VALENSI
Jurnal Kimia VALENSI Volume 8, No. 1, May 2022

Isotherm and Kinetic Studies on the Adsorption Behavior of Metanil Yellow Dyes onto Modified Shrimp Shell-Polyethylenimine (SS-PEI)

Rahmiana Zein (Andalas University)
Zulkarnain Chaidir (Andalas University)
Zilfa Zilfa (Andalas University)
Syiffa Fauzia (Research Center for Chemistry, National Research and Innovation Agency of Republic of Indonesia, Jakarta, 10340 Indonesia)
Putri Ramadhani (Andalas University)



Article Info

Publish Date
10 May 2022

Abstract

The present study investigated the ability of modified shrimp shell by Polyethylenimine (PEI) for enhanced removal of metanil yellow. The modification was carried out using citric acid as a cross linker. The removal of metanil yellow by modified shrimp shell-PEI was conducted by batch method and investigated some parameters affected adsorption including pH, initial dye concentration, and contact time. The optimum conditions were achieved at pH 5, initial dye concentration 1200 mg/L, and contact time 90 minutes. The adsorption isotherm study showed that the adsorption of metanil yellow dye by modified shrimp shell-PEI followed the Langmuir isotherm model with a maximum adsorption capacity (qm) 121.951 mg/g. The kinetic study indicated that the adsorption process suited to the pseudo-second-order model. The characterization results revealed the differences in the adsorbent characteristics before and after the adsorption of metanil yellow dye. The cross-linked PEI onto shrimp shell provided more active sites (amine groups) to bind dye molecules. It can be concluded that modified shrimp shell by PEI has increased its ability in metanil yellow removal.

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Journal Info

Abbrev

valensi

Publisher

Subject

Chemistry

Description

Jurnal Kimia Valensi is a biannual and peer-reviewed open access journal published by Department of Chemistry, Faculty of Science and Technology UIN Syarif Hidayatullah Jakarta. This journal covering all aspect of ...