Bulletin of Chemical Reaction Engineering & Catalysis
2019: BCREC Volume 14 Issue 1 Year 2019 (April 2019)

Facile Synthesis of Ag3PO4 Photocatalyst with Varied Ammonia Concentration and Its Photocatalytic Activities For Dye Removal

Febiyanto Febiyanto (Department of Chemistry, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)
Agus Soleh (Department of Chemistry, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)
Muhammad Sofi Khoerul Amal (Department of Chemistry, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)
Mohammad Afif (Department of Chemistry, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)
Sukma Sewiji (Department of Physics, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)
Anung Riapanitra (Department of Chemistry, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)
Uyi Sulaeman (Department of Chemistry, University of Jenderal Soedirman, Jl. Dr. Soeparno No. 61 Karangwangkal, Purwokerto, 53123)



Article Info

Publish Date
15 Apr 2019

Abstract

The highly active photocatalyst of Ag3PO4 could be synthesized under ammonia solution using the facile co-precipitation method with the starting material of AgNO3 and Na2HPO4.12H2O.  The variation of ammonia concentration was designed at 0.00, 0.05, 0.15, and 0.30 M. The products were characterized using X-ray diffraction, UV-diffuse reflectance spectroscopy, and scanning electron microscopy. The photocatalytic activities were evaluated using the Rhodamine B degradation under blue light irradiation.  The effect of calcination, pH condition, and visible light source irradiation was carried out in the experiment. The highest photocatalytic activity was found in the sample prepared using the addition of ammonia solution at the concentration of 0.05 M. This photocatalytic activity was 4.13 times higher compared to the Ag3PO4 prepared without the ammonia. The effective condition of photocatalytic activity was achieved at the sample prepared without calcination, degradation at pH of 7 and under blue light irradiation. 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...