Indonesian Review of Physics (IRiP)
Vol. 5 No. 1 (2022)

Effect of Sintering Temperature on Crystal Structure and Conductivity of the CaCO3-Doped Li4Ti5O12 Anodes from Blood Clam Shells (Anadara granosa)

Marhan Ebit Saputra (Universitas Bangka Belitung)
Megawati Ayu Putri (Universitas Bangka Belitung)
Eka Febrianti (Universitas Bangka Belitung)
Widodo Budi Kurniawan (Universitas Bangka Belitung)



Article Info

Publish Date
15 Jun 2022

Abstract

CaCO3-doped Li4Ti5O12 was synthesized by solid-state method with sintering temperatures at 750 °C, 800 °C, and 850 °C. The source of CaCO3 was used from blood clam shells (Anadara granosa) with a content of 97.67%. The influence of sintering temperature on crystal structure and conductivity of CaCO3-doped Li4Ti5O12 are extensively studied. XRD results show there is no CaCO3 phase found, which indicates that the doping of Li4Ti5O12 with CaCO3 has been successful. The smallest crystallite size was obtained at a sintering temperature of 800 °C, which is 46.49 nm, which is beneficial for shortening diffusion length and facilitating the electron and ion transport, causing an increase in anode conductivity. The most optimal conductivity was obtained in samples with a sintering temperature of 800 °C with a conductivity of 2.46 x 10-4 S/cm. When the sintering temperature is increased to 850 °C, the particles tend to agglomerate and deteriorate the electrochemical properties.

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Journal Info

Abbrev

irip

Publisher

Subject

Astronomy Earth & Planetary Sciences Education Materials Science & Nanotechnology

Description

This journal is continued version of Berkala Fisika Indonesia journal. The journal was published for the first time in 2008. The last published volume was 10 (1) 2018. The ISSN is 2085-0409 (printed version) and 2250-0465 (online ...