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Salmiaton Ali
Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor|Malaysia Catalyst Science and Technology Research Center (Putra Cat), Universiti Putra Malaysia, 43400 UPM Serdang, S
Chemical Engineering, Chemistry & Bioengineering Chemistry

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Green Biofuel Production via Catalytic Pyrolysis of Waste Cooking Oil using Malaysian Dolomite Catalyst Raja Mohamad Hafriz Raja Shahruzzaman; Salmiaton Ali; Robiah Yunus; Taufiq Yap Yun-Hin
Bulletin of Chemical Reaction Engineering & Catalysis 2018: BCREC Volume 13 Issue 3 Year 2018 (December 2018)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (20.814 KB) | DOI: 10.9767/bcrec.13.3.1956.489-501

Abstract

Malaysian Dolomite has shown potential deoxygenation catalyst due to high capacity in removing oxygen compound and produce high quality of biofuel with desirable lighter hydrocarbon (C8-C24). The performance of this catalyst was compared with several commercial catalysts in catalytic pyrolysis of Waste Cooking Oil. Calcination at 900 °C in N2 produced catalyst with very high activity due to decomposition of CaMg(CO3)2 phase and formation of MgO-CaO phase. The liquid product showed similar chemical composition of biofuel in the range of gasoline, kerosene and diesel fuel. Furthermore, Malaysian Dolomite showed high reactivity with 76.51 % in total liquid hydrocarbon and the ability to convert the oxygenated compounds into CO2, CO, CH4, H2, hydrocarbon fuel gas, and H2O. Moreover, low acid value (33 mg KOH/g) and low aromatic hydrocarbon content were obtained in the biofuel. Thus, local calcined carbonated material has a potential to act as catalyst in converting waste cooking oil into biofuel. 
Co-Authors Raja Mohamad Hafriz Raja Shahruzzaman Robiah Yunus Taufiq Yap Yun-Hin