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Contribution Succinonitrile Additive for Performa LiTFSi Solid Polymer Electrolytes for Li-Ion Battery Qolby Sabrina; Titik Lestariningsih; Christin Rina Ratri; Achmad Subhan
EKSAKTA: Journal of Sciences and Data Analysis VOLUME 1, ISSUE 2, August 2020
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/EKSAKTA.vol1.iss2.art2

Abstract

The purpose of this study is to evaluate the performance of Solid Polymer Electrolyte (SPE) which has the role of replacing liquid electrolyte in the battery system to reduce leakage. Evaluation of electrochemical SPE consisted of mixture lithium salt, solid plasticizer, and polymer precursor with different ratio. Impedance spectroscopy was used to investigate ionic conduction and dielectric response lithium bis(trifluoromethane)sulfony imide (LiTFSI) salt, and additive succinonitrile (SCN) plasticizer. The result showing enhanced high ionic conductivity. In half-cell configurations, wide electrochemical stability window of the SPE has been tested. The great potential of SPE for applications in lithium-ion batteries can be seen from the ability of window stability at room temperature. Additive SCN contributes to forming pores that make it easier for the Li-ion to move from the anode to the cathode and vice versa for better perform SPE. Pore of SPE has been characterization with FE-SEM. Additive 50% w.t SCN shows the best ionic conductivity with 4.2 volt wide stability window and pretty much invisible pores.
Effects of 1-hexyl-1-methylimidazolium iodide ionic liquid to poly(vinyl alcohol)–based solid polymer electrolyte Christin Rina Ratri; Qolby Sabrina; Titik Lestariningsih; Salsabila Zakiyyah
SINERGI Vol 26, No 1 (2022)
Publisher : Universitas Mercu Buana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22441/sinergi.2022.1.016

Abstract

A solid polymer electrolyte (SPE) membrane has been fabricated using poly (vinyl alcohol) (PVA) as polymer host dissolved in deionized (DI) water. Lithium bis(oxalato) borate (LiBOB) electrolyte salt and 1-hexyl 1-methylimidazolium iodide (HMII) are incorporated into the membrane to contribute free ions, enhancing ionic conductivity. SPE was produced using the solution cast technique on Petri dishes. Then these slurries were dried at room temperature. The final product is a self-standing opaque membrane with visually homogenous surfaces. Further observation using FE-SEM revealed magnified images of membrane surfaces and cross-sections. Molecule interaction and crystallinity were observed using FT-IR and XRD. Impedance measured using EIS was used to calculate ionic conductivity. It was found that ionic conductivity of pure PVA film was 3.9×10-7 S/cm while ionic conductivity of SPE before and after ionic liquid addition was 4.77×10-7 S/cm and 2.66×10-6 S/cm.