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Condition optimization of sea pandan leaves biosorben synthesis and adsorptivity test on chromium and lead metal ions in different kinds of waste Susila Kristianingrum; Endang Dwi Siswani; Annisa Fillaeli
Jurnal Sains Dasar Vol 3, No 1 (2014): April 2014
Publisher : Faculty of Mathematics and Natural Science, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1129.971 KB) | DOI: 10.21831/jsd.v3i1.2786

Abstract

This study aims to determine whether or not biosorben synthesized from sea pandanus leaves, the influence of the type of acid used, the optimum adsorption efficiency of Cr and Pb metal ions from various wastes, as well as the synthesis results of biosorben character. The subjects were biosorben of sea pandanus Pandanus tectorius types of Java's southern coast. The objects are adsorptive properties and the character of the pandanus sea biosorben synthesized before and after activation. Purposive sampling is used as the sampling technique. The independent variables are the type of activator (HCl and H2SO4) and waste water. The dependent variables are the adsorptive nature and character of the sea pandanus biosorben synthesis results. The study was conducted in three phases, namely the manufacture of biosorben sea pandan leaves, characterization and determination of adsorption efficiency (Ep) biosorben synthesized on metal ions of Cr and Pb in batik waste, leachate, and oil. Qualitative and quantitative analysis are done using Atomic Absorption Spectrophotometer instrument at a wavelength of 357.9 nm for Cr and 217 nm for Pb. Biosorben characterization was conducted on the moisture content, ash content, volatile content, and carbon content compared with SNI 06-3730-1995 and analyzed by FTIR spectra. It is also seen biosorben surface area of synthesized both before and after activation by porosimetry. Biosorben of pandanus sea has to be synthesized. Biosorben synthesized with 5% H2SO4 solution produced optimum Ep for Cr and Pb metal ions from waste leachate obtained are 75.831% and 98.714%. Character biosorben activation results in a solution of 5% HCl and H2SO4 by FTIR have almost similar spectra. Moisture content, ash content, volatile content, and carbon content of biosorben synthesized with 5% HCl and 5% H2SO4 in accordance with SNI 06-3730-1995. Porosimetry characterization of biosorben synthesized before activation is 3.5756 m2 / g, whereas after activation with HCl 5% to 770.7636 m2/g, and after activation with 5% H2SO4 solution become 153.7002 m2/g. Keywords: biosorben, sea pandanus, adsorptivity test, chromium, lead
PENGARUH PENGGUNAAN KERTAS SEBAGAI MEDIA TANAM TERHADAP KANDUNGAN Cr DALAM JAMUR TIRAM PUTIH (Pleurotus ostreatus) Itna Sari; Annisa Fillaeli
Jurnal Elemen Kimia Vol 5, No 5 (2016): Volume 5, No 5 Edisi 5 Tahun 2016
Publisher : Universitas Negeri Yogyakarta

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Abstract

Penelitian ini bertujuan untuk mengetahui kadar Cr dalam sampel kertasyang digunakan sebagai media tanam jamur tiram putih, mengetahui kadar Cr padajamur tiram putih, dan mengetahui hubungan komposisi media tanam jamur tiramputih dengan cemaran Cr pada jamur tiram putih. Subjek dalam penelitian ini adalahkertas majalah. Objek dalam penelitian ini adalah kadar Cr dalam media tanam danjamur tiram putih. Untuk mengetahui adanya pengaruh komposisi media tanamterhadap cemaran Cr dalam jamur tiram putih, media dibuat dengan komposisi 0, 10,25, dan 50% kertas majalah. Pengecekan kadar Cr dilakukan denganSpektrofotometer Serapan Atom (SSA) pada panjang gelombang 359.3 nm dengandestruksi basah menggunakan campuran antara HNO3 dan HCl.Berdasarkan hasil penelitian, kadar Cr dalam media tanam dengan komposisikertas majalah 0;10; 25; dan 50% adalah 0,653; 1,205; 1,221; dan 1,293 mg/kg.kadar Cr dalam jamur tiram putih dengan berbagai komposisi media tanam adalah3,05; 3,44; 14,91; dan 30,31 mg/kg. kadar Cr dalam jamur tiram putih dalam berbagaikomposisi media tanam adalah 3,05; 3,44; 14,91; dan 30,31 mg/kg. Komposisi mediatanam tersebut berpengaruh terhadap kadar Cr dalam jamur tiram putih. Semakinbesar komposisi media tanam maka kandungan Cr akan semakin tinggi dalam jamurtiram putih.