Saputra, Beny Akhmat
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Effect of Zeolite Concentration on Hydrogel Characteristics of Arrowroot-Based Starch-G-Poly(Acrylic Acid)/Zeolite Composite Sjaifullah, Achmad; Saputra, Beny Akhmat; Adiwinata, I Nyoman; Santoso, Agung Budi; Busroni; Reza, Muhammad
Indonesian Chimica Letters Vol. 1 No. 2 (2022)
Publisher : Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Jember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (856.304 KB) | DOI: 10.19184/icl.v1i2.201

Abstract

This study aims to synthesize a hydrogel zeolite composite of arrowroot starch graft copolymerized with acrylic acid through a radical polymerization reaction in a water. Various scenarios were tested using different natural zeolite concentration to determine the impact on swelling/water absorption of the composite. The resulting product was a solid gel-the test results showed that the swelling increased as the ratio of starch to acrylic acid decreased. Increased starch concentrations generally lead to decreased water absorption (swelling capacity). Adding a zeolite improved swelling to some extent and the optimum zeolite concentration was 60%. The increased concentration of zeolite also hardened the hydrogel composite. The highest swelling in the hydrogel composite of starch-g-poly(acrylic acid)/zeolite 60% is 1056.25 g.g-1. FTIR analysis of functional groups was conducted to determine differences in the IR spectra of arrowroot starch, acrylic acid, hydrogels, zeolites, and composite hydrogel. Si-O signal appearing on the IR spectra of hydrogel composite with wave number 1030 cm-1 indicates that composite hydrogel with zeolite was synthesized