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Fadlin, Fadlin
Geological Engineering, Jenderal Soedirman University (UNSOED)
Earth & Planetary Sciences Engineering

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Geochemical Signatures of Potassic to Sodic Adang Volcanics, Western Sulawesi: Implications for Their Tectonic Setting and Origin Shaban, Godang; Fadlin, Fadlin; Priadi, Bambang
Indonesian Journal on Geoscience Vol 3, No 3 (2016)
Publisher : Geological Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (11221.374 KB) | DOI: 10.17014/ijog.3.3.195-214

Abstract

DOI:10.17014/ijog.3.3.195-214The Adang Volcanics represent a series of (ultra) potassic to sodic lavas and tuffaceous rocks of predominantly trachytic composition, which forms the part of a sequence of Late Cenozoic high-K volcanic and associated intrusive rocks occurring extensively throughout Western Sulawesi. The tectonic setting and origin of these high-K rocks have been the subject of considerable debates. The Adang Volcanics have mafic to mafitic-intermediate characteristics (SiO2: 46 - 56 wt%) and a wide range of high alkaline contents (K2O: 0.80 - 9.08 %; Na2O: 0.90 - 7.21 %) with the Total Alkali of 6.67 - 12.60 %. Al2O3 values are relatively low (10.63 - 13.21 %) and TiO2 values relatively high (1.27 - 1.91 %). Zr and REE concentrations are also relatively high (Zr: 1154 - 2340 ppm; Total REE (TREY = TRE): 899.20 - 1256.50 ppm; TRExOy: 1079.76 - 1507.97 ppm), with an average Zr/TRE ratio of ~ 1.39. The major rock forming minerals are leucite/pseudoleucite, diopside/aegirine, and high temperature phlogopite. Geochemical plots (major oxides and trace elements) using various diagrams suggest the Adang Volcanics formed in a postsubduction, within-plate continental extension/initial rift tectonic setting. It is further suggested magma was generated by minor (< 0.1 %) partial melting of depleted MORB mantle material (garnet-lherzolite) with the silicate melt having undergone strong metasomatism. Melt enrichment is reflected in the alkaline nature of the rocks and geochemical signatures such as Nb/Zr > 0.0627 and (Hf/Sm)PM > 1.23. A comparison with the Vulsini ultrapotassic volcanics from the Roman Province in Italy shows both similarities (spidergram pattern indicating affinity with Group III ultrapotassics volcanics) and differences (nature of mantle metasomatism).
Geochemical Signatures of Potassic to Sodic Adang Volcanics, Western Sulawesi: Implications for Their Tectonic Setting and Origin Shaban, Godang; Fadlin, Fadlin; Priadi, Bambang
Indonesian Journal on Geoscience Vol 3, No 3 (2016)
Publisher : Geological Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17014/ijog.3.3.195-214

Abstract

DOI:10.17014/ijog.3.3.195-214The Adang Volcanics represent a series of (ultra) potassic to sodic lavas and tuffaceous rocks of predominantly trachytic composition, which forms the part of a sequence of Late Cenozoic high-K volcanic and associated intrusive rocks occurring extensively throughout Western Sulawesi. The tectonic setting and origin of these high-K rocks have been the subject of considerable debates. The Adang Volcanics have mafic to mafitic-intermediate characteristics (SiO2: 46 - 56 wt%) and a wide range of high alkaline contents (K2O: 0.80 - 9.08 %; Na2O: 0.90 - 7.21 %) with the Total Alkali of 6.67 - 12.60 %. Al2O3 values are relatively low (10.63 - 13.21 %) and TiO2 values relatively high (1.27 - 1.91 %). Zr and REE concentrations are also relatively high (Zr: 1154 - 2340 ppm; Total REE (TREY = TRE): 899.20 - 1256.50 ppm; TRExOy: 1079.76 - 1507.97 ppm), with an average Zr/TRE ratio of ~ 1.39. The major rock forming minerals are leucite/pseudoleucite, diopside/aegirine, and high temperature phlogopite. Geochemical plots (major oxides and trace elements) using various diagrams suggest the Adang Volcanics formed in a postsubduction, within-plate continental extension/initial rift tectonic setting. It is further suggested magma was generated by minor (&lt; 0.1 %) partial melting of depleted MORB mantle material (garnet-lherzolite) with the silicate melt having undergone strong metasomatism. Melt enrichment is reflected in the alkaline nature of the rocks and geochemical signatures such as Nb/Zr &gt; 0.0627 and (Hf/Sm)PM &gt; 1.23. A comparison with the Vulsini ultrapotassic volcanics from the Roman Province in Italy shows both similarities (spidergram pattern indicating affinity with Group III ultrapotassics volcanics) and differences (nature of mantle metasomatism).
Komatiitic Lamprophyre in West Sulawesi: First Evidence for >1350°C and 3.5 - 3.8 GPa Mantle Melts Godang, Shaban; Fadlin, Fadlin; Priadi, Bambang; Idrus, Arifudin; Sukadana, I Gde
Indonesian Journal on Geoscience Vol 8, No 1 (2021)
Publisher : Geological Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (5589.007 KB) | DOI: 10.17014/ijog.8.1.39-58

