+    IO-3 M and outer cell is contain solution La3"   that variedfrom  10-8 to JO-J  M. The chemical transport is effective at low pH  (below pH  4) and high pH  (upper pH  6). It is good way for separation of La3'.     The transport ion La3+    is low at pH 4 -  6. It is good areafor applied as sensor membrane electrode that has minimal diffusion potential.  The system has good  correlation in potential  membrane that gives slope value 19.36 as Nernst coefficient.
Pemisahan Ion Logam Besi dan Mangan pada Air Sumur (Dalam) Wonoboyo Menggunakan Metode Kolom Adsorpsi Sunarto Sunarto; Suyanta Suyanta; Regina Tutik Padmaningrum; Isana Supiah YL; Karlinda Karlinda
Jurnal Sains Dasar Vol 11, No 1 (2022): April 2022
Publisher : Faculty of Mathematics and Natural Science, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21831/jsd.v11i1.44189

Abstract

Penelitian ini bertujuan untuk memisahkan ion logam besi dan mangan pada air sumur (dalam) menggunakan metode adsorpsi kolom. Berdasarkan penelitian, diketahui efektivitas metode adsorpsi kolom untuk penurunan kadar logam besi dan mangan pada air sumur, efisiensi waktu penjerapan terhadap ion logam besi dan mangan, serta kondisi air sumur sebelum dan sesudah adsorpsi. Penelitian dilakukan pada air sumur (dalam) Wonoboyo, Kecamatan Jogonalan, Kabupaten Klaten. Proses adsorpsi menggunakan kolom berisi zeolit dan karbon aktif sebagai adsorben. Pada penelitian ini efektivitas pemisahan logam besi dan mangan dari air sumur (dalam) diketahui dari nilai efisiensi penjerapannya. Analisis logam besi dan mangan dilakukan dengan Spektrofotometri Serapan Atom (AAS). Selain itu juga dilakukan uji parameter air yaitu pH dan TDS. Hasil penelitian menunjukkan bahwa semakin lama proses adsorpsi, maka efektivitas adsorben zeolit dan arang aktif dalam menurunkan kadar Fe dan Mn meningkat. Efisiensi penjerapan cukup tinggi dengan rata-rata 97,50% untuk Fe dan 98,33% untuk Mn. Air yang sebelumnya keruh menjadi jernih dengan pH dan TDS yang semakin kecil, sehingga air lebih aman dikonsumsi karena semakin jauh dari nilai ambang batas yang ditetapkan dalam SNI dan permenkes RI N0.492/MENKES/PER/IV/2010.
MODIFICATION OF KELUD VOLCANIC ASH 2014 AS SELECTIVE ADSORBENT MATERIAL FOR COPPER(II) METAL ION Susila Kristianingrum; Endang Dwi Siswani; Suyanta Suyanta
Jurnal Sains Dasar Vol 5, No 1 (2016): April 2016
Publisher : Faculty of Mathematics and Natural Science, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (922.942 KB) | DOI: 10.21831/jsd.v5i1.12659

Abstract

Abstract This research aims to prepare an adsorbent from Kelud volcanic ash for better Cu(II) adsorption efficiency than Kiesel gel 60G E'Merck. Adsorbent synthesis was done by dissolving 6 grams of volcanic ash activated 700oC 4 hours and washed with HCl 0.1 M into 200 ml of 3M sodium hydroxide with stirring and heating of 100 °C for 1 hour. The filtrate sodium silicate was then neutralized using sulfuric acid. The mixture was allowed to stand for 24 hours then filtered and washed with aquaDM, then dried and crushed. The procedure is repeated for nitric acid, acetic acid and formic acid with a contact time of 24 hours. The products were then characterized using FTIR and XRD, subsequently determined acidity, moisture content, and tested for its adsorption of the ion Cu (II) with AAS. The results showed that the type of acid that produced highest rendemen is AK-H2SO4-3M ie 36.93%, acidity of the adsorbent silica gel synthesized similar to Kiesel gel 60G E'Merck ie adsorbent AK-CH3COOH-3M and the water content of the silica gel adsorbent synthesized similar to Kiesel gel 60G E'Merck ie adsorbent AK-H2SO4-2 M. The character of the functional groups of silica gel synthesized all have similarities with Kiesel gel 60G E'Merck as a comparison. Qualitative analysis by XRD for all modified adsorbent showed a dominant peak of SiO2 except adsorbent AK-H2SO4 amorphous and chemical bonds with FTIR indicates that it has formed a bond of Si-O-Si and Si-OH. The optimum adsorption efficiency of the metal ions Cu(II) obtained from AK-H2SO4-5M adsorbent that is equal to 93.2617% and the optimum adsorption capacity of the Cu(II) metal ions was obtained from the adsorbent AK-CH3COOH-3M is equal to 2.4919 mg/ g. Keywords: adsorbents, silica gel, adsorption, kelud volcanic ash
SEPARATION OF Ca AND Fe METAL ION IN SOURCE WATER BY ADSORPTION COLUMN TECHNIC WITH LOCAL ZEOLITE AND ACTIVE CARBON Suyanta Suyanta; Hanafi Idham Kholid; Bambang S
Jurnal Sains Dasar Vol 4, No 1 (2015): April 2015
Publisher : Faculty of Mathematics and Natural Science, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (91.587 KB) | DOI: 10.21831/jsd.v4i1.8446

