Makara Journal of Technology
Vol. 20, No. 3

Characterization and Utilization of Calcium Oxide (CaO) Thermally Decomposed from Fish Bones as a Catalyst in the Production of Biodiesel from Waste Cooking Oil

Lesbani, Aldes (Unknown)
Sitompul, Sabat Okta Ceria (Unknown)
Mohadi, Risfidian (Unknown)
Hidayati, Nurlisa (Unknown)



Article Info

Publish Date
03 Dec 2016

Abstract

Thermal decomposition of fish bones to obtain calcium oxide (CaO) was conducted at various temperatures of 400, 500, 800, 900, 1000, and 1100 °C. The calcium oxide was then characterized using X-ray diffractometer, FTIR spectrophotometer, and SEM analysis. The calcium oxide obtained from the decomposition at 1000 °C was then used as a catalyst in the production of biodiesel from waste cooking oil. Diffraction pattern of the calcium oxide produced from decomposition at 1000 °C showed a pattern similar to that of the calcium oxide produced by the Joint Committee on Powder Diffraction Standard (JCDPS). The diffractions of 2q values at 1000 °C were 32.2, 37.3, 53.8, 64.1, and 67.3 deg. The FTIR spectrum of calcium oxide decomposed at 1000 °C has a specific vibration at wave-length 362 cm-1, which is similar to the specific vibration of Ca-O. SEM analysis of the calcium oxide indicated that the calcium oxide’s morphology shows a smaller size and a more homogeneous structure, compared to those of fish bones. The use of calcium oxide as a catalyst in the production of biodiesel from waste cooking oil resulted in iod number of 15.23 g/100 g KOH, density of 0.88 g/cm3, viscosity of 6.00 cSt, and fatty acid value of 0.56 mg/KOH. These characteristic values meet the National Standard of Indonesia (SNI) for biodiesel.

Copyrights © 2016






Journal Info

Abbrev

publication:mjt

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Electrical & Electronics Engineering Engineering Materials Science & Nanotechnology Mechanical Engineering

Description

MAKARA Journal of Technology is a peer-reviewed multidisciplinary journal committed to the advancement of scholarly knowledge and research findings of the several branches of Engineering and Technology. The Journal publishes new results, original articles, reviews, and research notes whose content ...