Bulletin of Chemical Reaction Engineering & Catalysis
2018: BCREC Volume 13 Issue 3 Year 2018 (December 2018)

Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone

Xi-Shi Tai (College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061)
Peng-Fei Li (College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061)
Li-Li Liu (College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061)

Article Info

Publish Date
04 Dec 2018

Abstract

A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).

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Journal Info
Bulletin of Chemical Reaction Engineering & Catalysis
Website

Abbrev

bcrec

Publisher

Universitas Diponegoro

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...