PT Petrokimia Gresik is the most complete fertilizer producer in Indonesia and one of its production is ZK fertilizer. There are five measurable chemicals that correlate to form ZK fertilizer ie H2O, H2SO4, K2O, SO3 and Cl-. ZK fertilizer monitoring process has not been statistically done by PT Petrokimia Gresik, either univariat or multivariate. Since ZK fertilizer is composed of five chemicals that correlate each other, a multivariate control chart is used. RMCD is one of the robust parameter estimation methods for outlier data. The average vector and variance-covariance matrix derived from the RMCD method is used to calculate the statistics on the multivariate control chart. Therefore, the robust control chart is more sensitive to detecting a shift in production processes compared to the classical ones. The data used in Phase I is daily data per January 1 - April 30, 2017, while Phase II data used is daily data as of May 1 - July 15, 2017. The results of the control chart analysis in Phase I shows that the production process has not been controlled statistically analysis of cause-effect diagrams. Furthermore, the control chart limits in Phase I that have been stable after the repair are used for Phase II production data. The result of the control chart analysis in Phase II shows that the production process has shifted. This can be known by the number of points that out of control.