Walisongo Journal of Chemistry
Vol 4, No 1 (2021): Walisongo Journal of Chemistry

Silica-Rice Husk as Adsorbent of Cr (VI) Ions Prepared through Sol-Gel Method

Siti Rodiah (Universitas Islam Negeri Raden Fatah Palembang)
Mifta Huljana (Universitas Islam Negeri Raden Fatah Palembang)
Jauharuddin Luthfi Al Jabbar (Universitas Islam Negeri Raden Fatah Palembang)
Chairul Ichsan (Universitas Islam Negeri Raden Fatah Palembang)
Hasan Marzuki (Universitas Islam Negeri Raden Fatah Palembang)



Article Info

Publish Date
09 Jul 2021

Abstract

One of the heavy metals contained in the textile industry wastewater is chromium (Cr). Chromium hexavalent ions (Cr6+) are highly toxic and its accumulation in the human body will cause various negative impacts. This study aimed to determine the characteristics of silica synthesized by the sol-gel method to gain homogeneity and high purity. Synthesized silica was calcined at 700°C for 4 hours and its performance to adsorb Cr(VI) ions  in textile wastewater was investigated. The presence of -OH group from silanol (–Si-OH) was appeared at wavenumber 3367.70 cm-1, meanwhile siloxane functional groups were recorded at 1056.99 cm-1 and 784.38 cm-1 due to the O-Si-O asymmetric stretching and Si-O bending vibration. Optimum conditions of silica to adsorb Cr(VI) ions took place at pH 2 and contact time of 90 minutes by adsorption efficiency of 75,65% and followed the Freundlich isotherm.

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Journal Info

Abbrev

wjc

Publisher

Subject

Chemistry

Description

Walisongo journal of chemistry is a peer reviewed and open access journal published by Chemistry Department, faculty of Science and Technology, UIN Walisongo Semarang. This journal covering all areas of chemistry including inorganic, organic, physic, analytic, biochemistry, and environmental ...