Abstract

DOI: 10.17014/ijog.8.1.39-58The presence of lamprophyric lavas of Late Cenozoic in Talaya Volcanic Formation at the boundary between the subregencies of Mamuju and Tabulahan (Western Sulawesi) associated with the mantle enrichment rocks of the Adang Volcanics is the subject of this study. Petrologically, lamprophyre is composed of orthopyroxene (enstatite), clinopyroxene (augite), biotite, leucite, amphibole, magnetite, and autometasomatism of chlorite in grain minerals and groundmass. The lamprophyre is classified into monchiquite shoshonitic lamprophyre, and it has a komatiitic composition with the ratio of MgO/Al2O3 > 0.7906 (in wt %). The komatiitic monchiquite lamprophyre is characterized by high MgO (10.02 - 12.67 %), relatively low alumina (Al2O3= 10.98 - 11.70 %), SiO2= 46.43 - 47.8 %, TiO2 (0.84 - 1.00 %), FeOt (7.75 - 7.88 %), and relatively high content of alkaline (Na2O: 2.20 - 2.59 %; K2O: 1.58 - 2.45 %; Total alkali: 4.00 - 4.89 %, and CaO (9.29 - 10.71 %). The geochemical trace element plots using various diagrams suggests the geotectonic setting of the lamprophyric rock was formed in suprasubduction alkaline continental-arc, and the proposed source of magmatism comes from the suprasubduction activities from the east. The protolith of magma was originated from partial melting of depleted MORB mantle (DMM), composed of pyroxene-peridotite (garnet-lherzolite). The partial melting conditions are suggested to occur at high pressure (3.5 - 3.8 GPa) and the depth of ~120 km with melting temperature of >1350°C, and the magma is dominantly controlled by olivine fractional crystallization.
Geochemistry Study of Cross-castic Magma Alkalinity Evolution Godang, Shaban; Priadi, Bambang; Fadlin, Fadlin; Leeuwen, Theo Van; Idrus, Arifudin
Indonesian Journal on Geoscience Vol 8, No 2 (2021)
Publisher : Geological Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1147.345 KB) | DOI: 10.17014/ijog.8.2.177-196

Abstract

DOI:10.17014/ijog.8.2.177-196The discrimination of magmatic alkalinity is a classic study that has never stopped for the past ninety years. Various methodologies have been developed since Shand’s classification using the method of alumina saturation to approach silica saturation and the methodology without involving alumina and silica such as K2O vs. Na2O and others, while the aim is to find out the evolution of alkalinity during the magmatic differentiation. The classical magmatic alkalinity evolution has been known as a castic magma alkalinity evolution, where the initial magma in the form of magma-X(a) will evolve along the stages of differentiation and remain a derivative of the initial magma {magmaX(a)}. The same philosophy is also explained in the ternary AFM diagram. Is the magmatic differentiation, followed by fractional crystallization, always an evolution of alkalinity based on caste? This question often raises current debates. This study takes the example of cogenetic volcanic and albitites. The application of the cogenetic volcanic using the selected diagram, which is ‘Three in one an overlaid diagram’. The output of the diagram presents the differentiation of magma which based on the evolution of Mg-series and Fe-series in a discontinuous branch of Bowen 1922 that can take place the castic and cross-castic, e.g. (a) from Mg-series to Mg-series {castic}, (b) from Mg-series to Feseries {cross-castic}, (c) from high-Mg tholeiitic basalt to calc-alkaline series {cross-castic}, (d) from Fe-series to Fe-series {castic}. While the evolution of magmatic alkalinity based on the continuous branch and refer to Trapezoid model generally occurring a cross-castic, e.g. (A) from sodic calc-alkaline to sodic alkaline-calcic, (B) from sodic calc-alkaline to shoshonitic alkaline-calcic, (C) from sodic calc-alkaline to potassic calc-alkaline, (D) from potassic calc-alkaline to shoshonitic alkaline-calcic, (E) sodic alkaline-calcic to sodic alkaline/peralkaline, (F) shoshonitic alkaline-calcic to potassic/ultrapotassic alkaline-calcic (cross-castic in subalkaline), (G) shoshonitic/potassic alkalinecalcic to shoshonitic/potassic alkaline/peralkaline. In this study, Fossa delle Felci volcanics (Italy) shows the evolution of magma from Mg-series to Mg-series, but the evolution of alkalinity of magma reveals the cross-caste (from sodic calc-alkaline to shoshonitic alkaline-calcic). Salak volcanics (Western Jawa) shows the evolution of magma from the Mg-series to Fe-series (cross-castic), and also the cross-castic in the evolution of alkalinity from sodic calc-alkaline to alkaline-calcic. Gothara albitites (India) clearly reveal the sodic-rich alkaline, which the magma generates from the evolution of sodic alkaline-calcic to sodic alkaline without the presence of potassic.
Komatiitic Lamprophyre in West Sulawesi: First Evidence for >1350°C and 3.5 - 3.8 GPa Mantle Melts Godang, Shaban; Fadlin, Fadlin; Priadi, Bambang; Idrus, Arifudin; Sukadana, I Gde
Indonesian Journal on Geoscience Vol 8, No 1 (2021)
Publisher : Geological Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17014/ijog.8.1.39-58

