Arief Budhyantoro
Departemen MIPA, Universitas Surabaya

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SINTESIS FAUJASITE DARI ABU LAYANG BATUBARA : Pengaruh Refluks dan Penggerusan Abu Layang Batubara terhadap Kristalinitas Faujasite Sutarno Sutarno; Yateman Arryanto; Arief Budhyantoro
Jurnal Matematika & Sains Vol 9, No 3 (2004)
Publisher : Institut Teknologi Bandung

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Abstract

Synthesis of Faujasite from coal fly ash has been conducted which involved reflux, grinding fusion and hydrothermal reaction. Coal fly ash is refluxed with hydrochloric acid 5 M at 90 oC for 5 hours. Grinding effect of refluxed coal fly ash on Faujasite synthesis has been studied as other variable on synthesis of Faujasite. Coal fly ash is mixed with NaOH pellet which NaOH : coal fly ash ratio = 1.2, and then fused at 550 oC for 1 hour. Fused coal fly ash is mixed with 100 ml distilled water, stirred and aged for 24 hours. The resulted solution was then reaeted with hydrothermal bomb autoclave at 100 oC for 3 days. The result was characterized with X-ray diffraction using diffractometer shimadzu 3001. The experimental data showed that coal fly ash refluxed with hydrochloric acid 5 M increased in Si/Al ratio of coal fly ash. Synthesis of Faujasite with coal fly ash refluxed with HCl 5 M as raw material produced good crystallinity Faujasite, but the used of unrefluxed coal fly ash as raw material on synthesis of zeolite gave hydroxysodalitet. Synthesis of Faujasite from ungrand coal fly ash whichh is refluxed with HCl 5 M gave better Faujasite crystallinity than that of the grund one.
Pembuatan Batubata dengan Bahan Baku Lumpur Sidoarjo Endang Srihari Mochni; Arief Budhyantoro
Bina Teknika Vol 17, No 1 (2021)
Publisher : Faculty of Engineering UPN "Veteran" Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.54378/bt.v17i1.2570

Abstract

Many attempts to reduce the volume of Sidoarjo mudflow that came out, one of which is the use of Sidoarjo mud for making bricks. The results of research in the chemical laboratory show that the Sidoarjo mud mineral content is mostly silica and alumina minerals, so it is very supportive for use as a material for making bricks. Making bricks requires mixed materials, one of which is paper sludge. Paper sludge waste is discharged from the paper industry, which can pollute the environment if it is discharged directly into the environment. Therefore, a solution is needed by utilizing the potential of the sludge waste. One of them is by using paper sludge as an additive in making bricks, because most of the components of paper sludge waste are calcium carbonate. In building materials, calcium carbonate can function as an additive so that paper sludge waste can be used as an additional material in making bricks. The purpose of this study is to determine the best ratio of Sidoarjo mud with paper sludge to the quality of the bricks, find out the best combustion temperature to the quality of the bricks produced, and compare the quality of the bricks before and after burning. The bricks are synthesized with a variation of the ratio of Sidoarjo mud raw material and paper sludge (1: 0, 1: 1, 2: 1, 3: 1) and variations in combustion temperature (no combustion, 400°C, 450°C, 500°C, 750°C, 900°C). In this study, the best quality of bricks according to SNI is 2: 1 ratio bricks with a combustion temperature of 750 ° C. The ratio of 2: 1 brick with a combustion temperature of 750°C has a percentage of water absorption of 17.17% and compressive strength of 37.78 kg / cm2.