In Natural Language Processing (NLP), Word segmentation and Part-of-Speech (POS) tagging are fundamental tasks. The POS information is also necessary in NLP’s preprocessing work applications such as machine translation (MT), information retrieval (IR), etc. Currently, there are many research efforts in word segmentation and POS tagging developed separately with different methods to get high performance and accuracy. For Myanmar Language, there are also separate word segmentors and POS taggers based on statistical approaches such as Neural Network (NN) and Hidden Markov Models (HMMs). But, as the Myanmar language's complex morphological structure, the OOV problem still exists. To keep away from error and improve segmentation by utilizing POS data, segmentation and labeling should be possible at the same time.The main goal of developing POS tagger for any Language is to improve accuracy of tagging and remove ambiguity in sentences due to language structure. This paper focuses on developing word segmentation and Part-of- Speech (POS) Tagger for Myanmar Language. This paper presented the comparison of separate word segmentation and POS tagging with joint word segmentation and POS tagging.