Abstract

DOI: 10.17014/ijog.8.1.39-58The presence of lamprophyric lavas of Late Cenozoic in Talaya Volcanic Formation at the boundary between the subregencies of Mamuju and Tabulahan (Western Sulawesi) associated with the mantle enrichment rocks of the Adang Volcanics is the subject of this study. Petrologically, lamprophyre is composed of orthopyroxene (enstatite), clinopyroxene (augite), biotite, leucite, amphibole, magnetite, and autometasomatism of chlorite in grain minerals and groundmass. The lamprophyre is classified into monchiquite shoshonitic lamprophyre, and it has a komatiitic composition with the ratio of MgO/Al2O3 > 0.7906 (in wt %). The komatiitic monchiquite lamprophyre is characterized by high MgO (10.02 - 12.67 %), relatively low alumina (Al2O3= 10.98 - 11.70 %), SiO2= 46.43 - 47.8 %, TiO2 (0.84 - 1.00 %), FeOt (7.75 - 7.88 %), and relatively high content of alkaline (Na2O: 2.20 - 2.59 %; K2O: 1.58 - 2.45 %; Total alkali: 4.00 - 4.89 %, and CaO (9.29 - 10.71 %). The geochemical trace element plots using various diagrams suggests the geotectonic setting of the lamprophyric rock was formed in suprasubduction alkaline continental-arc, and the proposed source of magmatism comes from the suprasubduction activities from the east. The protolith of magma was originated from partial melting of depleted MORB mantle (DMM), composed of pyroxene-peridotite (garnet-lherzolite). The partial melting conditions are suggested to occur at high pressure (3.5 - 3.8 GPa) and the depth of ~120 km with melting temperature of >1350°C, and the magma is dominantly controlled by olivine fractional crystallization.
Geochemistry Study of Cross-castic Magma Alkalinity Evolution Godang, Shaban; Priadi, Bambang; Fadlin, Fadlin; Leeuwen, Theo Van; Idrus, Arifudin
Indonesian Journal on Geoscience Vol 8, No 2 (2021)
Publisher : Geological Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17014/ijog.8.2.177-196

Abstract

DOI:10.17014/ijog.8.2.177-196The discrimination of magmatic alkalinity is a classic study that has never stopped for the past ninety years. Various methodologies have been developed since Shand’s classification using the method of alumina saturation to approach silica saturation and the methodology without involving alumina and silica such as K2O vs. Na2O and others, while the aim is to find out the evolution of alkalinity during the magmatic differentiation. The classical magmatic alkalinity evolution has been known as a castic magma alkalinity evolution, where the initial magma in the form of magma-X(a) will evolve along the stages of differentiation and remain a derivative of the initial magma {magmaX(a)}. The same philosophy is also explained in the ternary AFM diagram. Is the magmatic differentiation, followed by fractional crystallization, always an evolution of alkalinity based on caste? This question often raises current debates. This study takes the example of cogenetic volcanic and albitites. The application of the cogenetic volcanic using the selected diagram, which is ‘Three in one an overlaid diagram’. The output of the diagram presents the differentiation of magma which based on the evolution of Mg-series and Fe-series in a discontinuous branch of Bowen 1922 that can take place the castic and cross-castic, e.g. (a) from Mg-series to Mg-series {castic}, (b) from Mg-series to Feseries {cross-castic}, (c) from high-Mg tholeiitic basalt to calc-alkaline series {cross-castic}, (d) from Fe-series to Fe-series {castic}. While the evolution of magmatic alkalinity based on the continuous branch and refer to Trapezoid model generally occurring a cross-castic, e.g. (A) from sodic calc-alkaline to sodic alkaline-calcic, (B) from sodic calc-alkaline to shoshonitic alkaline-calcic, (C) from sodic calc-alkaline to potassic calc-alkaline, (D) from potassic calc-alkaline to shoshonitic alkaline-calcic, (E) sodic alkaline-calcic to sodic alkaline/peralkaline, (F) shoshonitic alkaline-calcic to potassic/ultrapotassic alkaline-calcic (cross-castic in subalkaline), (G) shoshonitic/potassic alkalinecalcic to shoshonitic/potassic alkaline/peralkaline. In this study, Fossa delle Felci volcanics (Italy) shows the evolution of magma from Mg-series to Mg-series, but the evolution of alkalinity of magma reveals the cross-caste (from sodic calc-alkaline to shoshonitic alkaline-calcic). Salak volcanics (Western Jawa) shows the evolution of magma from the Mg-series to Fe-series (cross-castic), and also the cross-castic in the evolution of alkalinity from sodic calc-alkaline to alkaline-calcic. Gothara albitites (India) clearly reveal the sodic-rich alkaline, which the magma generates from the evolution of sodic alkaline-calcic to sodic alkaline without the presence of potassic.
Co-Authors Arifudin Idrus Godang, Shaban Godang, Shaban Leeuwen, Theo Van Priadi, Bambang Shaban, Godang Sukadana, I Gde