Abstract

This research aims are to separate of Ca and Fe metal ion in source water, with local zeolite and active carbon by adsorption column technic. Efficiency of separation are control by adsorption time and size of zeolite. Method that used was column adsorption with a flow system in which sample is applied to the filtration tube containing zeolite and active carbon. Initial and final concentrations of the samples were analyzed using Atomic Adsorption Spectrophotometer instrument. The results obtained shows that ability adsorption of zeolite to Ca and Fe metal ion are a good. Zeolite 1 (10 mesh) can reduce iron concentration until 93.98 % and zeolite 2 (5mesh) until 98.88% for 1 – 4 week range time. Whereas reducing of calcium concentration is not good, until 2 week period time adsorption of calcium ion is about 50%. Keywords: adsorption, zeolite, source water
Co-Authors A. Rahmawati. P Abdul Wahid Adilah Afikah afaninda dwi khairini Agrielsa Alphasati Sinaga Amalia Rahmadani Andika Febrian Andika Febrian* Angga Sugiarto Anggi Ristiyana Puspita Sari Anita Widiastuti Ari Astuti Arina Novia Dewi Asri Widowati Ayu Latiefah Eka Wahyuni Ayu Lilis Suryana Ayu Lilis Suryana* Bambang S Batrisya Batrisya Batrisya, Batrisya Buchari Buchari Dadan Rosana Dadan Rosana Danang Habib Pratama Dien Aulia Bansu Donny Auliya Arrohman* Dwi Agnes Setianingrum Eli Rohaeti Endang Dwi Siswani Erika Aprilliya Erna Erawati Erna Erawati Fika Deni Utari Fitria Lafifa Gagan Ganiya Aulia Rahman Galuh Titisari Ganefri . Gus Rijal Mujahidin Hana' Fadhilah Retiyanto Hanafi Idham Kholid Hentje Ponto I Gusti Putu Suryadarma I Nyoman Sila Iffah Nurlathifah Fikri Illyas Md Isa Illyas Md. Isa Imesta Zulfanida Ernest Indra Noviandri Insih Wilujeng Isana Supiah YL JKD JURNAL Jody Febriandini Jumadi Jumadi Jumadi Jumadi Jumadi Mabe Parenreng Karlinda Karlinda Karlinda Karlinda Khamsiah Mawar Fatmah Maizatul Najwa Jajuli Marwanti Marwanti Maryati Maryati Mentari Astuti Putri Legowo moh hanafi Muhammad Agung Muhammad Habib As-Shidiq Muhammad Hafizh Syaukani Muharram Muharram Musdalifah Musdalifah Nina Khaerunnisa Nina Khaerunnisa Noorshida Mohd Ali Norhayati Hahsim Norlaili Abu Bakar Normalia Sandy Palumpun Novita Widhi Widyapuraya Novita Widhi Widyapuraya Pujianto Pujianto Pujianto Pujianto Pujianto Pujianto Pujianto Pujianto Rahadian Rahadian Ray Cinthya Habellia Regina Tutik Padmaningrum retno asti Risanto Nugroho Rizki Arumning Tyas S Nurohman Sabar Nurohman Sarmila Eka Putri Sharifah Norain Mohd Sharif Shofiatun Zurida Siswantoyo Siswantoyo Siti Arifah Siti Kholifah Sofyan Dwi Nugroho Sri Arwini Bahrun Bahrun Sri Nursakinah Sri Rejeki Sri Rejeki Dwi Astuti Sri Rejeki Dwi Astuti Sugito Sugito Suharsono Suharsono Sukisman Purtadi Sunarto Sunarto Sunaryo Soenarto Susanto Imam Rahayu Susila Kristianingrum Syazwan Afif Mohd Zobir Tyas, Rizki Arumning Usman Mulbar Wan Rusmawati Wan Mahamod Wilda Muhimmatun Nisa Wiwin Reni Rachmawati Zuhailimuna Muda Zuhdan Kun Prasetyo