JIMSI
Vol 2, No 2 (2022): JURNAL TEKNIK KIMIA VOKASIONAL (JIMSI)

KAPASITAS ADSORPSI LOGAM MANGAN (Mn) MENGGUNAKAN BIOSORBEN PEKTIN DARI KULIT PISANG KEPOK

Mardhiyah Nadir (Politeknik Negeri Samarinda)
Sitti Sahraeni (Politeknik Negeri Samarinda)
Rifka Aulia Mawardi (Politeknik Negeri Samarinda)
Marlinda Marlinda (Politeknik Negeri Samarinda)



Article Info

Publish Date
12 Oct 2022

Abstract

The construction of a chemical plant has a negative impact on the environment by producing waste containing heavy metals such as manganese (Mn). One of the treatments of waste containing heavy metals by adsorption method. The use of pectin as a biosorbent in the adsorption process has been widely carried out because it has several advantages and contains active groups such as carboxyl and hydroxyl which play an important role in the adsorption process. This research aimed to determine the adsorption capacity of manganese (Mn) using pectin from kepok banana peel as a biosorbent. Pectin was obtained from the extraction of kepok banana peels using the Microwave Assisted Extraction (MAE) method. Manganese solution was adsorbed using 1 gram mass of pectin with variable adsorption time (60, 90, 120, 150, and 180 minutes). Identification of pectin functional groups at absorption wavelengths between 1000cm-1 to 3500 cm-1 using FT-IR spectrophotometer and the analysis results obtained that there are hydroxyl groups (3423,993 cm-1), carbonyl (1638,233 cm-1), carboxylate (1736.585 cm-1), ether (1079.942 cm-1) and carbocyclic (1238.076 cm-1). Mn metal after adsorption was analyzed using AAS. The results showed that the optimum adsorption time to adsorb Mn metal was 150 minutes with an adsorbed metal capacity of 0.182 mg/g (36.403%). The adsorption of Mn followed the Freundlich isotherm equation with KF = 0.0886 mg/g.  Keywords: adsorption, adsorption isotherm, adsorption capacity, Mn metal, pectin

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Journal Info

Abbrev

jimsi

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Engineering Materials Science & Nanotechnology

Description

This Journal publishes current original research on Chemical Engineering and Chemistry, especially on catalysts, biofuel, petro and oleo, and ...