Bulletin of Chemical Reaction Engineering & Catalysis
2020: BCREC Volume 15 Issue 1 Year 2020 (April 2020)

Carbon Waste Powder Prepared from Carbon Rod Waste of Zinc-Carbon Batteries for Methyl Orange Adsorption

Fitria Rahmawati (Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl. Ir. Sutami 36 A Kentingan Surakarta)
Viona Natalia (Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl. Ir. Sutami 36 A Kentingan Surakarta)
Agung T. Wijayanta (Research Group of Sustainable Thermofluids, Mechanical Engineering, Sebelas Maret University, Jl. Ir. Sutami 36 A, Kentingan, Surakarta)
Siti Rondiyah (Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl. Ir. Sutami 36 A Kentingan, Surakarta)
Koji Nakabayashi (Department of Advanced Device Materials, Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga-shi, Fukuoka 816-8580)
Jin Miyawaki (Department of Advanced Device Materials, Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga-shi, Fukuoka 816-8580)



Article Info

Publish Date
01 Apr 2020

Abstract

A research on the preparation of Carbon Waste Powder, CWP, was conducted and made from carbon rod waste which was extracted from used zinc-carbon batteries. This research was an effort to overcome environmental problem caused by battery waste by converting into adsorbent for methyl orange (MO) that frequently used by textile industries. The prepared powder was then analyzed to understand its characteristic peaks, crystallinity, and to compare the properties with other carbonaceous forms, i.e. a commercial Carbon Paper (CP), and a commercial meso- carbon micro-beads (MCMB). The analysis found that CWP is dominated by graphitic carbon. An adsorption experiment was then conducted to study their adsorption ability to methyl orange solution. The result found that those three carbonaceous materials have the ability to adsorb methyl orange with different activities. MCMB has the highest adsorption capacity of 0.197 mg.g-1. Meanwhile, CWP and CP show adsorption capacity of 0.066 mg.g-1 and 0.062 mg.g-1, respectively. Methyl orange adsorption on CWP and CP were under second order, which means the adsorption could be four times faster as the MO solution doubled. Moreover, the rate constant of MO adsorption on CWP is 8×10-4 min-1, which was higher than the rate constant of MO adsorption on CP. It confirmed that the CWP can be used as a promising adsorbent for dye waste water. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

Copyrights © 2020






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...