Puspa Nindro Mahayuwati
Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada

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Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production Wega Trisunaryanti; Triyono Triyono; Mohammad Ali Ghoni; Dyah Ayu Fatmawati; Puspa Nindro Mahayuwati; Endah Suarsih
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 3 Year 2020 (December 2020)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.3.8592.743-751

Abstract

Cobalt and/or Molybdenum based catalysts were simply dispersed on γ-Al2O3 through wet impregnation. The set of prepared monometallic and bimetallic catalysts of aCoO/γ-Al2O3, aMoO/γ-Al2O3, aCoOaMoO/γ-Al2O3, and bCoObMoO/γ-Al2O3 were investigated and evaluated in the hydrocracking of Calophyllum inophyllum (CIO) which is not a food crop as well as rich in unsaturated fatty acid that potential to be converted into biofuel. Out of the prepared catalysts, aCoOaMoO/γ-Al2O3 with total   metal content, acidity, and specific surface area of 13.62 wt%, 5.01 mmol.g-1, and 107.67 m2.g-1, respectively, showed the best catalytic performance. The high metal loading of aCoOaMoO/γ-Al2O3is favorable by producing 65.56 wt% liquid fraction through carbocation formation mechanism. It was selective to produce 8.61 wt% gasoline and 5.01 wt% diesel. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production Wega Trisunaryanti; Triyono Triyono; Mohammad Ali Ghoni; Dyah Ayu Fatmawati; Puspa Nindro Mahayuwati; Endah Suarsih
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 3 Year 2020 (December 2020)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.3.8592.743-751

Abstract

Cobalt and/or Molybdenum based catalysts were simply dispersed on γ-Al2O3 through wet impregnation. The set of prepared monometallic and bimetallic catalysts of aCoO/γ-Al2O3, aMoO/γ-Al2O3, aCoOaMoO/γ-Al2O3, and bCoObMoO/γ-Al2O3 were investigated and evaluated in the hydrocracking of Calophyllum inophyllum (CIO) which is not a food crop as well as rich in unsaturated fatty acid that potential to be converted into biofuel. Out of the prepared catalysts, aCoOaMoO/γ-Al2O3 with total   metal content, acidity, and specific surface area of 13.62 wt%, 5.01 mmol.g-1, and 107.67 m2.g-1, respectively, showed the best catalytic performance. The high metal loading of aCoOaMoO/γ-Al2O3is favorable by producing 65.56 wt% liquid fraction through carbocation formation mechanism. It was selective to produce 8.61 wt% gasoline and 5.01 wt% diesel. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).