Jurnal Teknik Kimia USU
Vol. 6 No. 1 (2017): Jurnal Teknik Kimia USU

PENYISIHAN ION LOGAM MERKURI (Hg2+) MENGGUNAKAN ADSORBEN BERBAHAN BAKU LIMBAH PERTANIAN DAN GULMA TANAMAN

Miftahurrahmah (Program Studi Magister Teknik Kimia, Program Pascasarjana Universitas Syiah Kuala)
Suhendrayatna (Jurusan Teknik Kimia, Fakultas Teknik, Universitas Syiah Kuala)
Muhammad Zaki (Jurusan Teknik Kimia, Fakultas Teknik, Universitas Syiah Kuala)



Article Info

Publish Date
19 May 2017

Abstract

This research was conducted to prepare adsorbents from agricultural and weeds waste biomass to remove Hg2+ metal ions from water phase. Water hyacinth biomass (agricultural waste) and rice husk (weed) was cleaned, dried in an oven dryer, and carbonized in a furnace at 500oC for 2 hours. Then, dried carbon was milled to get 100 mesh of size and was followed by activation using 0.5 N NaOH. The adsorption process was conducted by mix 1 gram of activated adsorbent on a 100 ml water containing 3 ppm Hg2+ metal ions at 100 rpm, pH 5, and 30oC. Hg2+ concentration in water phase were analyzed using AAS, Shimadzu AA-6300 for a specified time within a period of 20-100 minutes. This study shows that at the beginning process of adsorption, adsorbent from rice husk has ability to decrease 69.91% concentration of Hg2+ for 20 minutes, while adsorbent from water hyacinth reaches to 94.26%. The characterization results of FTIR spectra and SEM shows that adsorbent from water hyacinth was able to absorb more Hg2+ metal ions in a short time because it has a functional group that was able to bind heavy metals, and also has a random surface structure, compared with the adsorbent from rice husks that has less functional groups with uniform morphology structure

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Journal Info

Abbrev

jtk

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

Description

Jurnal Teknik Kimia USU merupakan jurnal elektronik yang mempublikasikan karya ilmiah di bidang teknik kimia yang diterbitkan oleh Departemen Teknik Kimia, Fakultas Teknik, Universitas Sumatera Utara. Jurnal ini tidak terbatas pada mahasiswa dan dosen Universitas Sumatera Utara, tetapi terbuka untuk ...