EKOLOGIA : Jurnal Ilmiah Ilmu Dasar dan Lingkungan Hidup
Vol 21, No 2 (2021): EKOLOGIA : Jurnal Ilmiah Ilmu Dasar dan Lingkungan Hidup

SINTESIS KEMOSENSOR ION CN- BERBASIS TURUNAN PIRAZOLIN DENGAN LOGAM Cu

Yulian Syahputri (Universitas Pakuan, Bogor)
Diah Indah Purwati (Universitas Pakuan, Bogor)
Sutanto Sutanto (Universitas Pakuan, Bogor)
Agus Taufiq (Akademi Kimia Analis Caraka Nusantara, Depok)



Article Info

Publish Date
24 Feb 2022

Abstract

One of the toxic anions such as cyanide (CN-) has a negative impact on living things. Pyrazoline derivatives can be complexed with transition metals and used as CN- ion fluorosensor, because pyrazoline derivatives have fluorescence properties. This study aims to synthesize of CN- ion chemosensors based on pyrazoline derivative namely para-di-2-(1-phenyl-3-pyridyl-4,5-dihydro-1H-pyrazole-5-yl)benzene with Cu metal. The resulting complex compounds were characterized using Spectrophotometer Infra Red (FTIR), Spectrophotometer UV-Visible, and Spectrofluorometer. Then, a complex compound chemosensor (fluorosensor) study of Cu2+ was carried out with the addition of CN- ions using a spectrofluorometer. The results showed that the synthesis of complex compound Cu2+ was successfully carried out and a brown precipitate was obtained with a yield of 43% with a melting point of 243.3°C. Based on the results of characterization by FTIR (cm-1) generates 3400 (Amine), 2920.88-2852.42 (C-H pyridine), 2360.38 (C=N), 1594.50-1490.39 (C=C aromatic), 1233.67-1021.17 (C-N),  982.66 (Cu-O), 348.00 (Cu-N), and 320-280 (Cu-Cl). The results of the spectroscopy UV-Visible analysis Cu2+ complex compounds at a concentration of 5x10-5 M obtained two absorption peaks, 242 nm and 306 nm. The result of the spectrofluorometer analysis of Cu2+ complex compound were 1516 a.u at a wavelength of 502 nm. The results of the chemosensor (fluorosensor) studies of the Cu2+ complex compound with the addition of CN- ions can be used as a turn on-off  type fluorosensor.

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Journal Info

Abbrev

ekologia

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Environmental Science Mathematics

Description

Ekologia adalah jurnal ilmiah yang diterbitkan untuk mengakomodasi tulisan hasil penelitian bagi sivitas akademika Universitas Pakuan khususnya dan instansi lain di luar Universitas Pakuan pada umumnya. Jurnal ini memuat artikel primer yang bersumber langsung dari hasil penelitian Ilmu Dasar dan ...