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Performance Test of Membrane Electrode Assembly in DAFC using Mixed Methanol and Ethanol Fuel with Various Volume Comparison Dwi Hawa Yulianti; Dedi Rohendi; Nirwan Syarif; Addy Rachmat
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 4, No 3 (2019): October 2019
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v4.i3.139

Abstract

Direct Alcohol Fuel Cell (DAFC) performance is influenced by electrocatalysis reactions that occur in Membrane Electrode Assembly (MEA). In this study, MEA was made with Pt-Ru/C (anode) and Pt/C (cathode) catalysts. The results of the electrode characterization with XRD showed a carbon peak at 26.63° and Ru at 40.58°. Based on the results of Cyclic Voltammetry (CV) measurements, the Electrochemical Surface Area (ECSA) electrode value is known to be 373.601 cm2/mg. Meanwhile, the impedance value is 4.315 Ω and the electrical conductivity value is 6.61x10-4 S/cm. MEA testing using MeOH 3 M fuel produces Open Circuit Voltage (OCV) of 0.650 V. Meanwhile, MEA performance testing uses a mixture of methanol and ethanol 2 M in loading conditions obtained the best mixture of fuel composition is methanol: ethanol = 90:10 with a maximum power density of 4.34 mW/cm2 and is able to maintain the voltage at 0.649 V under conditions of 6.875 mA/cm2. The results also showed that the volume of ethanol which was too high resulted in a decrease in cell performance in the fuel mixture caused by the competition of adsorption between competing methanol and ethanol occupying the active site of the catalyst.Keywords: DAFC, fuel cell, Pt-Ru/C, ethanol, methanol, Open Circuit Voltage