Jurnal Keramik dan Gelas Indonesia
Vol 30, No 2 (2021): Jurnal Keramik dan Gelas Indonesia

Modification of Silica as a Sealing Rubber Filler with Coupling Agents Hexamethyldisilazane (HDMS) and Methyltriethoxysilane (MTES)

Shely Octavania (Politeknik SMTI, Jakarta)
Eneng Maryani (Balai Besar Keramik)
Hernawan Hernawan (Balai Besar Keramik)
Lintong Sopandi Hutahaean (Politeknik SMTI, Jakarta)
Untung Prayudie (Politeknik SMTI, Jakarta)



Article Info

Publish Date
11 Feb 2022

Abstract

Materials that can be used in the manufacture of LPG cylinder sealant rubber is silica. However, easily agglomerates so it is not compatible with rubber. Therefore, the silica surface must be modified to reduce agglomeration and improve compatibility with rubber. This study aims to determine the effect of silica modification on the characteristics of LPG cylinder sealing rubber produced. Silica modification is carried out using 2 (two) types of coupling agents, namely HMDS and MTES with and without Si-69. Preparation of rubber compound with SIR 20 raw material is carried out using an open mill tool with a modified silica filler dose of 40 phr. The characteristics of rubber tested were compound maturity test using a Rheometer and tensile strength and elongation at break using a Universal Testing Machine. The test results show that silica modification can accelerate the maturation time of the compound and increase the tensile strength and elongation at break. The maturation time of the rubber compound with silica filler modified by MTES and HMDS was 7 minutes 36 seconds and 7 minutes 53 seconds. The resulting tensile strength and elongation values are 18.8 MPa and 720% (MTES) and 19.0 MPa and 770% (HMDS). The use of MTES and Si-69 as coupling agent for silica produced rubber with tensile strength and elongation at break of 15.9 MPa and 660%.

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Journal Info

Abbrev

jkgi

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Electrical & Electronics Engineering Materials Science & Nanotechnology

Description

The JKGI contains papers of original research that provide or lead to fundamental principles in the science of ceramics, functional ceramics and ceramic-based composites. These articles include reports of the discovery of new phases, phase relationships, processing approaches and microstructures ...